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801.
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803.
The wetting behaviour and associated pressure effect of water in single-walled carbon nanotubes (SWCNTs) are investigated through molecular dynamics (MD) simulations. It is found that water molecules can enter SWCNTs via surface diffusion, and the effective infiltration rate increases with pressure. The effect of pressure on infiltration rate is highly non-linear, exhibiting characteristics of both hydrophilic and hydrophobic surfaces. There exists a nominal infiltration pressure that is dependent on the SWCNT size, above which the water flux is significantly increased. 相似文献
804.
Tuukka Verho 《Philosophical Magazine Letters》2013,93(9):592-600
Novel high-performance composite materials often draw inspiration from natural materials such as bone or mollusc shells. A prime feature of such composites is that they are, like their natural counterparts, quasibrittle. They are tolerant to material flaws up to a certain characteristic flaw-tolerant size scale, exhibiting high strength and toughness, but start to behave in a brittle manner when sufficiently large flaws are present. Here, we establish that better flaw tolerance can be achieved by maximizing fracture toughness relative to the maximum elastic energy available in the material, and we demonstrate this concept with simple two-dimensional coarse-grained simulations where the transition from brittle to quasibrittle behaviour is examined. 相似文献
805.
Muhammad Ajmal Choudhary Julia Kundin Heike Emmerich 《Philosophical Magazine Letters》2013,93(9):451-458
Recently, we derived a generalized model for isotropic as well as anisotropic crystal lattice systems of arbitrary Poisson's ratio within the framework of the continuum phase-field crystal (PFC) approach [R. Prieler, J. Hubert, D. Li, B. Verleye, R. Haberkern, H. Emmerich, J. Phys.: Condens. Matter 21 (2009) p.464110] and showed how its parameters can be derived from classical density functional theory [M.A. Choudhary, D. Li, H. Emmerich and H. Löwen, J. Phys.: Condens. Matter 23 (2011) p.265005]. Here, we present a general procedure to model anisotropic material systems of arbitrary Poisson's ratios. In that way we can for the first time identify PFC solutions of arbitrary Poisson's ratios and thereby extend the applicability of the PFC method to a larger class of material systems. 相似文献
806.
We use dimensional analysis to derive scaling relationships for self-similar indenters indenting solids that exhibit power-law creep. We identify the parameter that represents the indentation strain rate. The scaling relationships are applied to several types of indentation creep experiment with constant displacement rate, constant loading rate or constant ratio of loading rate over load. The predictions compare favourably with experimental observations reported in the literature. Finally, a connection is found between creep and 'indentation-size effect' (i.e. changing hardness with indentation depth or load). 相似文献
807.
Y. You 《Philosophical Magazine Letters》2013,93(12):656-667
N atom is one of the most frequent foreign interstitial atoms in α-iron along with C atoms. The Fe–C potential has been well-developed and can reproduce many significant interactions of C with point defects present in α-iron. However, there exists no satisfactory Fe–N potential to describe the interactions of N with point defects. Here, we develop a many-body potential for N in α-iron. The potential parameters are determined by fitting to ab initio data, which includes energetics, configurations, and relaxations of Fe atoms close to N atom. This potential successfully describes the interactions of Fe–N across a wide range of defect environments. The potential employs the embedded atom method form and hence is appropriate for large-scale molecular dynamics simulation. 相似文献
808.
Bootstrap方法是一种有放回的再抽样方法, 可用于概化理论的方差分量及其变异量估计。用Monte Carlo技术模拟四种分布数据, 分别是正态分布、二项分布、多项分布和偏态分布数据。基于p×i设计, 探讨校正的Bootstrap方法相对于未校正的Bootstrap方法, 是否改善了概化理论估计四种模拟分布数据的方差分量及其变异量。结果表明:跨越四种分布数据, 从整体到局部, 不论是“点估计”还是“变异量”估计, 校正的Bootstrap方法都要优于未校正的Bootstrap方法, 校正的Bootstrap方法改善了概化理论方差分量及其变异量估计。 相似文献
809.
Ashley M. Butler Elizabeth V. Brestan Sheila M. Eyberg 《Child & family behavior therapy》2013,35(3):257-262
ABSTRACT This study examined the Eyberg Child Behavior Inventory (ECBI) discrepancy hypothesis, which asserts that a discrepancy in score elevations on the ECBI Intensity and Problem Scales is related to problematic parenting styles. The Intensity Scale measures the frequency of child disruptive behavior, and the Problem Scale measures parent perception of their child's behavior as problematic. In a sample of 216 female caregivers of 3-to7-year-old children, the magnitude of discrepancy between T scores on the two ECBI scales was found to predict parental tolerance for child misbehavior. A one-standard-deviation difference in ECBI T scores identified (a) parents intolerant of their child's misbehavior when the Problem score was highest and (b) overly permissive parents when the Intensity score was highest. 相似文献
810.
We investigated when consumers' judgments about a product reflect information about its product source (the person who creates the product). Three experiments manipulated congruence between the source's gender and the gender-typing of the source's product. When congruent with expectations (a male conductor played male-typed music), pre-trial source information had the same effect on post-trial product judgments as when source information was absent. Incongruence (a female conductor played male-typed music) distorted product attribute judgments when the source's competence was questioned. Her music was judged to be more delicate, less powerful and worse quality than his. This process of product experience being assimilated into incompetence stereotypes required minimal cognitive resources. When the incongruent source was undoubtedly competent, the amount of experiential evidence about an attribute influenced distortion. Consumers judged powerful music as powerful regardless of conductor gender, but, lacking much evidence about its delicacy, judged hers as more delicate than his. The selective effect of source gender information reflects consumers' cognitively effortful hypothesis testing of beliefs that gender expresses itself in a person's output against experiential evidence. 相似文献