Investigations of the optical spectra and local structure for nickel(II) ions in XF2 (X = Mg,Zn) single crystals

A complete diagonalization energy matrix method (CDM) is proposed for 3d ⁸ ions in orthorhombic site (D _{2 h} ) symmetry. As an application, the optical spectra of XF₂ : Ni²⁺ (X = Mg, Zn) is well explained on the basis of both the CDM and the semi-self-consistent field d-orbital (semi-SCF d-orbital) theory. In addition, by establishing the relationship between the optical spectra and local structure, it has been possible to calculate the crystal structure parameters for XF₂:Ni²⁺ from optical measurements on Ni²⁺ ions. The theoretical results are in good agreement with experimental findings.     

Study of incommensurate modulation in V-doped La2Cu1- x (VO) x O4 + δ by transmission electron microscopy

Structural variations in a hole-rich grain of V-doped La₂Cu_{1? x} (VO) _x O_{4+ δ} (x?=?0.045, δ?=?0.011) superconducting compound have been studied by electron diffraction and high-resolution transmission electron microscopy. Two types of one-dimensional (1-D) incommensurate modulation were observed one after the other when the specimen was exposed to electron beam irradiation. The features of these two modulated structures have been studied and are discussed.     

Effect of metastable Cr(Mo)s/Cr(Mo)a powders on mechanical alloying the immiscible Cu–Mo–Cr system

Metastable-state alloy powders are usually synthesised by milling and occur as products of mechanical alloying (MA), but they are rarely used as starting materials for other MA processes. In this work, metastable-state alloy powders, including supersaturated solid-solution Cr(Mo)s and amorphous Cr(Mo)a were prepared in advance. Then, the Cr(Mo)s/Cr(Mo)a powder mixture was mechanically alloyed with elemental Cu to form Cu–Mo–Cr alloy. The effects of the metastable-state powder Cr(Mo)s/Cr(Mo)a on MA of the immiscible Cu–Mo–Cr system were evaluated. Phases and microstructures of the milled powders were analysed by XRD and TEM, respectively. The results show that amorphous Cu-60wt.%Cr(Mo) and supersaturated solid-solution Cu-20wt.%Cr(Mo) alloy powders can be synthesised by MA. It is concluded that MA of the Cu–Mo–Cr ternary alloy system is significantly promoted when elemental Cu powder is milled with metastable-state alloy powder Cr(Mo)s/Cr(Mo)a. Furthermore, the promoting effect of amorphous Cr(Mo)a on MA the Cu–Mo–Cr alloy system is much greater than that of supersaturated solid-solution Cr(Mo)s, during the milling process.     

Microstructures and tensile properties of 304 steel with dual nanocrystalline and microcrystalline austenite content prepared by aluminothermic reaction casting

The microstructures of 304 stainless steels with different amounts of nanocrystalline and microcrystalline austenite prepared by an aluminothermic reaction casting, without and with annealing at 1073?K for 8?h, have been investigated by X-ray diffraction, an electron probe micro-analyser, a transmission electron microscope and a scanning electron microscope. The steels, both without and with annealing, consisted of different dual nanocrystalline and microcrystalline austenite combinations and a little nanocrystalline δ ferrite, while the average grain size of the nanocrystalline austenite increased from 19 to 26?nm and volume fraction of the microcrystalline austenite increased from 17 to 30% after annealing. The tensile strength of the steel was dramatically increased from 500 to 1000?MPa and the tensile elongation ratio increased from 8 to 12% after annealing. However, the tensile strength was decreased to 600?MPa and the tensile elongation ratio increased from 12 to 22% after an annealing at 1273?K. The combination of dual nanocrystalline and microcrystalline austenite obtained after the annealing at 1073?K results in the best tensile properties.     

Surface energy of free clusters of bubbles: An estimation

We propose an approximate equation for the surface energy of two-dimensional free bubble clusters which we compare with exact calculations of the surface energy of symmetrical clusters consisting of a central bubble surrounded by one or two shells of bubbles of two different areas. The accuracy of the equation is good for relatively narrow distributions of the areas and of the number of sides of the bubbles but underestimates the energy for large widths of those distributions. We propose a similar approximate equation for the surface energy of three-dimensional clusters.     

Ductile fracture mechanism in fine-grained magnesium alloy

The ductile fracture mechanism in a fine-grained magnesium alloy has been investigated by transmission electron microscopy-focused ion beam techniques. In coarse-grained or conventional magnesium alloys, twins form at the very beginning of the deformation process, and crack propagation occurs through the twin boundaries. However, in the alloy used in this study, subgrain structures were found instead of twins at the crack tip. Nanoscale twins formed subsequently owing to large stress in the crack propagation route. The fine-grained alloys showed high fracture toughness resulting from resistance to the twins at the beginning of the deformation.     

3D shape and orientation of nanoscale Pb inclusions at grain boundaries in Al observed by TEM and STEM tomography

We have combined high-angle annular dark field/scanning transmission electron microscopy (HAADF-STEM) tomography with bright field (BF)-TEM tomography to characterize small inclusions of Pb at a grain boundary in Al. It was found that the shape of the grain boundary inclusions is more complex than previously thought. By using moiré fringes observed at some orientations of the specimen in a BF-TEM tomographic tilt series, we were able to determine the orientation of each grain, the axis and angle of misorientation of the grain boundary, and the facet planes of the grain boundary inclusions. The 3D shape of the inclusions was determined by merging this information with the HAADF-STEM tomography.     

Twin-coupled domain structures in epitaxial relaxor ferroelectric Ba(Zr,Ti)O3 thin films on (001) MgO substrate

We report the twin-coupled multi-oriented domain structures in the epitaxial BZT20 (20%Zr) films grown on the (001) MgO substrate using pulsed-laser deposition. Transmission electron microscopy shows that the film consists of an epitaxial layer of pseudo-cubic perovskite structure and a nanopillar layer of multi-oriented twin domain structures near the surface. Four types of the twin domains were formed in the nanopillar layers by coherently joining their {111} with the epilayer and aligning their ?110? directions parallel to the ?110? axes of the epilayer. A non-uniform polarization switching behavior was observed due to the formation of such complex structure in the BZT20 films.     

High-resolution electron microscopy observations of microplastic fracture in SiC under ball milling at room temperature

Nanometre-sized kinks and cracks formed in 6H SiC under ball milling (BM) at room temperature have been observed and characterized on the atomic scale using high-resolution electron microscopy (HREM). Observations of the kinks show that numerous positive and negative partials are aligned at either of the kink boundaries, and the stacking sequences in the kink band are considerably different from those in the other areas. It was also observed that the (0001) lattice planes in the kink band are kinked, indicating that microplasticity occurs in the normally brittle material SiC under BM even at room temperature. HREM observations of cracks show that cracks previously observed by transmision electron microscopy are not completely open but are at the initiation stage of fracture. Inside a crack, one residual kink region can be clearly observed, which indicates a correlation between kink and crack, that is a crack evolves from a kink.     

Coarsening behaviour of gamma prime precipitates and concurrent transitions in the interface width in Ni-14 at.% Al-7 at.% Cr

Coupling atom probe tomography and transmission electron microscopy, the temporal evolution of γ′ precipitate morphology and size distribution and compositional width of the γ/γ′ interface, have been tracked in a model Ni-14Al-7Cr (at.%) alloy, during isothermal annealing at 800?°C subsequent to rapid quenching. During the initial annealing period, coalescence-dominated growth and coarsening of γ′ precipitates are accompanied by a gradual decrease in the interface width, eventually leading to classical LSW coarsening with a constant interface width at extended annealing time periods.