Primary dendrite arm spacing during transient directional solidification of Al alloys with low redistribution coefficients

Particular analytical expressions based on a curve fitting on numerical results for primary dendritic growth have been proposed in the literature to encompass binary alloy systems whose redistribution coefficient (k ₀) approaches zero. To date, these expressions have not been checked against experimental results of transient solidification. The present study developed a comparative analysis between the theoretical predictions furnished by such expressions and results from transient solidification experiments with low k ₀ aluminum alloys. The analysis has shown that the proposed approach generally describes the primary dendritic spacing during solidification of Al–Sn alloys which are characterized by very low k ₀ values as well as by very large solidification ranges.     

Strain rate response of a Ni–Ti shape memory alloy after hydrogen charging

In this work, we investigate the susceptibility of Ni–Ti superelastic wires to the strain rates during tensile testing after hydrogen charging. Cathodic hydrogen charging is performed at a current density of 10?A/m² during 2–12?h in 0.9% NaCl solution and aged for 24?h at room temperature. Specimens underwent one cycle of loading-unloading reaching a stress value of 700 MPa. During loading, strain rates from 10^?6 to 5?×?10^?2?^?s^?1 have been achieved. After 8?h of hydrogen charging, an embrittlement has been detected in the tensile strain rate range of 10^?6 to 10^?4?s^?1. In contrast, no embrittlement has been detected for strain rates of 10^?3?s^?1 and higher. However, after 12?h of hydrogen charging and 24?h of annealing at room temperature, the embrittlement occurs in the beginning of the austenite-martensite transformation for all the studied strain rate values. These results show that for a range of critical amounts of diffused hydrogen, the embrittlement of the Ni–Ti superelastic alloy strongly depends on the strain rate during the tensile test. Moreover, it has been shown that this embrittlement occurs for low values of strain rates rather than the higher ones. This behaviour is attributed to the interaction between the diffused hydrogen and growth of the martensitic domain.     

Hydrogen-assisted damage in austenite/martensite dual-phase steel

For understanding the underlying hydrogen embrittlement mechanism in transformation-induced plasticity steels, the process of damage evolution in a model austenite/martensite dual-phase microstructure following hydrogenation was investigated through multi-scale electron channelling contrast imaging and in situ optical microscopy. Localized diffusible hydrogen in martensite causes cracking through two mechanisms: (1) interaction between {1?1?0}_M localized slip and {1?1?2}_M twin and (2) cracking of martensite–martensite grain interfaces. The former resulted in nanovoids along the {1?1?2}_M twin. The coalescence of the nanovoids generated plate-like microvoids. The latter caused shear localization on the specific plane where the crack along the martensite/martensite boundary exists, which led to additional martensite/martensite boundary cracking.     

High-strain induced reverse martensitic transformation in an ultrafine-grained Ti-Nb-Ta-Zr alloy

We report on a novel phenomenon, that is a high-strain-induced reverse martensitic transformation in an ultrafine-grained Ti–36Nb–2Ta–3Zr (wt.%) alloy processed by equal channel angular pressing (ECAP) at room temperature. Our results show that a martensitic transformation from body-centred cubic β matrix to orthorhombic α″ martensite occurs under low-strain ECAP conditions and that a large portion (~34%) of martensite transforms into a matrix phase (i.e. reverse martensitic transformation) with increasing ECAP strain to a high value of 4 (i.e. 6 passes) with a corresponding reduction in the α″-lath thickness and a refinement of grain size in the matrix phase.     

Impact of coherent and incoherent twin boundaries on the microhardness of annealed nanocrystalline Ni–W alloys

The microstructural evolution of nanocrystalline Ni–W alloys with annealing temperature and more specifically grain boundary (GB) character is investigated through several techniques and correlated with the hardening behaviour. It is shown that two distinct regions can be identified in relation to the annealing temperature and the microstructural evolution. At temperatures below 550 °C (Regime I), a small increase in grain size is observed and is accompanied by a significant hardening and an increase in the fraction of Σ3 incoherent twin boundaries. At temperatures above 550 °C (Regime II), the thermal stability is overcome and important grain growth occurs with a decrease in both the volumic fraction of GBs and the microhardness. It is suggested that the microhardness evolution during heat treatment is influenced by two opposing processes: an increase in the fraction of incoherent twin boundaries (hardening effect) and grain growth (softening effect). Both aspects are directly associated with the mean free path of mobile dislocations.     

The relationship between dynamic strain aging and serrated flow behaviour in magnesium alloy

The relationship between dynamic strain ageing (DSA) and serrated flow has been investigated via alternately switching strain rates at various temperatures in a Mg–3Nd–1Zn alloy. The results reveal that serrated flow is enhanced with decreasing strain rate and increasing temperature and tends to vanish, while the DSA continually intensifies as revealed by a higher flow stress even after the serration flow disappears. A mechanism is proposed, which could explain some abnormal deformation behaviour, such as a negative strain rate sensitivity and thermal hardening.     

Screening alloy electrocatalysts by combining magnetron sputtering and scanning electrochemical microscopy

A high-throughput approach for developing materials is revolutionizing the current trial-and-error mode with great potential for accelerating the process. Here, we propose a simple approach combining multitarget sputtering and scanning electrochemical microscopy for the screening of hydrogen evolution reaction (HER) electrocatalysts. The ternary Co–Ni–Cu system is used as to demonstrate the feasibility of the strategy. The optimized composition for a HER catalyst is determined to be Co₁₄Ni₅₃Cu₃₃.     

Changes in electrical resistivity during isothermal annealing of thermally disordered Cu-15at.%Pd alloys

The changes in the electrical resistivity of thermally disordered Cu-15at.%Pd alloys during isothermal annealing at various temperatures has been investigated. The results obtained are compared with the changes in electrical resistivity calculated under the assumption that ordering proceeds only during isothermal annealing. The electrical resistivity in this alloy first increases and then decreases during isothermal annealing, and the magnitude of the increase decreases as the annealing temperature is lowered. A comparison between the results of measurement and calculation shows that the increase in electrical resistivity is considerably larger than that deduced at the early stage of ordering and occurs after the start of the ordering. An electron micrograph of a sample annealed at 643K for 42000s (11.7h) revealed that not only swirl-like antiphase domains but also fine domains with narrow stripes are present. Furthermore, it is shown that the electron diffraction pattern from the fine domains includes somewhat diffuse extra spots, which have never been observed in the L1 2 -type ordered structure, and that the fine domains disappear after a long anneal. These results indicate that the formation and disappearance of any quasistable phase influence the large increase and subsequent decrease in electrical resistivity during isothermal annealing.