Thermal stability of nanocrystalline fcc and hcp Ni(Si) synthesized by mechanical alloying of Ni90Si10

The thermal stability of nanocrystalline fcc and hcp Ni(Si), obtained by mechanical alloying of Ni₉₀Si₁₀, has been studied. The allotropic transformation from fcc to hcp Ni(Si) is accompanied by a volume expansion of 8.6% and is observed when fcc Ni(Si) reaches a critical crystallite size of 10nm. The hcp phase transforms to stable fcc Ni(Si) at 573K. It has been identified that the lattice distortion in nanometre-sized crystallites from the equilibrium configuration and the decrease in the interfacial energy with grain refinement act as self obstacles in controlling the grain growth of nanocrystalline materials.     

Microwave-induced heating of a single glassy phase and a two-phase material consisting of a metallic glass and Fe powder

Metallic glasses exhibit low viscosity in a temperature range between the glass transition and the crystallization temperature, a feature that allows successful sintering of glassy powders. Microwave heating, being volumetric, has significant advantages over conventional heating in materials processing, such as substantial energy savings, high heating rates and process cleanliness. In the present study, we investigate the stability of Cu₅₀Zr₄₅Al₅ glassy powders and the formation of a bulk two-component metallic glassy-crystal sample by microwave heating in a single-mode cavity (915 MHz) in an alternating magnetic field.     

Deformation mechanism crossover and mechanical behaviour in nanocrystalline materials

We use molecular dynamics simulations to elucidate the transition with decreasing grain size from a dislocation- to a grain-boundary-based deformation mechanism in nanocrystalline fcc metals. Our simulations reveal that this crossover is accompanied by a pronounced transition in the mechanical behaviour of the material; namely, at the grain size where the crossover occurs (the 'strongest size'), the strain rate under tensile elongation goes through a minimum. This simultaneous transition in both the deformation mechanism and the corresponding mechanical behaviour offers an explanation for the experimentally observed crossover in the yield strength of nanocrystalline materials, from Hall-Petch hardening to 'inverse Hall-Petch' softening.     

Twinning behaviour of TWIP steel studied by Taylor factor analysis

The twinning behaviour of Twinning-induced plasticity (TWIP) steel has been studied by analysing the grain orientation and the Taylor factor, based on microstructural and electron backscatter diffraction device observations. It is demonstrated that the Taylor factor can give an important guideline for determining the deformation mode of TWIP steel. The higher the Taylor factor, the easier the formation of twins and thus a tendency for the deformation mode to be mechanical twinning, while a low Taylor factor corresponds to a slip deformation mode. When the loading temperature is relatively low, the high Taylor factor regions increase and thus deformation twinning becomes easier while slip becomes more difficult, leading to increased tensile stress and decreased elongation.