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41.
Yongqiang Wang Zhiwei Zhang Hu Mao Guohui Zhu Na Li 《Philosophical Magazine Letters》2013,93(7):283-291
ABSTRACTThe tensile properties of TiNi43.5Fe6.5 alloy samples having different grain sizes (0.16, 0.35, 1.7, 2.3, and 3.9?μm) and fabricated by severe plastic deformation and annealing were investigated. It was observed that both the strength and the elongation of the alloy increase with a decrease in the grain size until the average size reaches 1.7?μm. However, for average grain sizes smaller than 1.7?μm, the elongation decreases continuously with further grain refinement. On the other hand, the strain-hardening rate does not decrease with the decrease in plasticity but instead increases slightly. The poor ductility of the ultrafine-grained TiNi43.5Fe6.5 alloy is accompanied by a high degree of strain hardening. This newly observed ductility behaviour of the ultrafine-grained TiNi43.5Fe6.5 alloy is elucidated by characterising the intragranular and grain boundaries. 相似文献
42.
Dongming Liu Haiming Wen Dalong Zhang Chuanxin Wang Yaojun Lin Yuhong Xiong 《Philosophical Magazine Letters》2013,93(11):741-748
In this study, we report on the influence of high pressure on the microstructure evolution of cryomilled nanostructured Al alloy powders during spark plasma sintering (SPS). Our experimental results suggest that the particular mechanism that governs grain growth during SPS depends on the magnitude of the applied pressure. In the case of material consolidated at a high pressure (e.g. 500 MPa), grain coarsening occurs via a combination of thermally activated grain boundary (GB) migration, stress-coupled GB migration and grain rotation-induced grain coalescence. In contrast, in the case of the material consolidated at a low pressure (50 MPa), grain growth occurs primarily via thermally activated GB migration. 相似文献
43.
I.I. Mazin 《Philosophical Magazine Letters》2013,93(10):731-738
Recent observation of proximity effect [H.B. Heersche, P. Jarillo-Herrero, J.B. Oostinga, L.M.K. Vandersypen, and A.F. Morpurgo, Nature, bf 446 (2007) p. 05555.] has ignited interest in superconductivity in graphene and its derivatives. We consider Ca-intercalated graphene bilayer and argue that it is a superconductor, and likely with a sizeable T c . We find substantial and suggestive similarities between Ca-intercalated bilayer (C6CaC6), and CaC6, an established superconductor with T c = 11.5 K. In particular, the nearly free electron band, proven to be instrumental for superconductivity in intercalated graphites, does cross the chemical potential in (C6CaC6), despite the twice smaller doping level, satisfying the so-called “Cambridge criterion”. Calculated properties of zone-center phonons are very similar to those of CaC6. This suggests that the critical temperature would probably be on the same scale as in CaC6. 相似文献
44.
Guang Cheng 《Philosophical Magazine Letters》2013,93(6):278-287
A three-dimensional finite element model is developed to accurately capture the force–depth and charge–depth nanoindentation response of several classes of anisotropic piezoelectric materials such as relaxor ferroelectrics for which analytical models are at present unavailable. Upon validating the finite element model for transversely isotropic materials, it is demonstrated that the nanoindentation response of anisotropic piezoelectric materials displays a strong dependence on the nature of the indenter geometry and relatively weak dependence on the indenter conductivity. Furthermore, by recourse to “longitudinal” and “transverse” indentations, the nanoindentation method can also be used to identify the poling directions in piezoelectric materials as well. 相似文献
45.
J.S. Kim S. Yi Daniel J. Sordelet U. Kühn J. Eckert 《Philosophical Magazine Letters》2013,93(9):582-590
The change of the specific surface area in porous Ni59Zr20Ti16Si2Sn3 metallic glass (MG) upon partial crystallization was investigated. The observed increase in the surface area of the annealed Ni-based MG foams is due to the formation of homogeneously distributed Ni10(Zr,Ti)7 rod-shape intermetallic phases with nominal diameters around 250?nm and ~800?nm length on the surface of MG struts during the crystallization. For longer annealing, the specific surface area decreases again due to a change of the morphology of the crystals from rod-like to disc-like appearance, thus suggesting an optimum regime for increasing the specific surface area upon isothermal annealing at a given temperature. 相似文献
46.
We report here the electrical resistivity of nanocrystalline perovskite-structured La–Sr manganites as a function of pressures up to 8?GPa, at room temperature. The nanocrystalline perovskite manganites were prepared by the sol–gel technique and found to have crystallite sizes of 12–18?nm. The pressure dependence of the electrical resistivity shows a first-order phase transition at 0.66(2)?GPa and a subtle phase transition between 3.5 and 3.8?GPa. The first-order transition at 0.66?GPa can be related to the transition from localized-electron to band magnetism. 相似文献
47.
Alexander V. Evteev Elena V. Levchenko Daniel P. Riley Irina V. Belova 《Philosophical Magazine Letters》2013,93(12):815-830
The kinetic reaction in a Ni-coated Al nanoparticle with equi-atomic fractions and diameter of approximately 4.5 nm is studied by means of molecular dynamics simulation, using a potential of the embedded atom type to model the interatomic interactions. First, the large driving force for the alloying of Ni and Al initiates solid state amorphization of the nanoparticle with the formation of Ni50Al50 amorphous alloy. Amorphization makes intermixing of the components much easier compared to the crystalline state. The average rate of penetration of Ni atoms can be estimated to be about two times higher than Al atoms, whilst the total rate of inter-penetration can be estimated to be of the order of 10?2 m/s. The heat of the intermixing with the formation of Ni50Al50 amorphous alloy can be estimated at approximately ?0.34 eV/at. Next, the crystallization of the Ni50Al50 amorphous alloy into B2-NiAl ordered crystal structure is observed. The heat of the crystallization can be estimated as approximately ?0.08 eV/at. Then, the B2-NiAl ordered nanoparticle melts at a temperature of approximately 1500 K. It is shown that, for the alloying reaction in the initial Ni-coated Al nanoparticle, the ignition temperature can be as low as approximately 200 K, while the adiabatic temperature for the reaction is below the melting temperature of the nanoparticle with the B2-NiAl ordered structure. 相似文献
48.
The microstructure evolution and hardness of nanocrystalline nickel during pack rolling at room temperature have been investigated. It was found that the roll-bonding side (R) and non-roll-bonding side (NR) behaved quite differently. The hardness of side R is higher than that of side NR. No obvious work softening was observed in either side R or side NR until the strain reached ~ 0.611. Quantitative X-ray diffraction analysis indicated that the grain size in side NR increases faster than that in side R, a result confirmed by transmission electron microscopy. Texture analysis showed that (2 0 0) preferred orientation first strengthens but then weakens in both sides NR and R, while a strong (2 2 0) preferred orientation emerges, particularly in side R. Further texture analysis suggests that dislocation slip is responsible for the texture discrepancy between side NR and side R. The dislocation activity, grain rotation and grain growth are discussed based on the experimental results. 相似文献
49.
研究采用实验法,以288名中小学生为被试,考察了不同情绪状态、不同情绪调节策略与不同类型情绪材料记忆的关系。结果表明:(1)快乐情绪的再认反应时短于悲伤情绪,快乐情绪的再认正确率高于悲伤情绪。(2)表达抑制策略下,词汇与图片的再认反应时无显著差异;认知重评策略下,词汇的再认反应时短于图片;对词汇和图片的再认反应时,认知重评组短于表达抑制组;认知重评组的再认正确率高于表达抑制组。(3)快乐材料再认反应时短于悲伤材料;快乐情绪下快乐材料的再认正确率高于悲伤材料,悲伤情绪下悲伤材料的再认正确率高于快乐材料。 相似文献
50.