Novel fabrication of bulk Al with gradient grain size distributions via powder metallurgy

We describe a novel approach to synthesize gradient microstructures, defined hereafter as containing a broad but continuous distribution of grain sizes. These microstructures extend the concept of a bimodal grain size distribution and the ability to design with multiple length scales. We demonstrate the proposed approach via experiments involving cryogenic ball milling of Al–4.5Mg–0.4Mn–0.05Fe and Al–50Mg powder followed by subsequent consolidation. Our results reveal that the grains in the consolidated powder present a gradient size distribution ranging from <100 nm to >3 μm. Moreover, phase composition analysis revealed a unique “interfingered” structure where the two starting phases were intermixed in a complex three-dimensional mesh. Hardness studies of this gradient microstructure show average Vickers hardness values of 200 ± 2.6, 204 ± 4.3 and 266 ± 50 for macrohardness, microhardness and nanoindentation, respectively. The standard deviation values highlight that the gradient microstructure is disordered locally, but homogenous macroscopically.     

Observation of Cu nanometre scale clusters formed in Fe85Si2B8P4Cu1 nanocrystalline soft magnetic alloy by a spherical aberration-corrected TEM/STEM

Microstructure of a nanocrystalline soft magnetic Fe₈₅Si₂B₈P₄Cu₁ alloy (NANOMET^®) was investigated by the state of the art spherical aberration-corrected TEM/STEM. Observation by TEM shows that the microstructure of NANOMET^® heat treated at 738 K for 600 s which exhibits the optimum soft magnetic properties has homogeneously distributed bcc-Fe nanocrystallites with the average grain size of 30 nm embedded in an amorphous matrix. Elemental mappings indicate that P is excluded from bcc-Fe grains and enriched outside the grains, which causes to retard the grain growth of bcc-Fe crystallites. The aberration-corrected STEM-EDS analysis with the ultrafine electron probe successfully proved that Cu atoms form nanometre scale clusters inside and/or outside the bcc-Fe nanocrystallites.     

On the enhancement of wear resistance of tool steels by cryogenic treatment

The present article aims to resolve the debate on the degree of benefit of processing tool or die steels by cryogenic treatment. This has been done by measuring transition loads for quenched and tempered die steel with and without cryogenic treatment. The wide range of reported degrees of improvement of wear resistance by cryotreatment is explained by the operative modes and mechanisms of sliding wear considering the wear rate ratio of conventionally treated to cryotreated steels on a two-dimensional map.     

On the deformation mechanism of twinning-induced plasticity steel

The microstructures of an Fe–20Mn–2Si–2Al Twinning-Induced Plasticity (TWIP) steel deformed at different temperature were characterized by X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). Based on microstructural features revealed at various characteristic temperature regions of deformation, the necessary and sufficient conditions of TWIP effect are proposed. Likewise, the competitive characteristic deformation mechanism occurring in this TWIP steel is presented and discussed qualitatively in terms of phase stability and stacking fault energy of the austenitic matrix.     

High-pressure electrical resistivity behaviour of nanocrystalline perovskite (La,Sr)(Mn,Fe)O3

We report here the electrical resistivity of nanocrystalline perovskite-structured La–Sr manganites as a function of pressures up to 8?GPa, at room temperature. The nanocrystalline perovskite manganites were prepared by the sol–gel technique and found to have crystallite sizes of 12–18?nm. The pressure dependence of the electrical resistivity shows a first-order phase transition at 0.66(2)?GPa and a subtle phase transition between 3.5 and 3.8?GPa. The first-order transition at 0.66?GPa can be related to the transition from localized-electron to band magnetism.     

Reactive solid-state dewetting

High-temperature annealing in air of thick crystalline silver films deposited on high-purity nickel foils promotes solid-state dewetting, whereas no hole through the film is produced when annealing under high purity argon. Scanning electron microscopy observations of the film surface and of cross-sections reveal that dewetting occurs only if a nickel oxide layer forms at the silver-nickel interface, as a result of oxygen diffusion through the silver film. The main dewetting mechanism over short times (1h 1120K in air) is observed to be the condensation, at the silver-nickel oxide interface, of vacancies into voids which grow towards the free surface of the silver film.     

Primary dendrite arm spacing during transient directional solidification of Al alloys with low redistribution coefficients

Particular analytical expressions based on a curve fitting on numerical results for primary dendritic growth have been proposed in the literature to encompass binary alloy systems whose redistribution coefficient (k ₀) approaches zero. To date, these expressions have not been checked against experimental results of transient solidification. The present study developed a comparative analysis between the theoretical predictions furnished by such expressions and results from transient solidification experiments with low k ₀ aluminum alloys. The analysis has shown that the proposed approach generally describes the primary dendritic spacing during solidification of Al–Sn alloys which are characterized by very low k ₀ values as well as by very large solidification ranges.     

Valued Relations Aggregation with the Borda Method

The Borda method is a well-known method used to aggregate a profile of crisp binary relations into one weak order. We present a generalization of the Borda method, allowing it to aggregate a profile of valued relations. We give a characterization of the Borda method in this context and we show some links with the PROMETHEE method.     

Characterizations of Negative Definability in Modal Logic

Negative definability ([18]) is an alternative way of defining classes of Kripke frames via a modal language, one that enables us, for instance, to define the class of irreflexive frames. Besides a list of closure conditions for negatively definable classes, the paper contains two main theorems. First, a characterization is given of negatively definable classes of (rooted) finite transitive Kripke frames and of such classes defined using both traditional (positive) and negative definitions. Second, we characterize the negatively definable classes of rooted general frames.     

刻画主体有智能的逻辑(英文)

本文提出两个标准来表示"一个主体有智能":该主体知道它的知识和它做过的活动。然后我们给出若干逻辑系统分别整体地、局部地和半局部地刻画上述标准。最后我们证明这些系统相对各自的语义是框架可靠和框架完全的。