Density evolution during the growth of disc-shaped aluminium nanoparticles on a liquid surface

Aluminium (Al) nanoparticles (NPs) have been successfully fabricated on a liquid surface by thermal evaporation at room temperature. The Al NPs exhibit a disc-shaped morphology with mean diameter and height in the ranges 20–35 and 1.3–3.7?nm, respectively. As the nominal film thickness increases from 0.02 to 0.18?nm, the mean diameter and height are nearly independent of the thickness, implying that the density of the NPs increases during their growth. An explanation for this phenomenon is presented.