Electronegativity difference as a factor for evaluating the thermal stability of Al-rich metallic glasses

This article proposes a factor, the critical electronegativity difference Δx _cri, to correlate alloy composition with thermal stability and glass-forming ability of Al–Ni–RE (RE: Rare Earth element) ternary metallic glasses. The Al-rich metallic glasses with Δx > Δx _cri exhibit glassy behavior, whereas alloys with Δx < Δx _cri are nanocrystalline. Nanoglassy alloys occur when Δx ≈ Δx _cri. The best glass formers are located near Δx _cri. Furthermore, an equation has been deduced to calculate Δx _cri with varying RE covalent atomic radius.     

Vertex interactions and film shapes in two-dimensional foam

A model of the structure of two-dimensional foam (cells separated by circular arcs (films) meeting at threefold vertices) is considered. Films that are so curved as to be nearly semicircular arcs are problematic for conventional foam structure computations, which aim to identify the pressures needed to achieve specified bubble areas. When the films have near semicircularity, tiny variations in pressure can lead to large changes in the computed bubble area, and hence a failure to meet the specified targets. A new algorithm for determining foam structure is presented. It is based on 'freezing' most of the system, except the nearly semicircular arcs, and then finding the particular bubble pressures associated with the latter via an analytic approximation. This procedure is shown to work well for structure relaxation in a small bubble cluster. Large relaxed bubble clusters are considered briefly at the end of the paper.     

Effect of heat treatment on the microstructure and mechanical properties of spray-formed 7055 aluminium alloy

7055 Al alloys samples were prepared by spray forming and hot-extrusion followed by two different aging treatment procedures. Their different distributions of GP zones, and nanoscale precipitates η′ (MgZn) and η (MgZn₂) are extensively investigated by transmission electron microscope (TEM). The mechanical properties, including tensile strength, Vickers hardness and elongation of both aged 7055 Al alloys, have also been measured and analysed. It is found that T6 and T76 aging treatment results in quite different microstructure and mechanical properties. The outstanding performance of the 7055 Al alloys after T6 aging treatment is attributed to nanoscale semi-coherent dispersion precipitates.     

Assessment of data glasses for motorcycle riders in a simulated lane change test

Relevant riding information such as speed or navigation instructions are typically displayed in head down dashboards on Powered Two-Wheelers. Data glasses provide information directly in the field of view and could, therefore, reduce glances away from the roadway ahead to focus on the dashboard. This study aimed to examine whether providing information in data glasses while riding as compared to classical head down displays makes a difference. Therefore, a total of N = 24 riders completed the ISO lane change test on a motorcycle riding simulator. Meanwhile, riders had to react to changing turn-by-turn indications which were either displayed in the dashboard, in the data glasses or redundantly in both display technologies. The performance in the lane change test and the reaction times achieved in the secondary task were examined along with riders’ workload by means of the Detection Response Task (DRT) and questionnaire data. Results revealed that riders’ lane change performances did not differ between the conditions ‘data glasses’ and ‘dashboard’. Information displayed in the data glasses was recognized faster and fewer turn-by-turn indications were missed. The performance in the DRT remained unchanged throughout the test conditions, while the subjective workload experience decreased with the use of data glasses. Overall, the results suggest that data glasses did not provoke an attentional capture effect and were, therefore, not inferior compared to dashboards regarding riding performance. However, data glasses did reduce the perceived workload and may in particular provide a safety benefit when time-critical information, such as warnings, need to be displayed.     

Structural analysis of 30RO–30Al2O3–40B2O3 ( R = Mg,Ca or Sr) glasses

Bond-compression and ring-deformation models are used to quantitatively analyze the acoustical properties (elastic moduli, Poisson's ratio, Debye temperature and longitudinal attenuation) of 30RO–30Al₂O₃–40B₂O₃ glasses (in wt%), where R?=?Mg, Ca or Sr. The network structure of the glass is quantified in terms of the four-fold coordinated formers, atomic ring size, cross-link density, first-order stretching force constant and bulk modulus. It is found that network strength increases in the order Mg?>?Ca?> Sr. Structural changes of the glasses are deduced by relating the elastic moduli, the ratio of bond compression to experimental bulk modulus and ultrasonic attenuation to structural parameters and oxygen density.     

Study on the damping behaviour of eutectic high-entropy alloys with lamellar structures

ABSTRACT

Damping is the ability to reduce the energy produced by vibrations in a system. In this research, the eutectic high-entropy alloys (EHEAs), AlCo_xCrFeNi_2.1 (x?=?0.7, 1.0 and 1.5), are firstly studied for their damping behaviour. EHEA is a promising concept of high-entropy alloys. By combining the advantages of eutectic phases and HEAs, the EHEAs show better liquidity, castability and compositional homogeneity than conventional HEAs. Meanwhile, it can strike a great balance in mechanical strength and tensile ductility owing to the lamellar structures. The microstructures and crystal structure of two near-EHEAs are also studied. AlCo_0.7CrFeNi_2.1 is a hypo-eutectic HEA with primary body-centred cubic phases. AlCo_1.5CrFeNi_2.1 is a hyper-eutectic HEA with primary face-centred cubic phases. The results showed that these eutectic and near-eutectic alloys gave rise to greater tan δ values than conventional dual-phase HEAs, which might be attributed to their lamellar structures.     

Effect of crystallization on the surface area of porous Ni-based metallic glass foams

The change of the specific surface area in porous Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃ metallic glass (MG) upon partial crystallization was investigated. The observed increase in the surface area of the annealed Ni-based MG foams is due to the formation of homogeneously distributed Ni₁₀(Zr,Ti)₇ rod-shape intermetallic phases with nominal diameters around 250?nm and ～800?nm length on the surface of MG struts during the crystallization. For longer annealing, the specific surface area decreases again due to a change of the morphology of the crystals from rod-like to disc-like appearance, thus suggesting an optimum regime for increasing the specific surface area upon isothermal annealing at a given temperature.     

Structural heterogeneity in a binary Pd–Si metallic glass

A Pd₈₁Si₁₉ bulk metallic glassy rod with a diameter of 4.5 mm was produced by water quenching the fluxed alloy. Despite a negative heat of mixing between Pd and Si elements and very simple components constituting the binary Pd–Si glass-forming system, structural heterogeneity was induced either by slow cooling of a liquid or sub-T_g annealing of glassy ribbons. The sub-T_g annealing experiments evidenced that a more ordered amorphous phase emerged from the original glassy matrix. Our work provides an alternative way to tune the microstructure of metallic glasses by subsequent thermal treatment on an as-prepared single glassy phase.     

Effect of Al-Zr clusters on the thermal stability of Cu-Zr-rich Cu-Zr-Al bulk metallic glasses

The Gibbs free energy of formation, ?G^a, of the amorphous phase of Cu–Zr-rich Cu–Zr–Al bulk metallic glasses (BMGs) has been calculated over a broad composition region to re-evaluate their thermal stability, based on the efficient cluster packing model. It is found that Al–Zr clusters have an important effect on the thermal stability of the Cu–Zr–Al BMGs with the same Cu/Zr content ratio. The crystallisation of the BMGs involves crystallisation of both Al–Zr and Cu–Zr clusters. The results could be useful for predicting the thermal stability and understanding the underlying mechanism of crystallisation of multicomponent metallic glasses.     

From ultrafast to slow: Heating rate dependence of the glass transition temperature in metallic systems

When a solid crosses the glass transition, viscous flow sets in and the glass transforms into a supercooled liquid. The glass transition temperature exhibits a heating rate dependence which was previously observed to follow a Vogel–Fulcher–Tammann (VFT) equation. Here we report on a change in the heating rate dependence of the glass transition, determined by the distinct increase in the specific heat capacity, of a metallic glass. We combine standard techniques such as differential scanning calorimetry with recently developed ohmic heating techniques in order to cover seven orders of magnitude in heating rate. Contrary to previous reports, our results show that the change of the glass transition temperature cannot be described by a single VFT equation. Instead we find two distinct regimes which independently follow a VFT expression.