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We studied single-particle pinning of grain boundary (GB) migration during grain growth. A phase-field model was formulated to simulate the pinning by a coherent particle and validated quantitatively by comparison with analytical prediction. A study of GB migration velocity using this model revealed that second-phase coherent particles have a previously unknown restraining effect over the whole of the GB-particle interaction range, which is qualitatively different from the interaction between GB and incoherent particles. 相似文献
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BiFe1? x Ta x O3 (x = 0, 0.05, 0.1) nanopowders have been fabricated by a simple sol–gel method. Dielectric measurements at microwave frequencies (2–18 GHz) were made using a vector network analyser. Without tantalum, the BiFeO3 nanopowder presents a relaxation-like response with a characteristic frequency of 15 GHz, which can be associated with an overdamped process. The Ta-doped nanopowders, however, show resonant behaviour with resonant frequencies of 12.5 and 14.6 GHz. The intensity of the resonant peak near 14.6 GHz decreases with increasing Ta addition. This behaviour is associated with a damped resonance process. Room-temperature magnetic measurements indicate that the addition of Ta influences the magnetic properties of the BiFeO3 nanopowders, with BiFe0.95Ta0.05O3 having the strongest ferromagnetism with a saturation magnetisation M s of about 0.05 µB/Fe. The origin of the enhanced ferromagnetism is possibly associated with the distortion of the oxygen octahedral by the Ta substitution or/and the statistical distribution of Fe3+ and Fe2+. 相似文献
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Huo‐Tsan Chang Hung‐Ming Hsu Jia‐Wen Liou Chi‐Tung Tsai 《Journal of applied social psychology》2013,43(10):2120-2135
This study explored the relationships between psychological contract types and innovative behavior. We focused on the mediating effect of work engagement and the moderating effect of job resources (organizational and social resources). Participants were 267 dyads of research and development engineers and their supervisors from 30 high‐tech companies. Moderated path analysis was used to test the hypotheses. Findings showed that: (a) work engagement fully mediated the negative relationship between transactional contracts and innovative behavior; in addition, it also fully mediated the positive relationship between relational contracts and innovative behavior; and (b) job resources attenuated the former and strengthened the latter mediating effects. These findings contribute to understanding how, why, and when psychological contract types lead to innovative behavior via work engagement. 相似文献
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对小学一到三年级81名汉语儿童进行英语、汉语语音意识以及英语单词认读的测试,同时纳入瑞文推理和工作记忆测试作为控制变量,考察英、汉语音意识的不同成分在英语单词认读中的作用。研究结果表明:(1)汉语儿童的英语、汉语语音意识的各个水平与单词认读相关均显著,但不同水平的语音意识对单词认读的影响作用不同。(2)在控制了非言语智力因素和工作记忆的条件下,只有英语、汉语的音位意识对汉语儿童的单词认读具有较强的预测作用。 相似文献
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