Thermodynamic fluctuations in magnetic states: Fe3Pt as a prototype

To understand the Invar anomalies, such as negative thermal expansion and spontaneous magnetization, we have applied our recently developed thermodynamic framework for a system with itinerant-electron magnetism to the ordered Fe₃Pt. The framework has coherently predicted the finite temperature intermixing between the fully ferromagnetic (FM) configuration and the spin-flipping configurations (SFCs). We have also discovered a tri-critical point at which a high-temperature second-order phase transition, between the fully ordered FM phase and the paramagnetic phase which is disordered due to SFCs, becomes first order at low temperatures.     

Determination of electrostatic characteristics at a 24°, [001] tilt grain boundary in a SrTiO3 bicrystal by electron holography

The electrostatic potential and associated space charge across a 24°, [001] tilt boundary of SrTiO₃ ceramic have been determined using electron holography. The results reveal a positive charged interface with a negative space charge on either side. The form of the double Schottky barrier and the local charge-density distribution at the interface are derived from the results.     

Survey of plateau behaviour in the cyclic stress-strain curve of copper single crystals

Experimental results relating to the plateau behaviour in the cyclic stress-strain (CSS) curve of copper single crystals located on different sides of the stereographic triangle are summarized. Unlike the situation for single-sliporiented crystals, the crystallographic orientation has a strong effect on the plateau behaviour in the CSS curves of double- and multiple-slip-oriented crystals. The existence or non-existence of a plateau in the CSS curves, as well as the corresponding plateau stress amplitude, depend not only on the modes and intensities of dislocation interactions among slip systems operating in the crystals but also on the slip deformation characteristics associated with crystal orientations. The plateau region in CSS curve disappears only when multiple slip plays a determining role during cyclic deformation.     

A phase-field model for deformation twinning

We propose a phase-field model for modeling microstructure evolution during deformation twinning. The order parameters are proportional to the shear strains defined in terms of twin plane orientations and twinning directions. Using a face-centered cubic Al as an example, the deformation energy as a function of shear strain is obtained using first-principle calculations. The gradient energy coefficients are fitted to the twin boundary energies along the twinning planes and to the dislocation core energies along the directions that are perpendicular to the twinning planes. The elastic strain energy of a twinned structure is included using the Khachaturyan's elastic theory. We simulated the twinning process and microstructure evolution under a number of fixed deformations and predicted the twinning plane orientations and microstructures.     

Interactions of persistent slip bands with a grain boundary on the common primary slip plane in a copper bicrystal

In this letter, the dislocation patterns on the common primary slip plane in a fatigued \[1-34]-\[182-7] copper bicrystal with a Sigma=19b grain boundary (GB) have been investigated using the electron channelling contrast technique in a scanning electron microscope. The results show that the two-phase dislocation structure, such as veins and persistent slip band (PSB) walls, embedded within veins, can be clearly seen on the common primary slip plane. In particular, the interactions of PSBs with the GB are clearly revealed. It is found that there are three kinds of interaction mode between the GB and the dislocations during cyclic deformation, and those are discussed. It is suggested that the dislocations carried by PSBs cannot transfer through the GB continuously even though the bicrystal has a common primary slip plane and its surface slip bands are continuous across the GB.     

Crystallization behaviour of Al-based amorphous alloy and nanocomposites by rapid quenching

The microstructure and crystallization behaviour of melt-spun Al₈₈Ni₉Ce₂Fe₁ amorphous alloy and nanophase composites have been studied by means of X-ray diffraction, transmission electron microscopy and scanning and isothermal calorimetry. The diffraction patterns from Al₈₈Ni₉Ce₂Fe₁ amorphous alloys are diffuse, indicating a basically amorphous structure but contain two rings presumed to be associated with quenched-in nuclei. In the cases of Al₈₈Ni₉Ce₂Fe₁ nanophase composites, nanoscale precipitated particles are homogeneously dispersed in an amorphous matrix, and the crystallite diameter and volume fraction are sensitive to quenching conditions. During thermal crystallization, a two-step phase transformation occurs in the amorphous alloy and nanocomposites, which is characterized by a diffusion-controlled precipitation of nanoscale Al particles and the growth of a Al₃(Ni, Fe) nanophase prior to a Al₁₁Ce₃ nanophase. This study gives insight into structure-control for obtaining nanophases dispersed in an amorphous matrix by rapid quenching.     

Burnout and its relations with basic psychological needs and motivation among athletes: A systematic review and meta-analysis

ObjectivesThe present study is a review on studies about the relationships between the three basic psychological needs/motivational regulations (i.e., amotivation, controlled regulation, extrinsic autonomous regulation, and intrinsic motivation) and burnout.DesignA systematic review and meta-analysis.MethodStudies were identified through five electronic databases and manual search using combinations of three groups of keywords. Three inclusion criteria were then used to screen the searched articles.ResultsEighteen studies met the inclusion criteria and these studies varied considerably in terms of their study characteristics (e.g., characteristics of participants, study designs, and outcome measures). The results also showed that the three basic psychological needs, intrinsic motivation, extrinsic autonomous regulation, and amotivation had small to large effects on predicting global burnout and its three dimensions. However, controlled regulation showed no or weak correlations with the burnout subscales.ConclusionsSelf-determination theory was generally supported in explaining athlete burnout.     

Cognition and Emotion in TV Message Processing: How Valence,Arousing Content,Structural Complexity,and Information Density Affect the Availability of Cognitive Resources

This paper examines whether emotional message content alters the effects of structural complexity and information density on available resources, measured by secondary task reaction times (STRTs), and message encoding, measured by audio recognition. In addition, hypotheses relating motivational activation and resource availability based on the motivational activation concepts of positivity offset (greater appetitive activation in a neutral environment) and negativity bias (faster aversive activation) influence are tested. Results replicate previous research supporting the contention that STRTs measure available resources. In addition, they show that the basic pattern of STRTs and recognition as a function of allocated and required resources is relatively consistent regardless of emotional content of the message. Emotion appears to function as a constant, increasing both resource allocation and resources required. Finally, these data provide some initial support for predicted relationships between motivational activation and resource allocation based on the constructs of positivity offset and negativity bias.