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Fluctuation-driven first-order crystal to rotator phase transition
Authors:Prabir K. Mukherjee
Affiliation:1. Department of Physics , Presidency University , 86/1 College Street, Kolkata 700 073 , India pkmuk1966@gmail.com
Abstract:This article develops renormalization-group techniques to analyze the phase transition between the crystal and the rotator-V (Rv), phase in n-alkanes. An explicit free energy is constructed and it is verified that the unstable fixed point corresponds to a fluctuation-driven first-order crystal to Rv phase transition. Available experimental data are consistent with our model.
Keywords:rotator phases  renormalization-group theory  phase transition
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