Electrical conductivity of Nd and Ce co-doped Gd2Zr2O7 ceramics

In this study, (Gd_{1? x} Nd _x )₂(Zr_{1? x} Ce _x )₂O₇ (0 ≤ x ≤ 0.5) ceramics have been prepared by pressureless sintering at 1973 K to investigate the influence of Nd and Ce co-doping on their electrical conductivity. The electrical conductivity of the ceramics was investigated by impedance spectroscopy measurements from 723 to 1173 K over the frequency range of 20 Hz to 2 MHz in air. The measured values obey the Arrhenius relation. For each composition, the grain conductivity gradually increases with increasing temperature from 723 to 1173 K. At a given temperature, it gradually decreases with increasing neodymium and cerium contents from x = 0 to 0.3; thereafter, the grain conductivity exhibits a slight increase with further increasing neodymium and cerium contents up to x = 0.5.     

Fabrication of opal-like thin films

A process is described for the fabrication of opal-like thin films by controlling a solid–liquid interface moving at an inclined glass substrate. A special airflow is adopted to control solvent evaporation. SEM images and photographs show that the films, composed of polystyrene spheres, are coloured, flat, uniform, packed multilayers, and are well arrayed over a large scale. The ordered domains range in size from 10 to 15?µm. The spheres in suspension crystallized, caused by an intense interaction between the spheres on the boundary between the suspension and the substrate. A wide photonic band gap is observed in the normal-incidence transmission spectra of the films fabricated by this method. Cracks and defects in the films are examined and discussed.     

Thermodynamic fluctuations in magnetic states: Fe3Pt as a prototype

To understand the Invar anomalies, such as negative thermal expansion and spontaneous magnetization, we have applied our recently developed thermodynamic framework for a system with itinerant-electron magnetism to the ordered Fe₃Pt. The framework has coherently predicted the finite temperature intermixing between the fully ferromagnetic (FM) configuration and the spin-flipping configurations (SFCs). We have also discovered a tri-critical point at which a high-temperature second-order phase transition, between the fully ordered FM phase and the paramagnetic phase which is disordered due to SFCs, becomes first order at low temperatures.     

Determination of the depth distribution of subsurface damage during polishing of alumina

High-resolution grazing-incidence parallel-beam powder diffraction has been used to detect the subsurface damage below alumina surfaces subjected to polishing with cerium oxide or diamond. Despite very significant evolution of the surface morphology, no changes in the subsurface strains were observed over a 20min period of polishing with ceria. For both polishing materials, the variation with angle in the full-width at half-height maximum was successfully modelled by a strain distribution that fell exponentially with increasing depth. Although the surface amplitude and depth dependence parameter are coupled, we have been able to place upper limits on the depth to which the damage extends. Under realistic assumptions, the depth of damage induced by 1µm diamond paste is comparable with that from 3µm ceria polish.     

Growth orientation of one-dimensional silicon nanowires prepared by thermal evaporation

One-dimensional silicon nanowires have been grown by thermal evaporation and their growth orientations determined by transmission electron microscopy studies. The nanowires, which are often highly curved in morphology and heavily twinned in microstructure, are crystallographically separated into several sections, each with a characteristic crystallographic orientation along the wire axis. Straight nanowires, or straight sections in a curved nanowire, are found to have non-unique crystallographic orientations when {111} twinning occurs.     

Survey of plateau behaviour in the cyclic stress-strain curve of copper single crystals

Experimental results relating to the plateau behaviour in the cyclic stress-strain (CSS) curve of copper single crystals located on different sides of the stereographic triangle are summarized. Unlike the situation for single-sliporiented crystals, the crystallographic orientation has a strong effect on the plateau behaviour in the CSS curves of double- and multiple-slip-oriented crystals. The existence or non-existence of a plateau in the CSS curves, as well as the corresponding plateau stress amplitude, depend not only on the modes and intensities of dislocation interactions among slip systems operating in the crystals but also on the slip deformation characteristics associated with crystal orientations. The plateau region in CSS curve disappears only when multiple slip plays a determining role during cyclic deformation.     

Mechanical-milling-induced amorphization of Se: A crystallite destabilization model

Complete solid-state amorphization has been realized in elemental Se by means of mechanical milling of crystalline Se powder. Quantitative X-ray diffraction and thermal analyses were employed to characterize the amorphization process and indicated that the amorphization onset corresponds to a critical crystallite size and a drop in microstrain. During the major amorphization process, the remaining crystallite size remains unchanged with a constant lattice expansion. A new kinetics model of crystallite destabilization is proposed for the solid-state amorphization which satisfactorily explains the experimental observations.     

A phase-field model for deformation twinning

We propose a phase-field model for modeling microstructure evolution during deformation twinning. The order parameters are proportional to the shear strains defined in terms of twin plane orientations and twinning directions. Using a face-centered cubic Al as an example, the deformation energy as a function of shear strain is obtained using first-principle calculations. The gradient energy coefficients are fitted to the twin boundary energies along the twinning planes and to the dislocation core energies along the directions that are perpendicular to the twinning planes. The elastic strain energy of a twinned structure is included using the Khachaturyan's elastic theory. We simulated the twinning process and microstructure evolution under a number of fixed deformations and predicted the twinning plane orientations and microstructures.     

The orientation and temperature dependences of dislocation velocity in Ni 3 Al single crystals

The average velocities of screw dislocations in Ni 3 Al single crystals have been directly measured as a function of resolved shear stress (RSS) and orientation in the temperature domain of the flow stress anomaly using the etch-pit technique. The velocity was found to be extremely sensitive to the RSS in all cases. In contrast with ordinary metals, the screw dislocation velocities in Ni 3 Al show anomalous behaviour; under a constant RSS, the velocities decrease dramatically with increasing temperature. Furthermore, the velocities and the tension-compression asymmetry of the velocities depend on the orientation of applied stress.     

Interactions of persistent slip bands with a grain boundary on the common primary slip plane in a copper bicrystal

In this letter, the dislocation patterns on the common primary slip plane in a fatigued \[1-34]-\[182-7] copper bicrystal with a Sigma=19b grain boundary (GB) have been investigated using the electron channelling contrast technique in a scanning electron microscope. The results show that the two-phase dislocation structure, such as veins and persistent slip band (PSB) walls, embedded within veins, can be clearly seen on the common primary slip plane. In particular, the interactions of PSBs with the GB are clearly revealed. It is found that there are three kinds of interaction mode between the GB and the dislocations during cyclic deformation, and those are discussed. It is suggested that the dislocations carried by PSBs cannot transfer through the GB continuously even though the bicrystal has a common primary slip plane and its surface slip bands are continuous across the GB.