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51.
We report here the electrical resistivity of nanocrystalline perovskite-structured La–Sr manganites as a function of pressures up to 8?GPa, at room temperature. The nanocrystalline perovskite manganites were prepared by the sol–gel technique and found to have crystallite sizes of 12–18?nm. The pressure dependence of the electrical resistivity shows a first-order phase transition at 0.66(2)?GPa and a subtle phase transition between 3.5 and 3.8?GPa. The first-order transition at 0.66?GPa can be related to the transition from localized-electron to band magnetism.  相似文献   
52.

It is a common observation that in two-phase Ti-Al-based binary alloys, deformation of the gamma phase occurs by 1/2<110]-type ordinary dis-location activity and twinning associated with 1/6<112] type partials. In the present study the microstructure of a new Ti-Al-based alloy (Ti-47at.% Al-2at.%Mn-2at.%Nb+ 0.8 vol.% TiB2) with a duplex microstructure consisting of primary equiaxed gamma grains and lamellar alpha2+ gamma colonies was studied by transmission electron microscopy (TEM) after deformation at elevated temperatures. Planar stacking faults were found in the gamma laths. A detailed contrast analysis by TEM shows that these planar stacking faults lying on {111} planes are bound by all the fcc variants of the Shockley partial dislocations of type 1/6<121>, in contrast with the observations in stoichiometric binary TiAl alloys, where only 1/6<112]-type Shockley partials are found to be associated with the true twins. It is proposed that the addition of ternary and quaternary elements such as Mn and Nb promotes the other variants of the fcc-like dissociations (not common in L10structure) in the present alloy.  相似文献   
53.
Abstract

This paper presents a survey of the relationships among multiple indicators of perceived occupational stress, trait negative affectivity, and later mental and physical health symptoms, among 157 Australian public servants during organisational restructuring. It was hypothesised that individual differences in negative affectivity would inflate the relationships between perceived stress and later strain as assessed by health symptoms in the follow-up phase. The possible role of negative affectivity in moderating the stress-strain relationships was also investigated. Multiple regression analyses conducted with depressive and physical health outcomes separately indicate that the only significant predictors of depressive symptoms were negative affectivity and role insufficiency, whereas the significant predictors of physical health symptoms were role ambiguity, physical environment, and negative affectivity. None of the interaction terms involving occupational stress and negative affectivity was found to be significant Implications of the findings are discussed in the context of the research literature on work stress, particularly the role of negative affectivity in inflating the stress-strain relationship and indications for future research.  相似文献   
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There is an established inverse relationship between unemployment and psychological wellbeing. However, little is known about the processes that underlie this relationship. Using latent deprivation, conservation of resources, and social capital to form a theoretical framework, this study explored the relationship between the latent benefits associated with employment, family support, and financial strain. In a sample of 174 unemployed individuals, latent benefits were shown to partially mediate the relationship between family support and psychological well-being. Additionally, this mediation was moderated by financial strain, with latent benefits being more related to psychological well-being in those with greater financial strain. These findings provide guidance in understanding how to better address the needs that contribute to psychological well-being in those who are unemployed.  相似文献   
56.
This paper examines the spillover and crossover effects of emotional exhaustion on marital satisfaction for both employees and partners as well as on employee work–family conflict and partner family–work conflict. It investigates how the transmission of psychological strain from the workplace to the family domain mediates these relationships. In a sample of 226 employee–partner dyads from manufacturing, electronics, banking, service industries and public organizations, the results support the notion that employees' emotional exhaustion spawns negative strain in the home. More specifically, the results of spillover mediation analyses show the relationships between emotional exhaustion and employee marital satisfaction/work–family conflict in the home. In a crossover model, the results indicate that employee psychological strain mediates the relationships between emotional exhaustion and the marital satisfaction of partners/family–work conflict in partners. These findings provide supports for spillover and crossover models to investigate a direction for the effectiveness of emotional exhaustion on family issues. Theoretical and practical implications of the results are discussed, and directions for future research are offered.  相似文献   
57.
When occupational stressors, that is stress-producing environmental circumstances (SPECs) in the workplace, lead to anxiety, this anxiety is considered work-related strain. Social support is frequently recommended as a treatment of such strain, because it is expected to help in one of three ways: by directly reducing the anxiety, by interacting with SPECs to reduce the strength of their effects on anxiety, and by weakening the strength of the SPECs themselves. Future research on anxiety and social support in conjunction with work-related SPECs could shed new light on the relations among these three, variables by employing one or more of three approaches: designing investigations that allow stronger causal inference, testing hypotheses derived from theory, and examining potential cross-cultural differences in the nature of and reactions to social support.  相似文献   
58.
Variables thought to be associated with the magnitude of interrelationship observed among the elements in a system of social attitudes were investigated. Subjects (N = 753) were asked to respond to an inventory requesting self-report and background data. Several weeks later, Ss were given two forms of the Social Attitude Scale, a scale tapping the liberalism-conservatism domain. The results indicated that those Ss who reported recent changes in religious, moral, or political attitudes displayed a more highly interconnected system of liberal-conservative attitudes than those who did not. Variables relating to active participation in social affairs tended to be associated with higher levels of attitude system organization. Sex differences were observed, with men displaying higher levels of system organization than women. This relationship held even when participation rates were taken into consideration.  相似文献   
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This study examined the dynamic interplay among job demands, job control, and work self-determination in order to predict burnout dimensions. A three-way interaction effect was found between job demands, job control and work self-determination in predicting each dimension of burnout (emotional exhaustion, depersonalization, and personal accomplishment). Overall, results showed that job control moderates the unhealthy effects of job demands in predicting emotional exhaustion and depersonalization only for employees with high levels of work self-determination. In addition, job control increases the relation between job demands and the sense of personal accomplishment only for employees with high levels of work self-determination. These results are discussed in light of the Job Demand-Control model.  相似文献   
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