Mixed-valence impurity in a nanoscale particle

We consider a mixed-valence Anderson impurity with infinite U embedded into a small metallic particle. The nanosize of the system leads to discrete energy levels rather than to a continuum of energy eigenstates for the host. Using the Brillouin-Wigner approximation we show that the magnetic susceptibility, which arises from the van Vleck admixing of the magnetic configuration into the ground state, is only weakly affected by the finite spacing of energy levels, while the specific heat and the entropy display an exponential activation at low temperatures, that is have properties deviating from a Fermi liquid.     

Changes in electrical resistivity during isothermal annealing of thermally disordered Cu-15at.%Pd alloys

The changes in the electrical resistivity of thermally disordered Cu-15at.%Pd alloys during isothermal annealing at various temperatures has been investigated. The results obtained are compared with the changes in electrical resistivity calculated under the assumption that ordering proceeds only during isothermal annealing. The electrical resistivity in this alloy first increases and then decreases during isothermal annealing, and the magnitude of the increase decreases as the annealing temperature is lowered. A comparison between the results of measurement and calculation shows that the increase in electrical resistivity is considerably larger than that deduced at the early stage of ordering and occurs after the start of the ordering. An electron micrograph of a sample annealed at 643K for 42000s (11.7h) revealed that not only swirl-like antiphase domains but also fine domains with narrow stripes are present. Furthermore, it is shown that the electron diffraction pattern from the fine domains includes somewhat diffuse extra spots, which have never been observed in the L1 2 -type ordered structure, and that the fine domains disappear after a long anneal. These results indicate that the formation and disappearance of any quasistable phase influence the large increase and subsequent decrease in electrical resistivity during isothermal annealing.     

Dislocation motion in silicon: the shuffle-glide controversy revisited

Considering recently computed formation and migration energies of kinks on nondissociated dislocations, we have compared the relative mobilities of glide partial and shuffle perfect dislocations in silicon. We found that the latter should be more mobile over all the available stress range, invalidating the model of a stress driven transition between shuffle and glide dislocations. We discuss several hypotheses that may explain the experimental observations.     

Severe-to-mild wear transition at higher temperatures in Al-17Si-5Cu alloy after short-duration isothermal heat treatment

ABSTRACT

The wear behaviour of hypereutectic Al–Si alloys, which are suitable for use in automobile engines as a replacement for cast iron, has not been explored at higher temperatures. In the present study, the wear behaviour of Al-17Si-5Cu alloy (AR alloy) has been studied in as-received condition as well as after applying a short-duration isothermal heat treatment developed by the present research team. It was found that AR alloy exhibits severe wear, whereas heat-treated alloy (HT alloy) shows mild wear at higher temperatures (up to 300°C) at all applied loads. This severe-to-mild wear transition is addressed here.     

The state of order in Fe–Al studied by precession electron diffraction

Precession electron diffraction (PED) has been carried out on a fully ordered Fe–40at.%Al solid solution in order to explore its suitability for determining the state of order. The integrated intensity ratio of a superlattice reflection with respect to a fundamental reflection was measured as a function of the sample thickness and the results are well fitted by dynamical simulations. It is proposed that, in addition to conventional X-ray diffraction, PED may provide access to the state of order at microscopic and nanoscopic scales.     

3D shape and orientation of nanoscale Pb inclusions at grain boundaries in Al observed by TEM and STEM tomography

We have combined high-angle annular dark field/scanning transmission electron microscopy (HAADF-STEM) tomography with bright field (BF)-TEM tomography to characterize small inclusions of Pb at a grain boundary in Al. It was found that the shape of the grain boundary inclusions is more complex than previously thought. By using moiré fringes observed at some orientations of the specimen in a BF-TEM tomographic tilt series, we were able to determine the orientation of each grain, the axis and angle of misorientation of the grain boundary, and the facet planes of the grain boundary inclusions. The 3D shape of the inclusions was determined by merging this information with the HAADF-STEM tomography.     

Formation of plate-shaped Guinier–Preston zones during natural aging of an Al–Zn–Mg–Cu–Zr Alloy

Plate-shaped Guinier–Preston (G–P) zone formation in an Al–Zn–Mg–Cu–Zr alloy has been studied using transmission electron microscopy. The results provide, for the first time, direct evidence showing nucleation and growth of plate-shaped coherent G–P zones during natural aging.     

Microstructural development during transient directional solidification of a hypomonotectic Al–In alloy

Upward directional non-steady-state solidification experiments have been performed on a hypomonotectic Al–5.5?wt%In alloy. The alloy developed cellular as-solidified microstructure for tip growth rates, V _L, higher than 0.95?mm/s. The casting regions associated with V _L?<?0.95?mm/s were shown to be characterized by a microstructure formed by In droplets disseminated in the Al matrix. Tip growth rate and microstructural features, such as cell spacing and interphase spacing, have been experimentally determined. The experimental cell spacings have been compared with theoretical predictions furnished by the Hunt–Lu model. It was found that the experimental scatter lies below the minimum range of values theoretically predicted. Moreover, the experimental cell spacing evolution with V _L is characterized by a ?1.1 power law. The droplets’ interphase spacing, λ, is related to the growth rate by the Jackson–Hunt relationship (λ ² V _L?=?constant).     

Production of recrystallized nano-grains in a fine-grained Cu–Zn alloy

A fine-grained Cu–30%Zn alloy sheet was rolled at 77 K to induce ultrafine mechanical twins. Subsequent annealing of the rolled alloy at temperatures up to 543 K led to the uniform appearance of recrystallized ultrafine grains (UFGs), which contained numerous annealing twins. Average grain sizes of 150 ～ 300 nm were produced in this way. The formation of such UFGs during annealing is attributed to the high nucleus density associated with the fine initial grain size as well as to the high densities of mechanical twins and dislocations produced by cryorolling. The high driving force for recrystallization enabled the use of relatively low annealing temperatures, which limited the subsequent grain growth.     

Effect of Mg content on Portevin–Le Chatelier band strain in Al–Mg sheet alloys

Experimental measurements of stress drops and band strains in type-B Portevin–Le Chatelier (PLC) bands were carried out for 5xxx series Al–Mg sheets with Mg content between 1.8 and 4.5?wt%. While the stress drops increase with global strain, the band strain values in all the samples follow a common linear relationship with global strain. The results indicate that the type-B PLC band strain is independent of solute content at given strain rate.