High-pressure phase transition and lattice dynamics of rock-salt and FeSi-type phases of MgS

A phase transition of MgS under high pressure is investigated using a first-principles method. It is found from energy-volume calculations that the rock-salt (B1) phase of MgS transforms into a FeSi-type (B28) phase at 143?GPa. The calculated ground-state parameters in the B1 phase are in excellent agreement with available experimental and theoretical data. Ab initio phonon calculations are also performed to investigate the structural behaviour of MgS under high pressure. An unstable transverse acoustic mode and a phase transition from B1 to B28 phase at ~143.7?GPa driven by this soft mode are predicted. The B28 structure of MgS is stable up to 350?GPa according to lattice dynamics calculations.     

Exaggerated grain growth and improved properties of Y1 Ba2 Cu3 O7-x by Pt addition

Abstract

Superconducting and mechanical properties of Y₁ Ba₂Cu₃ O₇ can be improved by the use of sintering aids. 0·2 wt% of finely divided laser-ablated platinum powder has been mixed with the parent material and produced a dense product with exaggerated grain growth and improved critical current density and Vickers hardness. At higher concentrations of platinum, while the mechanical properties are further improved, the increased density appeared to inhibit access of oxygen for the tetragonal to orthorhombic phase transition and the current density was reduced.     

Electrical conductivity of Nd and Ce co-doped Gd2Zr2O7 ceramics

In this study, (Gd_{1? x} Nd _x )₂(Zr_{1? x} Ce _x )₂O₇ (0 ≤ x ≤ 0.5) ceramics have been prepared by pressureless sintering at 1973 K to investigate the influence of Nd and Ce co-doping on their electrical conductivity. The electrical conductivity of the ceramics was investigated by impedance spectroscopy measurements from 723 to 1173 K over the frequency range of 20 Hz to 2 MHz in air. The measured values obey the Arrhenius relation. For each composition, the grain conductivity gradually increases with increasing temperature from 723 to 1173 K. At a given temperature, it gradually decreases with increasing neodymium and cerium contents from x = 0 to 0.3; thereafter, the grain conductivity exhibits a slight increase with further increasing neodymium and cerium contents up to x = 0.5.     

Electropulsing-induced strengthening of steel at high temperature

Electropulsing usually promotes a metastable phase to evolve towards its equilibrium state. This work reports an alternative case, where electropulsing promotes the decomposition of the stable δ-phase in duplex stainless steel at high temperature. This decomposition enables both the γ-phase and the σ-phase in the steel to survive and hence to strengthen it at high temperature. The hardness of the quenched sample with electropulsing treatment is 49.4% higher than that without electropulsing treatment. A fundamental understanding of the observation is developed.     

Very high temperature creep behavior of a single crystal Ni-based superalloy under complex thermal cycling conditions

Very high temperature thermal cycling has been performed on the single crystal superalloy MC2 to evaluate the effect of periodic overheating on creep behavior. The experiments consist of alternately performing 1 min dwell time at 1100°C and 1150°C for every 15 min during creep test at 1050°C/120 MPa. Both thermal cycling and prior γ′-rafting appear to be deleterious to the cyclic creep properties. The observed non-isothermal creep behavior is correlated with γ′-dissolution/coalescence processes, especially during overheatings where γ′ micro-rafts seem to play a significant role.     

A continuum model of deformation-twin dominant crack growth in fcc metals

A continuum model is proposed to address the effects of deformation twinning on ductile versus brittle fracture behaviour of low strain-hardening fcc metals after exhaustion of work hardening. Instead of discrete twin nucleation, a number of partial dislocations ahead of the tip exhibit themselves as twins at the final stage of failure. The crack-tip plasticity is amended for deformation twinning and the constitutive form for the flow strength of arrays of twins of the same sign is expressed as a second gradient of microrotation for their coupling. The twins not only shield the crack tip but also inhibit further dislocation emission to form a dislocation-free zone (DFZ) in the immediate vicinity of the tip. The stress fields induced by deformation twinning lead to fracture branching under Mode I loading. The model is borrowed from the conceptual model presented by Beltz et al. [Acta Mater. 44 3943 (1996)], based on the equivalence of the stresses derived from twin-based crack-tip plasticity, macroscopic plasticity and elasticity on the DFZ boundary. The DFZ size and the crack-tip shielding ratio are obtained, as well as the branching angle. The branching angle is noteworthy for low strain-hardening metals. A strong dependence of the toughness on intrinsic surface energy and hardening index is examined. The toughness reduction due to crack-tip constraints and in the ductile-to-brittle transition (DBT) temperature region is revisited and found to be in agreement with experimental observations and available predictions.     

Determination of the depth distribution of subsurface damage during polishing of alumina

High-resolution grazing-incidence parallel-beam powder diffraction has been used to detect the subsurface damage below alumina surfaces subjected to polishing with cerium oxide or diamond. Despite very significant evolution of the surface morphology, no changes in the subsurface strains were observed over a 20min period of polishing with ceria. For both polishing materials, the variation with angle in the full-width at half-height maximum was successfully modelled by a strain distribution that fell exponentially with increasing depth. Although the surface amplitude and depth dependence parameter are coupled, we have been able to place upper limits on the depth to which the damage extends. Under realistic assumptions, the depth of damage induced by 1µm diamond paste is comparable with that from 3µm ceria polish.     

Growth orientation of one-dimensional silicon nanowires prepared by thermal evaporation

One-dimensional silicon nanowires have been grown by thermal evaporation and their growth orientations determined by transmission electron microscopy studies. The nanowires, which are often highly curved in morphology and heavily twinned in microstructure, are crystallographically separated into several sections, each with a characteristic crystallographic orientation along the wire axis. Straight nanowires, or straight sections in a curved nanowire, are found to have non-unique crystallographic orientations when {111} twinning occurs.     

Multiple phase transitions in CuO

Electrical resistivity, thermoelectric power, magnetic susceptibility and calorimetric measurements were carried out on a single crystal of CuO. In addition the two known antiferromagnetic transitions between 210K and 230K, a new phase transition around 160K was found in CuO. The experimental results show that this new transition is related to changes in the electronic state of CuO.     

Survey of plateau behaviour in the cyclic stress-strain curve of copper single crystals

Experimental results relating to the plateau behaviour in the cyclic stress-strain (CSS) curve of copper single crystals located on different sides of the stereographic triangle are summarized. Unlike the situation for single-sliporiented crystals, the crystallographic orientation has a strong effect on the plateau behaviour in the CSS curves of double- and multiple-slip-oriented crystals. The existence or non-existence of a plateau in the CSS curves, as well as the corresponding plateau stress amplitude, depend not only on the modes and intensities of dislocation interactions among slip systems operating in the crystals but also on the slip deformation characteristics associated with crystal orientations. The plateau region in CSS curve disappears only when multiple slip plays a determining role during cyclic deformation.