A novel approach for controlling precipitation kinetics based on diffusional and thermodynamic interactions in multicomponent systems

A novel concept for selection of alloying elements based on diffusional and thermodynamic interactions is proposed. A general model to predict enhancement or reduction of diffusion flux of an element arising from the addition of another is described and specifically applied to determine the appropriate ternary alloying addition to reduce the fast precipitation kinetics observed in binary Ti–Fe based alloy. It is experimentally shown that addition of Cr and Mo decreases the kinetics of precipitation of TiFe, whereas addition of Ta and Nb enhances the kinetics, which is consistent with the predictions of the proposed model.     

Deformed substructures in fine-grained tetragonal zirconia

Transmission electron microscopy (TEM) has been employed to examine the deformed microstructures of a high-purity tetragonal zirconia polycrystal containing 3mol% yttria. The TEM observations reveal that piled-up and tangled dislocations are developed within grains at a high stress, but such substructures do not appear at a lower stress, except for a small number of isolated dislocations. The stress-dependent deformed microstructures suggest that the dislocation substructures observed at a high stress are not due to any experimental artefacts. Applying a model proposed by Eshelby et al. to the observed pile-up dislocations, it can be estimated that a stress concentration of the order of 14-25 is generated around multiple-grain junctions during deformation.     

Self-assembly-assisted growth of two-dimensional Penrose tiling

An algorithm for the growth of two-dimensional Penrose tiling, based on symmetry operations on a seed rhombus, is discussed and demonstrated. Independent of empirical matching rules, as suggested by Penrose [Bull. Inst. Math. Appl. 10 266 (1974)], and also overcoming the scaling-down operation, as proposed by Ramachandrarao et al. (Acta Crystallogr. A 47 210 (1991)], the present algorithm follows a mechanism akin to self-assembly and can be continued ad infinitum.     

Formation of Ga–Pd–Sc icosahedral quasicrystal and approximant phases

ABSTRACT

We report the formation of an icosahedral quasicrystal and its approximant in the Ga–Pd–Sc alloy. The primitive-type quasicrystal with a six-dimensional lattice constant of 0.713?nm formed in the melt-quenched Ga₅₃Pd₃₀Sc₁₇ alloy, with a similar composition to that of the Ga₅₅Pd₃₀Sc₁₅ 1/1 approximant. The atomic-scale observation and chemical analysis of the 1/1 approximant by scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy showed that the approximant consisted of Tsai-type clusters with a characteristic chemical ordering. Furthermore, a series of approximants were observed in the Ga₅₅Pd₃₀RE₁₅ alloys by replacing Sc with other rare-earth elements (REs) (RE?= Y, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu). These approximants, which have relatively small lattice constants and consequently smaller RE–RE distances compared with those for other RE-containing Tsai-type approximants, may be candidates for materials with novel electronic and magnetic properties similar to those observed in Au-based quasicrystals and approximants.     

Supersonic crack motion in a harmonic lattice

Antiplane shear cracks in a harmonic square lattice have been studied in a molecular dynamics simulation. They can reach velocities larger than the shear wave velocity.     

Dislocation relaxation and alloy softening of bcc alloys

Recently, low-frequency internal friction measurements on a series of Fe–Cr alloys by Konstantinovi? and Terentyev [M.J. Konstantinovi? and D. Terentyev, Mater. Sci. Eng. A 521–522 (2009) p.106] have demonstrated that increasing Cr concentrations lead to an increase in the strength of the β-relaxation at the cost of the γ-relaxation (Chambers’ notation). In the same concentration and temperature regime, the alloys show alloy softening. It is argued that both phenomena are due to the same process, namely the influence of foreign atoms on the transformation of the cores of a ₀?1 1 1?/2 screw dislocations from their low-temperature configuration, capable of forming kink pairs on {1 1 0} planes, to their high-temperature configuration with kink-pair generation on {2 1 1} planes.     

high-resolution electron microscopy at a (113) symmetric Thermally activated step motion observed by tilt grain-boundary in aluminium

Grain-boundary migration is demonstrated to proceed by lateral propagation of a small step in a (113), [110] symmetric Al tilt grain-boundary. In-situ high-resolution (transmission) electron microscopy (HREM) at 523K allowed the study of atomic-scale detail at video rates during the migration process. The grain-boundary translational states on both sides of the step are identical, which leads to a step dislocation. This defect can move laterally by a combination of climb and glide. Dynamic HREM images indicate considerable atomic agitation within the dislocation core. A detailed temporal analysis of the step movements shows small random displacements of the dislocation core.     

Strong interactions between hydrogen in solid solution and stress-induced martensite transformation of Ni–Ti superelastic alloy

The role of the dynamic interactions between hydrogen in a solid solution and the stress-induced martensite transformation in hydrogen embrittlement has been investigated using trained Ni–Ti superelastic alloy. In a cyclic tensile test in the stress plateau region caused by stress-induced martensite and reverse transformations after hydrogen charging, a further decrease in the critical stress for the martensite transformation is observed. In addition, the number of cycles to fracture for a trained specimen is significantly larger than that for a non-trained specimen. Since most of the charged hydrogen is preferentially trapped in defects induced by training, the hydrogen embrittlement is considerably suppressed as a result of decreasing interactions between the hydrogen and the transformation. The present results indicate that hydrogen in a solid solution more strongly interacts with the stress-induced martensite transformation than hydrogen trapped in defects, thereby further enhancing the hydrogen embrittlement related to phase transformations.     

Dynamic precipitation of Al–Zn alloy during rolling and accumulative roll bonding

In this study, cold rolling was performed on a binary Al–20 wt%Zn alloy and dynamic precipitation identified for the first time in Al alloys under cold rolling. Zn clusters formed after application of 0.6 strain, and the Zn phase precipitated upon further increasing strain. Both grain refinement and rolling-induced defects are considered to promote Zn precipitation. The hardness of Al–Zn alloy initially increased with strain up to a strain of 2.9 and then decreased with increasing rolling strain. Dynamic precipitation greatly affects the strengthening mechanism of the rolled Al–Zn alloy under various strains.