Comments on ‘A model of diffusion-induced grain boundary migration’ by T. K. Chaki

Abstract

Chaki (1988) has recently proposed a model for diffusion-induced grain boundary migration (DIGM). In his Letter he concluded that the interface energy of a grain boundary and the free energy of mixing are responsible for DIGM and, from the equations he derived, it was claimed that they can explain many DIGM experimental results. However, on examining his model closely there appear to be some fundamental difficulties. The following are comments on his Letter:

(1) In Chaki's calculation of ΔG_s he assumed that, after interface 1 had moved a distance δx, the radius of curvature of this interface increased from R to R + δx, which gives a surface energy drop of 2γV_m δx/R². However from many DIGM observations (for example Balluffi and Cahn (1981)) the curvature of a migrating boundary is increased rather then decreased, that is, the surface free- energy term actually prevents a grain boundary from migrating rather than helping it!

(2) Chaki considered ΔG_cryst during the migration of interface 2. It is also necessary to consider AGcrys, during the migration of interface 1, since within the migration distance δx the structure is changed from a crystalline structure to a grain boundary core structure. ΔG_m should also be considered during the migration of interface 2 since the concentration of the area swept by interface 2 will not be the same as that of a grain boundary core.     

Electromechanical behavior of single-walled carbon nanotube thin films

Carbon nanotubes have been intensively studied owing to their great potential in nanoelectronics and nanomechanical devices. Recently, experimental results have shown that single-walled carbon nanotubes (SWCNTs) change their electronic properties when subjected to strain. In this study, the electromechanical characteristics of SWCNT networks were investigated for the application of printable strain sensors on flexible substrates. SWCNT films were formed on plastic substrates of poly(ethylene terephthalate) using a spray process. In this manner, we were able to control the transparency and obtain uniform electrical properties of the films. The films are isotropic on account of the random orientation of bundles of SWCNTs. Experimental results showed a nearly linear change in the resistance across a film when it was subjected to tensile strain, even in the inelastic range of the flexible substrate. The results demonstrate the potential use of SWCNT films for highly sensitive printable strain sensors on a macroscale.     

Crystallization behaviour of Al-based amorphous alloy and nanocomposites by rapid quenching

The microstructure and crystallization behaviour of melt-spun Al₈₈Ni₉Ce₂Fe₁ amorphous alloy and nanophase composites have been studied by means of X-ray diffraction, transmission electron microscopy and scanning and isothermal calorimetry. The diffraction patterns from Al₈₈Ni₉Ce₂Fe₁ amorphous alloys are diffuse, indicating a basically amorphous structure but contain two rings presumed to be associated with quenched-in nuclei. In the cases of Al₈₈Ni₉Ce₂Fe₁ nanophase composites, nanoscale precipitated particles are homogeneously dispersed in an amorphous matrix, and the crystallite diameter and volume fraction are sensitive to quenching conditions. During thermal crystallization, a two-step phase transformation occurs in the amorphous alloy and nanocomposites, which is characterized by a diffusion-controlled precipitation of nanoscale Al particles and the growth of a Al₃(Ni, Fe) nanophase prior to a Al₁₁Ce₃ nanophase. This study gives insight into structure-control for obtaining nanophases dispersed in an amorphous matrix by rapid quenching.     

Cue competition effects in the planarian

The learning abilities of planarian worms (Dugesia tigrina) were assessed by using a number of Pavlovian conditioning paradigms. Experiment 1 showed that planaria were susceptible to basic conditioning in that they readily developed a conditioned response to a change in ambient luminance when it was consistently paired with an electric shock over a number of trials. In Experiment 2, the change in luminance was presented in a compound with a vibration stimulus during conditioning. Subsequent tests revealed poor conditioning of the elements compared with control groups in which the animals were conditioned in the presence of the elements alone, an instance of overshadowing. In Experiment 3, pre-training of one of the elements before compound conditioning resulted in blocking of learning about the other element. These results add to other studies that have reported cue competition effects in animal species belonging to different phyla (chordate, mollusk, arthropod), suggesting that learning in these phyla could be ruled by similar principles. The results are discussed adopting an evolutionary-comparative approach.     

Burnout and its relations with basic psychological needs and motivation among athletes: A systematic review and meta-analysis

ObjectivesThe present study is a review on studies about the relationships between the three basic psychological needs/motivational regulations (i.e., amotivation, controlled regulation, extrinsic autonomous regulation, and intrinsic motivation) and burnout.DesignA systematic review and meta-analysis.MethodStudies were identified through five electronic databases and manual search using combinations of three groups of keywords. Three inclusion criteria were then used to screen the searched articles.ResultsEighteen studies met the inclusion criteria and these studies varied considerably in terms of their study characteristics (e.g., characteristics of participants, study designs, and outcome measures). The results also showed that the three basic psychological needs, intrinsic motivation, extrinsic autonomous regulation, and amotivation had small to large effects on predicting global burnout and its three dimensions. However, controlled regulation showed no or weak correlations with the burnout subscales.ConclusionsSelf-determination theory was generally supported in explaining athlete burnout.     

The Blood of Jesus in revival theology and the contemporary Church with particular reference to the East African Revival and Roy Hession

One of the most common phrases heard in testimony, preaching, and song during the East African Revival (EAR) was the phrase ‘The Blood of Jesus Christ’. Taken from a rich biblical heritage, this phrase encapsulates a wide range of ideas concerning the work of the cross and the power of forgiveness in a believer's life. Whilst, as will be noted, the use of The Blood has been common to many revivals, this article examines especially the theology behind this phrase by looking at the most prominent of the EAR authors – Roy Hession. It investigates seven different applications of The Blood in a believer's life: The Blood as a testament that sin is forgiven, The Blood as cleansing the conscience, The Blood as victory over despair, The Blood as the remover of shame, The Blood as washing away sin, The Blood as the gateway of the Holy Spirit, and finally The Blood as the source of true fellowship. The theology of The Blood has a long history of use in the Church but it also comes with difficulties. To this end the article will investigate the legitimacy of the practice often found in Africa and some Pentecostal circles of invoking The Blood as protection against the demonic. The article closes by considering the reasons why speaking of The Blood in church can be uncomfortable yet is paradoxically of vital importance to revival.     

Opinions From Others Like You: The Role of Perceived Source Similarity

A theoretical framework is proposed to test the influence of opinions of other consumers, based on perceived similarity, in two contexts. The perceived similarity of the source may be diagnostic for consumers who are concerned about mispurchase. Experiment 1, therefore, compared the effects of ads featuring a consumer versus an expert as an endorser, with participant use status as a moderator that may affect concerns about mispurchase. Potential product users rated the consumer endorser higher on perceived similarity, which increased ad credibility and resulted in better ad and brand attitudes. Experiment 2 compared the effects of information about a product delivered on a consumer blog with that of information from the advertiser's official Web site, with concern about mispurchase as a moderator. More concerned consumers rated the blogger higher than the advertiser on perceived similarity, leading to greater information credibility and more favorable attitudes toward the blog and the product.     

Multilevel models for multiple-baseline data: modeling across-participant variation in autocorrelation and residual variance

Multilevel models (MLM) have been used as a method for analyzing multiple-baseline single-case data. However, some concerns can be raised because the models that have been used assume that the Level-1 error covariance matrix is the same for all participants. The purpose of this study was to extend the application of MLM of single-case data in order to accommodate across-participant variation in the Level-1 residual variance and autocorrelation. This more general model was then used in the analysis of single-case data sets to illustrate the method, to estimate the degree to which the autocorrelation and residual variances differed across participants, and to examine whether inferences about treatment effects were sensitive to whether or not the Level-1 error covariance matrix was allowed to vary across participants. The results from the analyses of five published studies showed that when the Level-1 error covariance matrix was allowed to vary across participants, some relatively large differences in autocorrelation estimates and error variance estimates emerged. The changes in modeling the variance structure did not change the conclusions about which fixed effects were statistically significant in most of the studies, but there was one exception. The fit indices did not consistently support selecting either the more complex covariance structure, which allowed the covariance parameters to vary across participants, or the simpler covariance structure. Given the uncertainty in model specification that may arise when modeling single-case data, researchers should consider conducting sensitivity analyses to examine the degree to which their conclusions are sensitive to modeling choices.