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A constitutive model for quasicrystal plasticity
Authors:M. Feuerbacher  P. Schall  Y. Estrin  Y. Bréchet
Affiliation:1. Material Science Division , Indira Gandhi Centre for Atomic Research , Kalpakkam, Tamil Nadu, India;2. Department of Physics , Anna University , Chennai, Tamil Nadu, India;3. Material Science Division , Indira Gandhi Centre for Atomic Research , Kalpakkam, Tamil Nadu, India;4. Pressure and Vacuum Standards , National Physical Laboratory , New Delhi, India;5. Department of Physics , Anna University , Chennai, Tamil Nadu, India
Abstract:High-pressure X-ray diffraction studies on gadolinium sesquioxide (Gd2O3) have been carried out up to a pressure of ~25 GPa in a diamond-anvil cell at room temperature. Gadolinium oxide, which has a cubic or bixbyite structure under ambient conditions, undergoes an irreversible structural phase at around 12 GPa. The high-pressure phase has been identified as a hexagonal La2O3-type structure. The bulk modulus and its pressure derivative of this phase have been calculated.
Keywords:rare earth sesquioxides  f-electron systems  diffraction  high-pressure effects  oxides  phase transformations
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