Thermal expansion of icosahedral Al-Pd-Mn and decagonal Al-Cu-Co quasicrystals

Thermal expansion measurements have been performed by X-ray diffractometry on icosahedral Al-Pd-Mn (i-(Al-Pd-Mn)) in the temperature range between 10 and 700K and on decagonal Al-Cu-Co (d-(Al-Cu-Co)) in the range between 100 and 750K. The linear thermal expansion coefficient alpha(T) of i-(Al-Pd-Mn) is about half of that for the pure aluminium phase at room temperature and does not show a negative thermal expansion at low temperatures. The degree of anisotropy in the thermal expansion of d-(Al-Cu-Co) is small; the ratio of the average alpha between the tenfold periodic direction and a quasiperiodic direction perpendicular to it is 0:93 +/- 0:05. The Gruneisen parameter gamma(T) has been evaluated from the measured alpha(T). gamma for d-(Al-CuCo) is almost isotropic, similar to alpha. The gamma values for the two phases lie in the range between 1.5 and 1.8, which are comparable with those for conventional metallic crystals. They are almost constant over the temperature range studied.