Influence of properties of layered silicate minerals on adsorbed DNA surface affinity,self-assembly and nanopatterning

We report on the specific interaction between DNA and some mica-family minerals and other layered silicate structures. The interaction depends on mineral surface's crystallography, chemistry and potential. These properties are responsible for a remarkable variety of adsorption mechanisms and can be used to modulate surface self-assembly and nanopatterning of DNA. The controlled deposition of DNA onto non-conductive mineral regions with atomically flat boundaries has very attractive applications in nano-biotechnology (for example, microelectronics, microarrays and sensors). In addition, the extreme affinity discovered for some mineral surfaces, together with their ability to organize the DNA molecules, could be an indication of their catalytic potential. It may also have had relevance in the prebiotic environment, with important implications for the earth and life sciences.     

Optical characterization of spin-coated cobalt porphyrazine thin films: effect of annealing temperature

Cobalt porphyrazine thin films were prepared by the spin-coating technique. The coated substrates were annealed at different temperatures (373, 423 and 523 K). The optical properties of the films were investigated by measuring the transmittance and reflectance spectra. The refractive index, extinction coefficient, optical band gap, dielectric constant values and thickness of the films were determined. Results showed that the refractive index, the extinction coefficient and the dielectric constants increased on annealing the films at 373 K in comparison with films annealed at other temperatures. On the other hand, the values of the band gap energy and thickness of the annealed film at 373 K were found to be the lowest in comparison with films annealed at different temperatures.     

Formation of yittrium oxide in cemented carbides

Rare-earth (RE) elements are helpful in improving the mechanical properties of cemented carbides. In this work, the formation of Y₂O₃ in functionally graded cemented carbides is investigated using transmission electron microscopy. The results indicate that Y₂O₃ can stabilize the Co phase with the face-centred cubic structure (α-Co), since it has a cubic structure similar to the high-temperature Co phase. The α-Co phase has a higher plasticity than ε-Co, and this suggests a possible mechanism for the role of RE elements in toughening cemented carbides.     

Novel long-period stacking-ordered structure of martensite in zirconium–cobalt–palladium alloys

A novel long-period stacking-ordered (LPSO) structure of a martensitic phase in a Zr–Co–Pd alloy was discovered and characterized by means of conventional transmission electron microscopy and high-angle annular dark-field scanning transmission electron microscopy. The new phase had a 6O structure and its lattice parameters were estimated to be a = 0.34, b = 0.45 and c = 1.53 nm. The formation mechanism and the space group of the LPSO structure are described.     

Size effects and Hall–Petch relation in polycrystalline cobalt

The mechanical behaviour of polycrystalline hexagonal close-packed cobalt was investigated over a large range of grain size d in order to examine the occurrence of size effects. Crystallographic texture and amount of face centred cubic allotropic phase were maintained unchanged thanks to appropriate heat treatment procedures. The Hall–Petch (HP) relation exhibits two distinct behaviours from the very beginning of plastic strain levels. The conventional HP law is fulfilled for a number of grains across the thickness t higher than a critical value (t/d)_c = 14. For t/d lower than (t/d)_c, a multicrystalline regime is evidenced highlighting a strong reduction in flow stress. The high value of (t/d)_c is related to the low-stacking fault energy of cobalt in the basal plane. The size effect is predominant in the first work hardening stage where slip mechanisms and stacking faults predominate. In the second stage, driven by mechanical twinning processes, this effect is less sensitive. Finally, the size effect could also affect the end of the elastic stage, in link with nonlinear elasticity mechanisms.     

Chemical ordering of Co and Ni in a W-(AlCoNi) crystalline approximant related to Al–Co–Ni decagonal quasicrystals studied by atomic resolution energy-dispersive X-ray spectroscopy

A W-(AlCoNi) crystalline approximant, which is closely related to Al–Co–Ni decagonal quasicrystals, in an Al_72.5Co₂₀Ni_7.5 alloy has been studied by atomic resolution energy-dispersive X-ray spectroscopy (EDS), in an instrument attached to a spherical aberration (Cs)-corrected scanning transmission electron microscope. On high-resolution EDS maps of Co and Ni elements, obtained by integrating many sets of EDS data taken from undamaged areas, chemical ordering of Co and Ni is clearly detected. In the structure of the W-(AlCoNi) phase, consisting of arrangements of transition-metal (TM) atoms located at vertices of pentagonal tilings and pentagonal arrangements of mixed sites (MSs) of TM and Al atoms, Co atoms occupy the TM atom positions with the pentagonal tiling and Ni is enriched in part of the pentagonal arrangements of MSs.