On anomalous channelling effects in ion-implanted silicon

Abstract

In this work results of a Monte Carlo simulation of the ion penetration in a crystalline silicon target are reported. It is shown that, contrary to the common expectation, channelling is sustained by a non-vanishing divergency of the ion beam for a nominally random orientation of the target.     

Effects of crystallization on corrosion resistance and electron work function of Zr65Al7.5Cu17.5Ni10 amorphous alloys

The effects of crystallization on the electron work function and corrosion resistance of Zr₆₅Al_7.5Cu_17.5Ni₁₀ amorphous alloys have been studied. The single-phase amorphous alloy exhibits a better corrosion resistance and has a higher work function than the partially and fully crystallized alloys with the same composition. The close relationship between corrosion resistance and work function indicates that the Kelvin probe technique can be a powerful tool for characterizing the corrosion behaviour of amorphous alloy on an electronic level.     

Low-energy boron implants into silicon: A molecular dynamics simulation study of implants into a stepped surface

Molecular dynamics simulations have been conducted to study implantation of boron with a low kinetic energy (E _k in the range 5 eV) into the silicon surface. The bombarded surface has a realistic stepped structure and the geometry of the step edge is taken from the theory of Chadi (1987, Phys. Rev. Lett., 59, 1691). It is found that reflection is the more common event. However subsurface implants and adatom formations are also observed. The effect of the step morphology is important and different trajectories are observed if the ions hit steps of different shapes.     

Characterisation of magnesium oxide and its interface with α-Mg in Mg–Al-based alloys

Magnesium oxide (MgO) films and particles have been collected by pressurised filtration of a Mg-8.6wt%Al-0.67wt%Zn (AZ91D) alloy melt. The morphology of the oxides and their interfaces with the α-Mg phase were investigated by high-resolution transmission electron microscopy. It was found that the oxide films consisted of large numbers of sub-micrometre-sized MgO particles, and that melt shearing can effectively break up the oxide films and disperse the oxide particles. For the first time, orientation relationships (ORs) of OR I: [1?1?1]_MgO～2° from (0?0?0?1)_α-Mg and (0?1?1)_MgO?//[2?1?1?0)_α-Mg; and OR II: (1?1?1)_MgO//(1?1?0?1)_α-Mg and [0?1?1]_MgO//[1?2?1?1]_α-Mg, were observed between the MgO particles and the α-Mg matrix. The calculated Bramfitt planar disregistries were 5.5% and 2.5% for the two ORs, respectively, indicating good lattice matching between MgO and α-Mg at the interface. With the evidence of grain refinement effect observed in the sheared AZ91D magnesium alloy, the possibility of MgO particles to act as potent nucleants for heterogeneous nucleation of α-Mg grains is discussed in terms of the crystallographic criterion.     

Linear instability signals the initiation of motion of a twin plane under load

This letter presents a study of the atomic mechanism of the initiation of motion of a static twin plane under applied mechanical load in a model shape-memory material. By tracking the deformation under load and using linear stability analysis, we find that the eigenvalues of the Hessian matrix provide an indicator of the initiation of motion of the twin plane. The initiation of motion is signaled by a linear instability and a drop in the lowest eigenvalue to zero as well as a sharp drop in higher eigenvalues. Additionally, by comparing with direct molecular dynamics, we see that the eigenmode associated with the zero eigenvalue is found to accurately predict the initial mode of motion. We also find that the initial motion occurs through the formation of a stacking fault just ahead of the existing twin plane and the broadening of the stacking fault drives further transformation.     

Catalyst incorporation in ZnSe nanowires

ZnSe nanowires, 5–10?nm wide and several microns long, were fabricated by Au-catalyzed molecular beam epitaxy. Specially designed silicon–silicon dioxide substrates allowed an examination of individual nanowires with a combination of phase-contrast high-resolution transmission electron microscopy, Z-contrast scanning transmission electron microscopy imaging and energy-dispersive X-ray spectroscopy using a low-current electron probe with a diameter of 0.2?nm. Experimental results demonstrate direct evidence of Au incorporation within single-crystal sphalerite ZnSe nanowires.     

Precipitation in a Cu–4Ti–2Be alloy

It is known that the binary Cu–2?wt.% Be alloy can be strengthened by ageing its supersaturated solution at 523?K. The increase in the strength arising from ageing is because of the formation of GP zones. The same level of strength is achieved by ageing the supersaturated solid solution of a dilute binary Cu–4?wt.% Ti alloy at 723?K. In contrast to Cu–2?wt.% Be alloy, the increase in strength in this alloy occurs on account of spinodal decomposition of the as-quenched microstructure through the mechanism of clustering and ordering. In the present study, decomposition of a supersaturated solid solution of the ternary Cu–4?wt.% Ti–2?wt.% Be alloy was studied. Whereas ageing of this alloy at 523?K resulted in the formation of GP zones like in a Cu–2?wt.% Be alloy, ageing at 723?K resulted in a spinodally decomposed microstructure as in a Cu–4?wt.% Ti alloy. The decomposition of the ternary alloy at the two temperatures by two different mechanisms indicates that Be and Ti in solution in Cu act, more or less, independently of each other during ageing.     

{ }-{ } Double twinning in magnesium

Microstructural investigations have been carried out on a fully lamellar Ti₄₉Al₄₇Cr₂Nb₂