A thermodynamic model for nanocrystallization in bulk metallic glasses

The structural complexity of glass-forming alloys, which generally contain more than three components, can lead by partial crystallization during annealing to a dispersion of nanocrystals in an amorphous matrix, giving the material a very high mechanical strength. In the present study, the evolution of the driving force for crystallization is expressed as a function of the composition and the chemical potentials of the components. Application to Zr₆₀Al₁₀Cu₃₀ and Zr₆₀Al₁₀Cu₂₀Pd₁₀ bulk metallic glasses shows that the first crystallization step leads to a metastable equilibrium between nanocrystals of an intermetallic and a percolating amorphous phase. The effects of the number of components and of chemical bonding on the fraction crystallized is analysed and discussed.     

{ }-{ } Double twinning in magnesium

Microstructural investigations have been carried out on a fully lamellar Ti₄₉Al₄₇Cr₂Nb₂     

A constitutive model for quasicrystal plasticity

High-pressure X-ray diffraction studies on gadolinium sesquioxide (Gd₂O₃) have been carried out up to a pressure of ～25 GPa in a diamond-anvil cell at room temperature. Gadolinium oxide, which has a cubic or bixbyite structure under ambient conditions, undergoes an irreversible structural phase at around 12 GPa. The high-pressure phase has been identified as a hexagonal La₂O₃-type structure. The bulk modulus and its pressure derivative of this phase have been calculated.     

Neutron and X-ray diffraction studies and cohesive interface model of the fatigue crack deformation behavior

The crack-tip deformation behavior during a single overload, fatigue test of ferritic stainless steel, and Ni-based HAYNES 230 superalloy is studied at different structural levels using (1) neutron-diffraction, from which both the elastic-lattice strain and volume-averaged total dislocation densities are obtained, (2) polychromatic X-ray microdiffraction to probe the geometrically necessary dislocations and boundaries distribution, and (3) an irreversible and hysteretic cohesive interface model which has been implemented into a finite element framework to simulate the stress/strain evolution near the fatigue crack tip. Neutron strain measurements and finite element simulations are in qualitative agreement on the macroscopic length scale. Large plastic deformation induced by the overload and the resulting compressive residual strains are observed in front of the crack tip after the overload, and are the principal reason for the fatigue-crack-growth retardation. Strong strain gradients surrounding the crack propagation result in the formation of a high density of geometrically necessary dislocations near the fractured surface and cause local lattice rotations on the submicron level.     

Characterization of PLZT ceramics modified by isovalent (Ba,Sr), donor (Nb) and acceptor (Zn) dopants for piezoelectric applications

This article describes the influence of microstructure on the dielectric and piezoelectric properties of isovalent- donor- and acceptor-modified lead lanthanum zirconium titanate (PLZT) ceramics. The ceramic compositions, with formula: [Pb_0.954La_0.016Ba_0.01Sr_0.02][Zr_0.525Ti_0.475]_{0.981?( m /2)}Nb_0.012Zn _m O₃ where m =?0, 0.2, 0.4, 0.6, 0.8 and 1.0 mol% Zn, were synthesized via a solid-state reaction method. X-ray diffraction studies are supported by tolerance factor and electronegativity difference measurements. Scanning electron microscopy studies reveal grain growth enhancement with increase of Zn concentration. As the Zn concentration increased from 0 to 0.8 mol%, the room-temperature dielectric constant increased while the Curie temperature decreased continuously. An increase in the Zn content had the most significant effect on the piezoelectric properties. The optimum piezoelectric properties were observed for 1 mol% Zn composition.     

Mechanically driven alloying forces in the fabrication of a Cr–Zr nanocomposite

A highly supersaturated nanocrystalline Cr–25?wt% Zr alloy has been prepared by mechanical alloying of elemental crystalline powders. High-purity powders of Cr and Zr were milled for up to 20?h. The development of the microstructure was investigated by X-ray diffraction (XRD) and scanning electron microscopy. XRD patterns confirmed complete alloying of the Zr and Cr. The contribution of grain boundaries, the chemical potential of a solute atom induced by dislocations, and the elastic strain energy arising from the different sizes of Cr and Zr atoms have been calculated. The alloy formation is discussed with respect to the thermodynamic conditions of the material. The role of internal strains and stored enthalpies by dislocations on solute atoms is the major mechanical driving force for alloying and this is critically assessed in this article.     

New polytypes of long-period stacking ordered structures in a near-equilibrium Mg97Zn1Y2 alloy

By atomic-scale high-angle annular dark-field scanning transmission electron microscopy, the long-period stacking ordered (LPSO) structures in a near-equilibrium Mg₉₇Zn₁Y₂ (at.%) alloy have been characterised. In addition to 18R and 14H, new polytypes of LPSO structures are analysed and determined as 60R, 78R, 26H, 96R, 38H, 40H, 108H and 246R. All of these LPSO structures feature AB′C′A building blocks with two Mg layers and three Mg layers sandwiched between them. The Bravais lattices and space groups of new polytypes of LPSO structures were easily determined via the newly introduced method. A structural relationship between the LPSOs is proposed.     

Observation using synchrotron X-ray diffraction of the crystallographic evolution of α-titanium after oxygen diffusion

In this study, the effect of oxygen diffusion on the crystallographic evolution of α-titanium has been studied using synchrotron X-ray diffraction. Measurements were carried out directly on sample cross-sections that were directly pre-oxidized at high temperature. Changes in hardness, oxygen content and lattice parameters after oxidation were determined by coupling microhardness measurements and electron probe microanalyzer results.