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Hydrothermal growth of ZnO nanoparticles under different conditions
Authors:Mehmet Yilmaz  Burcu Bozkurt Cirak  Cagri Cirak  Sakir Aydogan
Affiliation:1. Advanced Materials Research Laboratory, Department of Nanoscience and Nanoengineering, Graduate School of Natural and Applied Sciences, University of Ataturk, Erzurum, Turkey;2. Faculty of Education, Department of Elementary Science, University of Ataturk, Erzurum, Turkey;3. Department of Alternative Energy Sources, Vocational High School, University of Erzincan, Erzincan, Turkey;4. Faculty of Science, Department of Physics, University of Erzincan, Erzincan, Turkey;5. Faculty of Science, Department of Physics, University of Ataturk, Erzurum, Turkey
Abstract:In this study, a simple low-temperature hydrothermal method was used to synthesize ZnO nanoparticles. The structural, morphological and optical characterizations of the nanoparticles were evaluated with regard to the zinc content. To achieve this, the molar ratios of the precursors were changed from 0.05 to 0.1 M. The structural and morphological analyses showed that all samples had a polycrystalline hexangular wurtzite crystal structure and the shape of the ZnO nanoparticles changed with increasing zinc content. A possible growth mechanism of the ZnO nanoparticles is explained in terms of the zinc content. Optical measurement revealed that the shape of the nanoparticles affects the position of the band-edge emission as well as the shape of the luminescence spectrum.
Keywords:Nanoparticles  crystal growth  semiconductors  ZnO  luminescence
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