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861.
The energetic driving force and resistance for shearing and cracking in metallic glasses (MGs) are quantitatively evaluated. A universal thermodynamic criterion is proposed for better understanding the intrinsic correlations between fracture toughness and Poisson’s ratio, the competitions between various deformation modes and the ductile-to-brittle transition in MGs and other materials. A new cooperation parameter δ is also introduced to depict quantitatively the relative propensity of shearing versus cracking. This work could provide insights into the long-standing issues of deformation mechanisms of glassy materials, and be helpful in searching for ductile and tough MGs. 相似文献
862.
Gong Li Y.P. Gao Z.H. Chi J. Liu T. Zhang R.P. Liu 《Philosophical Magazine Letters》2013,93(7):543-551
A 52 m drop tube has been used to solidify bulk-glass-forming Zr41Ti14Cu12.5Ni10Be22.5 alloy. Glassy balls with different sizes solidified from the droplets whose structural features, glass-transition behaviour and crystallization kinetics have been investigated. The results indicate that the apparent activation energies of the glass transition and main crystallization reaction are significantly different from those of samples prepared by water quenching. The structural difference between the two types of glassy specimen is revealed by compression studies and in situ energy-dispersive X-ray diffraction. The results are important for understanding the structural features of bulk-forming glasses. 相似文献
863.
The effects of irradiation with electrons having energies in the range 0.7–1.7 MeV on the dark conductivity and the network of hydrogenated amorphous silicon (a-Si:H) thin films have been studied. The dark conductivity measurements show that electron irradiation leads to a degradation in the dark conductivity, with the degradation being greater at lower electron energies. The Raman results suggest that the irradiation induces structural defects in the a-Si:H films, with the lower energy electrons producing more disorder in the amorphous network. 相似文献
864.
In this study, bulk nanostructured composite Cu60Fe40 alloy is prepared by a combustion synthesis technique. The prepared Cu60Fe40 alloy consists of Cu(Fe) solid solution and Fe(Cu) solid solution phases. The large-scaled compositional segregation in the Cu-rich and Fe-rich phases is not observed, respectively. A few micron-sized dendrite (Fe(Cu) solid solution) is embedded into the nanostructured matrix (Cu(Fe) solid solution). The grain size of the matrix is in the range 50–300?nm. The yield and fracture strength of the Cu60Fe40 alloy are 540 and 1050?MPa, respectively, and the fracture strain obtained from the compression test is about 20.9%. The Cu60Fe40 alloy displays notable work hardening in the compressive deformation. 相似文献
865.
Solubility criterion for sequential disordering in metal-metal multilayers upon solid-state reaction
An n-body Ni-Ti potential is derived and applied in a molecular dynamics simulation to study the maximum supersaturated solubility of the terminal solid solutions and solid-state reaction in a Ni/Ti bilayer. It reveals that during interfacial reaction of the Ni/Ti bilayer the Ti lattice reaches its maximum solubility by dissolving Ni earlier than Ni does through dissolution of Ti, which results in a sequential disordering of first Ti and then Ni, although Ti has a higher melting point than Ni. In the Ni-Zr, Ni-Mo and Ni-Ta systems, however, the Ni lattice collapses more rapidly because it reaches a maximum solubility earlier than its partners, which have higher melting points than Ni. A solubility criterion is thus relevant for all the above cases; the lower the maximum solid solubility the less stable is the lattice of the metal upon solid-state reaction. 相似文献
866.
The effect of the image force on the Peierls stress (τ p ) of a screw dislocation below a free surface is studied via a self-consistent semidiscrete variational Peierls–Nabarro model. The consequence of reduction in elastic energy and increase in stacking fault energy by the presence of the free surface is found to additively increase the Peierls stress (τ p ). This model gives a physical interpretation of the same tend observed in a recent molecular dynamic study, while previous continuum analysis predicted the opposite. 相似文献
867.
Ferroelectric (FE) materials directly convert electrical energy to mechanical energy and are critical to applications such as sensors, transducers, and actuators. The giant electromechanical response is the manifestation of the critical point between the first-order and second-order ferroelectric–paraelectric (FE–PE) transitions. For the simple classic FE lead titanate (PbTiO3), it is commonly accepted that there is a critical point in the temperature–pressure phase diagram separating the first- and second-order FE–PE transitions at zero electric field. Here, we show that the FE-PE transition in PbTiO3 is second-order at zero electric field. We introduce the concept of the invariant critical points (ICP) among three phases, representing the stability of the PE phase with respect to two FE phases in a three-dimensional electric field-pressure-temperature phase diagram of PbTiO3. It is pointed out that the electromechanical response near ICPs is larger than that near the line of critical end points (LCEPs) between two phases. 相似文献
868.
We study shear vibration of a rotated Y-cut quartz crystal plate carrying an array of microbeams with their bottoms fixed to the top surface of the plate. The beams undergo flexural vibrations when the plate is in shear motion. The plate is modeled by the theory of anisotropic elasticity. The beams are modeled by the Euler–Bernoulli theory for beam bending. A frequency equation that determines the resonant frequencies of the structure is derived. An analytical solution on beam-induced frequency shift is obtained using a perturbation procedure. It is shown that the frequency shift may be used to measure geometric/physical properties of the beam array. A vibrating crystal plate carrying a beam array may also be considered for application as an ultrasonic brush. 相似文献
869.
In piezoelectric nanocomposites, surface/interface plays an important role in determining the size-dependent behavior of media. Within the framework of couple stress, the effect of surface/interface around a nano-hole on the anti-plane electro-mechanical behavior is examined. By introducing a surface/interface model, the stress and electric displacement effects on the size-dependent behavior are both considered. The governing equations in piezoelectric materials are decoupled into the classical ones. The displacement and electric potential are expressed by Bessel functions. By satisfying the boundary conditions around the hole with the interface/surface effect, the expanded coefficients are obtained. Through analysis, it is shown that the mechanical and electrical fields drastically depend on the relative size of the hole with respect to the characteristic length of the material. The effects of couple stresses on the stress and electric field are also addressed. Comparison with the existing results is also given. 相似文献
870.
The interaction between a dislocation and an elliptical hole in icosahedral quasicrystals is considered. An explicit expression for the complex potential is derived using the extended Stroh formalism. Based on the conformal mapping method and a perturbation technique, closed-form solutions are obtained. The field intensity factors at a crack tip and the image forces on the dislocation arising from the crack are calculated. The effects of phonon–phason elastic coupling on the mechanical behavior are also observed. 相似文献