The Relationship Between Blood Lead,Bone Lead and Child Intelligence

We report associations between serial measures of blood lead and intelligence in children age 10–12 years, half heavily exposed to lead from the prenatal period onward, and half relatively unexposed. For a subsample, we examine bone lead-IQ associations, comparing them with blood lead associations. Both blood and bone lead levels were associated with intelligence decrements, small relative to the contribution of social factors. For each doubling of Tib-Pb, Full Scale, Performance, and Verbal IQ decreased by an estimated 5.5, 6.2, and 4.1 points, respectively. Bone lead-IQ associations were stronger than those for blood lead, which nonetheless provide robust analogues. Current BPb, easy to obtain, provides a useful means for assessing Pb exposure/IQ associations.     

High-pressure phase transition and lattice dynamics of rock-salt and FeSi-type phases of MgS

A phase transition of MgS under high pressure is investigated using a first-principles method. It is found from energy-volume calculations that the rock-salt (B1) phase of MgS transforms into a FeSi-type (B28) phase at 143?GPa. The calculated ground-state parameters in the B1 phase are in excellent agreement with available experimental and theoretical data. Ab initio phonon calculations are also performed to investigate the structural behaviour of MgS under high pressure. An unstable transverse acoustic mode and a phase transition from B1 to B28 phase at ~143.7?GPa driven by this soft mode are predicted. The B28 structure of MgS is stable up to 350?GPa according to lattice dynamics calculations.     

Electrical conductivity of Nd and Ce co-doped Gd2Zr2O7 ceramics

In this study, (Gd_{1? x} Nd _x )₂(Zr_{1? x} Ce _x )₂O₇ (0 ≤ x ≤ 0.5) ceramics have been prepared by pressureless sintering at 1973 K to investigate the influence of Nd and Ce co-doping on their electrical conductivity. The electrical conductivity of the ceramics was investigated by impedance spectroscopy measurements from 723 to 1173 K over the frequency range of 20 Hz to 2 MHz in air. The measured values obey the Arrhenius relation. For each composition, the grain conductivity gradually increases with increasing temperature from 723 to 1173 K. At a given temperature, it gradually decreases with increasing neodymium and cerium contents from x = 0 to 0.3; thereafter, the grain conductivity exhibits a slight increase with further increasing neodymium and cerium contents up to x = 0.5.     

High-temperature creep associated with the climb of extended dislocations subjected to chemical stresses

The effect of chemical stresses upon the relation between extended dislocations and high-temperature creep in a thin plate has been investigated. The critical stress needed for the contraction of extended jogs and its effect on the creep rate are obtained. The results indicate that the critical stress needed for the contraction increases with decreasing stacking fault energy (SFE). However, creep occurs more easily with increasing SFE and increasing angle of the Burgers vector to the dislocation line, as well as with the concentration of any diffusing atoms.     

Thermodynamic fluctuations in magnetic states: Fe3Pt as a prototype

To understand the Invar anomalies, such as negative thermal expansion and spontaneous magnetization, we have applied our recently developed thermodynamic framework for a system with itinerant-electron magnetism to the ordered Fe₃Pt. The framework has coherently predicted the finite temperature intermixing between the fully ferromagnetic (FM) configuration and the spin-flipping configurations (SFCs). We have also discovered a tri-critical point at which a high-temperature second-order phase transition, between the fully ordered FM phase and the paramagnetic phase which is disordered due to SFCs, becomes first order at low temperatures.     

Sol-gel-hydrothermal growth of oxide thin films at low temperatures

Lead zirconate titanate (PZT) (Pb(Zr_0.52Ti_0.48)O₃) and barium titanate (BaTiO₃) thin films have been successfully prepared using a novel sol-gel- hydrothermal (SG-HT) technique at low temperatures, which involves a combination of the conventional sol-gel process and a hydrothermal method. Highly (111)-oriented PZT thin films with a single perovskite phase and polycrystalline BaTiO thin films with well developed crystallites were obtained at a processing temperature as low as 160⁰C. The microstructural characteristics demonstrate that the SG-HT-derived PZT and BaTiO₃ thin films with good crystallinity and surface morphology are converted from the amorphous phase to the desired perovskite phase on platinum-coated and bare silicon substrates at a low processing temperature of 100-200 C. These results suggest that the SGHT technique, which is of great significance because of its low processing temperature, will become a potential and promising process for fabricating PZT, BaTiO₃ and other oxide thin films.     

Stemming the tide: Predicting women engineers' intentions to leave

This investigation adapts and extends the Social Cognitive Career Theory (SCCT) by integrating it with central constructs from turnover theory. The extended model proposes that domain specific self-efficacy and outcome expectations predict job satisfaction and organizational commitment — the two key job attitudes that have been established as influential predictors of turnover cognitions and behaviors. Further, we proposed that one form of organizational supports, specifically developmental opportunities at work, are sources of self efficacy and outcome expectations, and that the relationship between organizational supports and job attitudes is mediated by self-efficacy and outcome expectations. The proposed model was tested on a national sample of 2,042 women engineers. Overall, the results provided support for our newly developed model. Implications for theory, research, and practice are discussed.     

Need Satisfaction Supportive Game Features as Motivational Determinants: An Experimental Study of a Self-Determination Theory Guided Exergame

Empirical studies have validated that basic needs satisfaction supported by video game play predicts motivation and engagement outcomes. However, few studies specifically manipulated game features for each of the three basic needs specified in the self-determination theory (SDT) to examine how the game features impact players' need satisfaction and game experience. The current study employed an in-house developed exergame and manipulated the game features in a 2 (autonomy-supportive game features: on vs. off) × 2 (competence-supportive game features: on vs. off) experiment to predict need satisfaction, game enjoyment, motivation for future play, effort for gameplay, self-efficacy for exercise using the game, likelihood of game recommendation, and game rating. The manipulated game features led to the corresponding need satisfaction. Manipulated autonomy-supportive and competence-supportive game features had main effects on most motivation and engagement outcomes. Need satisfaction of autonomy and need satisfaction of competence were both found to be mediators for the relationships between the game features and the motivation and engagement outcomes. The findings add evidence to support the underlying mechanism postulated by SDT for media enjoyment and motivation as well as the emerging entertainment research conceptualizing enjoyment as need satisfaction. The findings also have practical implications for intervention effort that intends to capitalize the motivational pull of video games.     

Can Toddlers Learn Vocabulary from Television? An Experimental Approach

This study was inspired by the rise in television targeting toddlers and preverbal infants (e.g., Teletubbies, Baby Mozart). Overall, we investigated if very young children who are in the early stages of language acquisition can learn vocabulary quickly (fast map) from television programs. Using a fast mapping paradigm, this study examined a group (n = 48) of toddlers (15–24 months) and their ability to learn novel words. Utilizing a repeated measures design, we compared children's ability to learn various novel words in 5 different conditions. These included the presentation and identification of a novel word by an adult speaker via live presentation when the toddler was attending (i.e., joint reference), an adult via live presentation when the toddler was not attending, an adult speaker on television, and an edited clip from a children's television program (Teletubbies). Overall, the toddlers were most successful in learning novel words in the joint reference condition. They were significantly less successful in the children's program condition. Furthermore, there was a significant interaction between age and condition on children's performance. Both younger (15–21 months) and older (22–24 months) participants identified the target objects when they were taught the novel word by an adult speaker; however, it appeared that children under the age of 22 months did not identify the target item when they were taught the novel word via the television program.     

A Probabilistic Approach to Conditional Reasoning Development

How likely is the glass to break, given that it is heated? The present study asks questions such as this with or without the premise if the glass is heated, it breaks. A reduced problem (question without premise) measures the statistical dependency (conditional probability) of an event to occur, given that another has occurred. Such statistical dependency represents knowledge-based reasoning (inferring from “glass heated” to “its breaking”) and is a component of the response to the complete problem (question with premise). The complete problems therefore measure not only knowledge-based reasoning in terms of statistical dependencies (inductive component) but assumption-based reasoning (deductive component). Two experiments revealed: a) Knowledge-based reasoning continues to develop and attains adult levels at 7th grade for the problems tested, and b) assumption-based reasoning (deductive component) is reliable only for secondary school students (7th graders).