Voids formed from solidifying tin particles in solid aluminium

In this study, voids commonly associated with tin particles in two aluminium alloys containing microalloying additions (0.01 at.%) of tin have been observed by transmission electron microscopy. The voids were generated by quenching the alloys at moderate rates (10²–10³ K s^?1) from a temperature (718 K) in excess of the melting temperature (501 K) of elemental tin in tin–microalloyed aluminium. Estimates of the void volume as a function of the volume of the associated tin particle reveal a linear relationship consistent with the excess volume resulting from the solidification of the tin particle. The formation and stabilisation of shrinkage voids in metallic alloys are suggested to arise from a combination of high vacancy supersaturation, the large volumetric misfit strain of the solidifying tin particle and a reduction in void surface energy associated with segregation of alloying elements.     

Influence of heat treatment on the microstructural evolution of Al–3 wt.% Cu during high-pressure torsion

Solution-treated, peak-aged and overaged samples of the model alloy Al–3?wt.% Cu, obtained by selective heat treatments of the pre-material, have been subjected to high-pressure torsion at room temperature and at 200?°C. The mechanical behaviour of the samples was investigated with torque measurements during deformation and microhardness measurements after deformation. Irrespective of the initial material condition, in the saturation regime a comparable equilibrium microstructure was found consisting of ultrafine aluminium grains stabilized by precipitates formed at grain boundaries.     

Stress-enhanced grain growth in a nanostructured aluminium alloy during spark plasma sintering

In this study, we report on the influence of high pressure on the microstructure evolution of cryomilled nanostructured Al alloy powders during spark plasma sintering (SPS). Our experimental results suggest that the particular mechanism that governs grain growth during SPS depends on the magnitude of the applied pressure. In the case of material consolidated at a high pressure (e.g. 500 MPa), grain coarsening occurs via a combination of thermally activated grain boundary (GB) migration, stress-coupled GB migration and grain rotation-induced grain coalescence. In contrast, in the case of the material consolidated at a low pressure (50 MPa), grain growth occurs primarily via thermally activated GB migration.     

Experimental investigations of TB2 alloy by pack boriding with rare-earth oxides

ABSTRACT

An orthogonal test with four factors, namely temperature, time, type of rare-earth oxides (REOs) and REO content, was performed to obtain the optimised boriding parameters of TB2 alloy by pack boriding with REOs. It is found that temperature has the strongest effect on the boride layer thickness, while time has the strongest effect on the surface hardness and coefficient of friction. The optimum parameters for pack boriding of TB2 alloy with REO are a temperature of 1373?K, a time of 20?h, La₂O₃ as the REO with a content of 4?wt.%.     

Importance of chamber gas pressure on processing of Al-based metallic glasses during melt spinning

The effect of chamber gas pressure on the amorphicity of Al₈₅Ni₅Y₁₀ alloy was studied for the melt-spinning process. The amorphicity of as-quenched ribbons was characterized by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The chamber atmosphere pressure is crucial to the cooling rate of melt spinning. At high vacuum, at pressure less than 0.001?atm, fully crystalline fragments are obtained. Monolithic amorphous ribbons were only obtained at a gas pressure of 0.1?atm, 0.2?atm or higher. The extended contact length between ribbons and the copper wheel contributes to the high cooling rate of melt spinning in Al-based glass forming alloys; that is supported by images recorded by a high-speed camera. Higher chamber pressure increases contact length between ribbons and the wheel, which is qualitatively elucidated by Bernoulli's equation.     

Superelastic behavior of ultrafine-grain-structured Ti-35 wt%Nb alloy fabricated by equal-channel angular extrusion

The superelasticity of a Ti-35?wt%Nb alloy has been explored by fabricating an ultrafine-grain-structured specimen through equal-channel-angular-extrusion processing. A complete superelasticity of 3.5% was realized by refining the grain size down to about 0.25?µm and by inducing the precipitation of an ω-phase. The superelasticity was possible because the β-phase was largely stabilized at room temperature as a result of the severe grain refinement and Nb-enrichment in the matrix on account of the ω-precipitation.     

Structural heterogeneity in a binary Pd–Si metallic glass

A Pd₈₁Si₁₉ bulk metallic glassy rod with a diameter of 4.5 mm was produced by water quenching the fluxed alloy. Despite a negative heat of mixing between Pd and Si elements and very simple components constituting the binary Pd–Si glass-forming system, structural heterogeneity was induced either by slow cooling of a liquid or sub-T_g annealing of glassy ribbons. The sub-T_g annealing experiments evidenced that a more ordered amorphous phase emerged from the original glassy matrix. Our work provides an alternative way to tune the microstructure of metallic glasses by subsequent thermal treatment on an as-prepared single glassy phase.     

Dodecagonal quasicrystal in Mn-based quaternary alloys containing Cr,Ni and Si

A dodecagonal quasicrystal showing 12-fold symmetry forms in Mn-rich quaternary alloys containing 5.5 or 7.5 at.% Cr, 5.0 at.% Ni and 17.5 at.% Si. After annealing at 700 °C for 130 h, the quasicrystal precipitated in a matrix of β-Mn-type crystalline phase. The shape of the quasicrystal is needle-like having a length of several tens of micrometres. Electron diffraction as well as powder X-ray diffraction experiments has revealed the following characteristics of the quasicrystal: diffraction symmetry 12/mmm, the presence of systematic extinction for h₁h₂h₂h₁h₅-type reflections with odd h₅ index, and then five-dimensional space group P12₆/mmc. Indexing of the reflections indicated that the dimension of the common edge in the equilateral triangle–square tiling is 4.560 Å, and the periodicity is 4.626 Å along the 12-fold axis. This is the first example of the dodecagonal quasicrystal synthesized by ordinary metallurgical method in 3-d transition-metal alloys.     

Texture development during cross rolling of a dual-phase Fe–Cr–Ni alloy: experiments and simulations

Texture development during multi-step cross rolling of a dual-phase Fe–Cr–Ni alloy has been investigated. X-ray diffraction was used to investigate changes in crystallographic texture of both the constituent phases (austenite and ferrite) through changes in orientation distribution function. After deformation, rotated brass (rotated along φ₁, i.e. the sample normal direction ND), along with a weak cube texture was observed in austenite, while a strong rotated cube texture was obtained in ferrite. Texture was also simulated for various strains using a co-deformation model by self-consistent visco-plastic (VPSC) formulation. Simulations showed strong rotated brass texture in austenite and a strongly rotated cube, α-fibre (sample rolling direction RD //<1 1 0>) and γ-fibre (ND //<1 1 1>) in ferrite after highest strain (ε_t = 1.6). VPSC models could not effectively capture the change in crystallographic texture during cross rolling. In ferrite, simulations showed an overestimation of γ-fibre component and an underestimation of rotated cube component. Simulated texture of austenite, on the other hand, showed an overestimation of rotated brass with an absence of cube component. The results are rationalised based on the possible role of shear banding and activation of non-octahedral slip system during cross rolling, both of which are not incorporated in conventional VPSC models.     

Application of the Bons–Azuma method and determination of grain growth mechanism in rolled Ti–Zr alloys

Zr-containing Ti alloys have widely been developed owing to the infinite solid solubility of Zr in Ti and its avirulence, leading respectively to high strength and good biocompatibility. It is known that the Zr addition gives rise to grain refinement when rolled Ti–Zr alloys are annealed; nevertheless, the governing mechanism by which Zr addition in Ti can reduce grain size is not fully understood. In this study, the grain growth behaviour of rolled Zr-free and Zr-containing (Ti–10Zr, wt.%) alloys is analysed using analytical transmission electron microscopy and the classical and Bons–Azuma methods by evaluating the grain growth exponent. Irrespective of the evaluation technique and Zr content, the grain growth exponent is found to be close to ~0.3, indicating the occurrence of normal grain growth in the Zr-free alloy and solute drag mechanism in the Zr-containing alloy. It is found that the grain size and grain growth rate are significantly reduced by Zr segregation near grain boundaries, resulting from the solute drag mechanism.