Intrinsic factor controlling the deformation and ductile-to-brittle transition of metallic glasses

The energetic driving force and resistance for shearing and cracking in metallic glasses (MGs) are quantitatively evaluated. A universal thermodynamic criterion is proposed for better understanding the intrinsic correlations between fracture toughness and Poisson’s ratio, the competitions between various deformation modes and the ductile-to-brittle transition in MGs and other materials. A new cooperation parameter δ is also introduced to depict quantitatively the relative propensity of shearing versus cracking. This work could provide insights into the long-standing issues of deformation mechanisms of glassy materials, and be helpful in searching for ductile and tough MGs.     

Networking amorphous phase reinforced titanium composites which show tensile plasticity

Titanium matrix composites reinforced by an in situ formed networking amorphous phase have been prepared directly in the form of as-cast ingots. The composites show significant compressive and tensile plasticity. In contrast to the highly localized plasticity for most monolithic amorphous alloys, the tensile deformation of the current composites distributes uniformly over the entire specimen as a consequence of substantial work (strain) hardening. The formation mechanism of the networking structure, as a result of well-separated two-step solidification of the current alloy melts, have possible implications for composite synthesis in other alloy systems.     

Microstructure and mechanical behavior of nanostructured composite Cu60Fe40 alloy

In this study, bulk nanostructured composite Cu₆₀Fe₄₀ alloy is prepared by a combustion synthesis technique. The prepared Cu₆₀Fe₄₀ alloy consists of Cu(Fe) solid solution and Fe(Cu) solid solution phases. The large-scaled compositional segregation in the Cu-rich and Fe-rich phases is not observed, respectively. A few micron-sized dendrite (Fe(Cu) solid solution) is embedded into the nanostructured matrix (Cu(Fe) solid solution). The grain size of the matrix is in the range 50–300?nm. The yield and fracture strength of the Cu₆₀Fe₄₀ alloy are 540 and 1050?MPa, respectively, and the fracture strain obtained from the compression test is about 20.9%. The Cu₆₀Fe₄₀ alloy displays notable work hardening in the compressive deformation.     

Solubility criterion for sequential disordering in metal-metal multilayers upon solid-state reaction

An n-body Ni-Ti potential is derived and applied in a molecular dynamics simulation to study the maximum supersaturated solubility of the terminal solid solutions and solid-state reaction in a Ni/Ti bilayer. It reveals that during interfacial reaction of the Ni/Ti bilayer the Ti lattice reaches its maximum solubility by dissolving Ni earlier than Ni does through dissolution of Ti, which results in a sequential disordering of first Ti and then Ni, although Ti has a higher melting point than Ni. In the Ni-Zr, Ni-Mo and Ni-Ta systems, however, the Ni lattice collapses more rapidly because it reaches a maximum solubility earlier than its partners, which have higher melting points than Ni. A solubility criterion is thus relevant for all the above cases; the lower the maximum solid solubility the less stable is the lattice of the metal upon solid-state reaction.     

A new stable icosahedral quasicrystal in the Cd-Mg-Dy system

A new stable icosahedral quasicrystal has been found in annealed Cd-Mg-Dy alloys. The composition of the icosahedral phase was determined to be approximately Cd₆₆Mg₂₁Dy₁₃. Powder X-ray and electron diffraction patterns revealed that the phase has a primitive icosahedral lattice with a quasilattice parameter a_R = 0.5634 nm. The electron diffraction study confirmed that the phase has a well ordered primitive icosahedral structure.     

Elastic solutions with arbitrary elastic inhomogeneity and anisotropy

An efficient numerical algorithm is proposed to accurately compute the elastic fields in two-dimensional (2D) or three-dimensional (3D) microstructures with arbitrary elastic inhomogeneity and anisotropy. It combines the equivalent inclusion method of Eshelby, the microelasticity theory of Khachaturyan, and the spectral iterative perturbation method of Hu and Chen. Its efficiency is compared with those of existing approaches in the literature. The method can be conveniently implemented in phase-field modeling of stress-dependent microstructure evolution and/or of mass/electrical transport.     

Retention and thermal desorption of helium in amorphous and crystalline FeBSi alloys

Helium retention in metals is related to their atomic structure and the type of defects they contain. In order to investigate the dependence of helium retention on structure, amorphous Fe₇₉B₁₆Si₅ and crystalline FeBSi alloys were irradiated by helium ions at room temperature. In the crystalline alloy irradiated with 5 keV He⁺ ions, three types of helium trapping sites were found: surface defects produced by the irradiation, interstitial-type dislocation loops, and voids. Although these defects did not exist in the amorphous FeBSi alloy, we did observe thermal desorption peaks related to all three types. In addition, helium was released during the crystallization of amorphous FeBSi that had been irradiated by He⁺ ions.     

THE BEHAVIORAL EFFECTS OF A PROCEDURE USED BY PEDIATRIC OCCUPATIONAL THERAPISTS

Pediatric occupational therapists often use specific activities associated with deep pressure touch as a modality when providing services based in sensory integration theory. This study investigated the effects of these activities contingent on choice responding. Initially, preference assessments identified that activities such as being swaddled in a blanket or sandwiched between halves of a therapy mat were potential reinforcers for each of the three participants. Then, the stimuli were presented contingently under a two‐response concurrent schedule. The results suggested that for each participant, the application of these activities functioned as a positive reinforcer. Given that such activities are often used in pediatric occupational therapy interventions, the clinical implications of these findings are discussed. Copyright © 2012 John Wiley & Sons, Ltd.