Internal stress and defect-related free volume in submicrocrystalline Ni studied by neutron diffraction and difference dilatometry

A combined study of neutron diffraction and difference dilatometry on submicrocrystalline Ni prepared by high pressure torsion aims at studying the anisotropic behaviour during dilatometry and its relation to internal stress and structural anisotropy. Macroscopic stresses were undetectable in the dilatometer samples. Along with specific tests such as post cold-rolling, this shows that an observed anisotropic length change upon annealing is not caused by internal stress, but can be explained by the inherent microstructure, i.e. the anisotropic annealing of relaxed vacancies at grain boundaries of shape-anisotropic crystallites.     

应变率显像评价尿毒症EF正常患者左心室局部功能

为探讨应变率显像(SRI)技术评价尿毒症左心室射血分数(EF)正常患者左心室局部功能的价值,对41例尿毒症EF正常患者及20例健康自愿者左心室心肌纵向SRI曲线进行分析,测量各曲线收缩峰值应变率(SRs)、舒张早期峰值应变率(SRe)、舒张晚期峰值应变率(SRa)并计算SRe/SRa。结果显示,尿毒症组左心室各节段SRs、SRe、SRe/SRa均低于对照组(P0.05)。因此,尿毒症EF正常患者已经存在局部心肌舒缩功能障碍,并且这种障碍可以被SRI技术敏感、定量地评价。     

Variable-ratio schedules as variable-interval schedules with linear feedback loops.

The mathematical theory of linear systems has been used successfully to describe responding on variable-interval (VI) schedules. In the simplest extension of the theory to the variable-ratio (VR) case, VR schedules are treated as if they were VI schedules with linear feedback loops. The assumption entailed by this approach, namely, that VR and VI-plus-linear-feedback schedules are equivalent, was tested by comparing responding on the two types of schedule. Four human subjects' lever pressing produced monetary reinforcers on five VR schedules, and on five VI schedules with linear feedback loops that reproduced the feedback properties of the VR schedules. Pressing was initiated by instructions in 2 subjects, and was shaped by successive approximation in the other 2. The different methods of response initiation did not have differential effects on behavior. For each of the 4 subjects, the VR and the comparable VI-plus-linear-feedback schedules generated similar average response rates and similar response patterns. The subjects' behavior on both types of schedule was similar to that of avian and rodent species on VR schedules. These results indicate that the assumption entailed by the VI-plus-linear-feedback approach to the VR case is valid and, consequently, that the approach is worth pursuing. The results also confute interresponse-time theories of schedule performance, which require interval and ratio contingencies to produce different response rates.     

Newly observed microscopic planar defects on {111} in natural diamond

Abstract

Circular disc-crack-like defects randomly distributed on {111} planes have been discovered by 300kV transmission electron microscopy in diamond that had crystallized on non-faceted growth surfaces of mean orientation {100}. In a sample of ～ 100 defects, disc diameters were narrowly distributed about a mean of 1·2 μm and one in seven discs were located on a coplanar stacking fault of average diameter 2 μm. Discs totally enclosed within the specimen exhibit concentric moiré fringes covering their image areas when viewed obliquely, showing them to be dilated into thin lenticles. Internal pressures, deduced from moiré-fringe counts on six lenticles, were in the range 1·5 to 1·8 GPa.     

Fractal growth of graphite nodules in iron

It has been found from a large number of statistical tests that graphite nodules in malleable iron grow with time according to a power law. The growth of the nodules and their fractal dimension have been investigated experimentally as a function of annealing time. Based on the assumption of carbon-diffusion-controlled growth in the initial stage, the growth equation is R _G = K ₁ t ^1/(D-1), where R _G is the radius of the graphite nodules, t the time, D the fractal dimension and K ₁ a constant. Assuming cementite-dissolution-controlled growth in the later stages of growth, the relation is R _G = K ₃ t ^3/D , where K ₃ is a constant. The fractal dimension, or the aggregate state of the graphite nodules, strongly influences the growth process.     

On elastic–viscoplastic modeling of nanotwinned metals based on coupled intra-twin and twin-boundary-mediated deformation mechanisms

An elastic–viscoplastic model has been developed for nanotwinned (nt) metals based on coupled intra-twin and twin-boundary-mediated (TBM) deformation mechanisms. The grain-size dependence of intra-twin plasticity was incorporated in the proposed model to determine the transitional twin thickness corresponding to the maximum strength. In addition, the joint distribution of grain size and twin thickness was also taken into account to simulate the microstructure of nt metals. The results obtained show that the TBM deformation mechanism dominated at low strain rate and small twin thickness, and that the grain-size and twin-thickness distributions had significant influence on the macroscopic behavior of nt metals. A linear relation between the transitional twin thickness and grain size is predicted by the proposed model, which is in good agreement with the results obtained from three-dimensional molecular dynamics simulations and experiments.     

New insights on tensile plasticity of ultrafine-grained metallic materials

ABSTRACT

The tensile properties of TiNi_43.5Fe_6.5 alloy samples having different grain sizes (0.16, 0.35, 1.7, 2.3, and 3.9?μm) and fabricated by severe plastic deformation and annealing were investigated. It was observed that both the strength and the elongation of the alloy increase with a decrease in the grain size until the average size reaches 1.7?μm. However, for average grain sizes smaller than 1.7?μm, the elongation decreases continuously with further grain refinement. On the other hand, the strain-hardening rate does not decrease with the decrease in plasticity but instead increases slightly. The poor ductility of the ultrafine-grained TiNi_43.5Fe_6.5 alloy is accompanied by a high degree of strain hardening. This newly observed ductility behaviour of the ultrafine-grained TiNi_43.5Fe_6.5 alloy is elucidated by characterising the intragranular and grain boundaries.     

High-pressure electrical resistivity behaviour of nanocrystalline perovskite (La,Sr)(Mn,Fe)O3

We report here the electrical resistivity of nanocrystalline perovskite-structured La–Sr manganites as a function of pressures up to 8?GPa, at room temperature. The nanocrystalline perovskite manganites were prepared by the sol–gel technique and found to have crystallite sizes of 12–18?nm. The pressure dependence of the electrical resistivity shows a first-order phase transition at 0.66(2)?GPa and a subtle phase transition between 3.5 and 3.8?GPa. The first-order transition at 0.66?GPa can be related to the transition from localized-electron to band magnetism.     

Observation of planar stacking faults in a Ti-rich two-phase Ti-Al alloy after deformation at elevated temperatures

It is a common observation that in two-phase Ti-Al-based binary alloys, deformation of the gamma phase occurs by 1/2<110]-type ordinary dis-location activity and twinning associated with 1/6<112] type partials. In the present study the microstructure of a new Ti-Al-based alloy (Ti-47at.% Al-2at.%Mn-2at.%Nb+ 0.8 vol.% TiB₂) with a duplex microstructure consisting of primary equiaxed gamma grains and lamellar alpha₂+ gamma colonies was studied by transmission electron microscopy (TEM) after deformation at elevated temperatures. Planar stacking faults were found in the gamma laths. A detailed contrast analysis by TEM shows that these planar stacking faults lying on {111} planes are bound by all the fcc variants of the Shockley partial dislocations of type 1/6<121>, in contrast with the observations in stoichiometric binary TiAl alloys, where only 1/6<112]-type Shockley partials are found to be associated with the true twins. It is proposed that the addition of ternary and quaternary elements such as Mn and Nb promotes the other variants of the fcc-like dissociations (not common in L1₀structure) in the present alloy.