Stability of nanocrystalline disordered NiAl synthesized by mechanical alloying

The thermal stability of highly disordered mechanically alloyed nanocrystalline NiAl has been evaluated. The reordering of disordered NiAl(Cr) shows extremely fast kinetics on isothermal annealing at and above 673K, while the process is quite sluggish below this temperature. On the other hand, significant reordering in NiAl(Fe) takes place even at 573K. A unique dependence of reordering on the grain growth of the nanophase is evident during thermal treatment. Rapid grain coarsening begins only as the absolute temperature approaches approximately 0.4 T m, where T m is the melting point of the aluminide.     

Magnetic properties of Mn-doped armchair ZnO nanotubes: a Monte Carlo study

The magnetic properties of a Mn-doped armchair ZnO nanotube have been studied using Monte Carlo simulation. The variation of zero-field-cooled and field-cooled magnetisation with reduced temperatures for different values of the dilution x (where x is the Mn concentration: Zn_1?xMn_xO) are given. The freezing temperatures and magnetisation vs. crystal field are calculated for different dilutions x. Finally, the hysteresis loops for different dilutions and temperatures are given for a fixed reduced temperature and crystal field. Superparamagnetic behaviour is observed for small values of x and low temperatures.     

Characterization of Al/n-ZnO/p-Si/Al structure with low-cost solution-grown ZnO layer

We report the fabrication of Al/n-ZnO/p-Si/Al diode structures with a flower-like ZnO layer. The average grain size, microstrain and dislocation density in the ZnO layer were determined as 25?nm, 1.55?×?10^?3 and 3.23?×?10¹³?cm^?2, respectively. From absorption spectra, the optical band gap was found to be ～3.17?eV. A red shift was attributed to non-stoichiometry arising from Zn⁺² ions substituting for oxygen vacancies. The ideality factor was determined as 1.55. The barrier height was calculated as 0.71?eV from I–V characteristics and 0.73?eV using the Norde plots.     

A novel method for measurement of electronic work function of micro/nanostructure materials using a Kelvin probe system

Work function (WF) can be measured using the Kelvin probe (KP) technique to characterize surface behavior of micro/nanostructures grown on substrates such as metals or semiconductors. However, for such micro/nanostructures, substrates with different WF can strongly affect the measurements if they are exposed directly to face the Kevin probe tip. In this article, a model is proposed to investigate the WF of sparse ZnO nanorods grown on an Si substrate. It is demonstrated that theoretical results from the model are consistent with experimental observations performed using a KP system.     

Hydrothermal growth of ZnO nanoparticles under different conditions

In this study, a simple low-temperature hydrothermal method was used to synthesize ZnO nanoparticles. The structural, morphological and optical characterizations of the nanoparticles were evaluated with regard to the zinc content. To achieve this, the molar ratios of the precursors were changed from 0.05 to 0.1 M. The structural and morphological analyses showed that all samples had a polycrystalline hexangular wurtzite crystal structure and the shape of the ZnO nanoparticles changed with increasing zinc content. A possible growth mechanism of the ZnO nanoparticles is explained in terms of the zinc content. Optical measurement revealed that the shape of the nanoparticles affects the position of the band-edge emission as well as the shape of the luminescence spectrum.