Characterisation of magnesium oxide and its interface with α-Mg in Mg–Al-based alloys

Magnesium oxide (MgO) films and particles have been collected by pressurised filtration of a Mg-8.6wt%Al-0.67wt%Zn (AZ91D) alloy melt. The morphology of the oxides and their interfaces with the α-Mg phase were investigated by high-resolution transmission electron microscopy. It was found that the oxide films consisted of large numbers of sub-micrometre-sized MgO particles, and that melt shearing can effectively break up the oxide films and disperse the oxide particles. For the first time, orientation relationships (ORs) of OR I: [1?1?1]_MgO～2° from (0?0?0?1)_α-Mg and (0?1?1)_MgO?//[2?1?1?0)_α-Mg; and OR II: (1?1?1)_MgO//(1?1?0?1)_α-Mg and [0?1?1]_MgO//[1?2?1?1]_α-Mg, were observed between the MgO particles and the α-Mg matrix. The calculated Bramfitt planar disregistries were 5.5% and 2.5% for the two ORs, respectively, indicating good lattice matching between MgO and α-Mg at the interface. With the evidence of grain refinement effect observed in the sheared AZ91D magnesium alloy, the possibility of MgO particles to act as potent nucleants for heterogeneous nucleation of α-Mg grains is discussed in terms of the crystallographic criterion.     

Application of the stagnant stage concept for monitoring Mn partitioning at the austenite-ferrite interface in the intercritical region for Fe–Mn–C alloys

The length of the stagnant stage during the new ferrite growth starting from a mixture of austenite and ferrite has been investigated for a Fe-0.17Mn-0.023C (wt%) alloy. It was found that the stagnant stage depends on the thermal path followed to create the mixture, and deduce that the tie-lines for austenite to ferrite transformation are quite different from those for ferrite to austenite transformation. The length of the stagnant stage is determined by the very local partitioning effect at the interface, and it can be used as a tool to monitor the Mn partitioning.     

Supersonic crack motion in a harmonic lattice

Antiplane shear cracks in a harmonic square lattice have been studied in a molecular dynamics simulation. They can reach velocities larger than the shear wave velocity.     

Interactions between interfacial dislocations and γ/γ′ interface during high temperature – low stress creep in nickel-based single crystal superalloy

ABSTRACT

The interaction between interfacial dislocations and γ/γ′ interface is critical to the high temperature creep properties of single crystal superalloys. However, only a few studies have paid attention to the detailed structure such as local interfacial morphologies and the elemental distribution around interfacial dislocations. In this paper, the interfacial protrusions and related dislocations in a single crystal superalloy after creep at high temperature – low stress have been investigated in detail. It is found that the morphology and size of the interfacial protrusions remain almost the same during the early and middle stages of high temperature creep, which indicates a local equilibrium at the interfacial protrusions. Steps at different height are formed at the γ/γ′ interface at the initial stage of high temperature creep since dislocations could move along the γ/γ′ interface, which indicates that dislocation motion at different creep stage may affect the morphology of γ/γ′ interface.     

Multiple hydrogen trapping at monovacancies

Novel structures for multiple hydrogen atoms trapped at a monovacancy are discussed. Using atomistic simulations based on semiempirical interatomic potentials and density functional theory, we find low-energy configurations for four, five, and six hydrogen atoms around a monovacancy different than those that have been previously studied in the literature. The energetics of hydrogen binding are compared to results, both theoretical and experimental, previously published in the literature. We argue that up to four hydrogen atoms may be exothermically bound to monovacancy.     

Linear-parabolic shift of initially sharp interface in AB diffusion couple above the ordering temperature

It is shown that initially sharp interface in AB diffusion couple, above the ordering temperature, can shift with anomalous kinetics, i.e. deviations from the parabolic growth kinetics are possible. The initial slopes of the shift versus time functions can be even unity for large diffusion asymmetry (the ratio of diffusion coefficients of the parent materials in orders of magnitude) and gradually decrease to 0.5 at larger distances (longer times). This is in accordance with earlier results obtained in phase separating systems. It is shown that from the results of simulations the crossover thickness, X*, between the linear and parabolic regimes can also be calculated, and the applicability of the linear–parabolic law is confirmed. Furthermore, it is illustrated that the crossover thickness depends exponentially on the diffusion asymmetry parameter, with the exponent close to the value obtained from analytical estimations.     

Failure to Mentalize: Defect or Defense?

ABSTRACT

The author reviews current thinking on the phenomena of failure to mentalize and provides an alternative to the structural defect point of view. Also included are some clinical implications of this alternative viewpoint.     

工作家庭冲突的初步研究

工作家庭冲突是一种特殊类型的角色交互冲突 ,它对于了解人的胜任特征模型和提高人力管理的效率有重要的意义。本研究通过在银行、科研单位和高新技术企业进行的有关工作家庭冲突的调查结果表明 ,较之家庭—工作冲突 ,工作—家庭冲突能较好预测员工的工作压力 ,它通过工作压力间接地对工作满意感起作用 ,女性员工的工作态度更容易受到工作—家庭冲突的影响。