Characterisation of magnesium oxide and its interface with α-Mg in Mg–Al-based alloys

Magnesium oxide (MgO) films and particles have been collected by pressurised filtration of a Mg-8.6wt%Al-0.67wt%Zn (AZ91D) alloy melt. The morphology of the oxides and their interfaces with the α-Mg phase were investigated by high-resolution transmission electron microscopy. It was found that the oxide films consisted of large numbers of sub-micrometre-sized MgO particles, and that melt shearing can effectively break up the oxide films and disperse the oxide particles. For the first time, orientation relationships (ORs) of OR I: [1?1?1]_MgO～2° from (0?0?0?1)_α-Mg and (0?1?1)_MgO?//[2?1?1?0)_α-Mg; and OR II: (1?1?1)_MgO//(1?1?0?1)_α-Mg and [0?1?1]_MgO//[1?2?1?1]_α-Mg, were observed between the MgO particles and the α-Mg matrix. The calculated Bramfitt planar disregistries were 5.5% and 2.5% for the two ORs, respectively, indicating good lattice matching between MgO and α-Mg at the interface. With the evidence of grain refinement effect observed in the sheared AZ91D magnesium alloy, the possibility of MgO particles to act as potent nucleants for heterogeneous nucleation of α-Mg grains is discussed in terms of the crystallographic criterion.     

TEM observation of oxide scale formed on a Ti–Al–Zr alloy oxidized at 360°C in alkaline steam

Ti–Al–Zr alloy has been oxidized at 360°C in alkaline steam at a pressure of 10.3?±?0.7?MPa. Cross-sectional transmission electron microscopy (TEM) observations indicated that the oxide scale of Ti–Al–Zr alloy was composed of outer and inner subscales, in which the outer layer consists of anatase-TiO₂ and the inner layer a mixture of TiO and Ti₂O. The thickness of the Ti₂O, TiO and anatase-TiO₂ were approximately 50, 100 and 400?nm, respectively. These results were confirmed by X-ray energy dispersive spectrometry (EDS) measurements. The enhanced corrosion of titanium alloys in LiOH solution is attributed to a high hexagonal Ti₂O to tetragonal TiO₂ phase transformation rate induced by the substitution of Li⁺ for Ti⁴⁺ in the oxide layer.     

Effect of aspect ratio on the compressive deformation and fracture behaviour of Zr-based bulk metallic glass

The compressive deformation and fracture features of Zr₅₉Cu₂₀Al₁₀Ni₈Ti₃ bulk metallic glassy samples with aspect ratios in the range of 0.67–2.00 have been investigated. The compressive plastic strain of the glass monotonically increases with decreasing aspect ratio, but the maximum strength almost maintains a constant value of 1.77–1.88?GPa. All the compressive shear-band angles are equal to?～40° if modified by the rotation of the primary shear bands.     

Wear behaviour of a gradient surface produced by a punching process in a Cu-30 Ni alloy

The grain size variation in a gradient surface produced by a punching and recovery process on a Cu-30Ni alloy has been observed by atomic force microscopy. The friction characteristics of the gradient surface in a 3.5 wt% NaCl solution were investigated using a micro-indenter probe, a pin-on-disc type tribometer, a strain sensor and an optical microscope. The results showed that the hardness and grain size can be well represented by the Hall–Petch relationship when the gain size is more than 30?nm. The wear rate, friction coefficient and adhesive force all increase depth below the surface. These variations are attributed to a gradual increasing grain size with depth. The morphologies of the worn track were also studied to understand further the corrosive wear behaviour of gradient surfaces.     

Hacia una historia del psicoanálisis

RESUMEN

El autor comienza señalando que la comprensión histórica del psicoanálisis exige un tratamiento plural, cuyo enfoque ilumine las diferentes perspectivas -así como su mutua interrelación- que han venido ilustrando su peculiar entidad. Por ello en este trabajo define de forma sistemática los principales enfoque históricos de los que es susceptible el fenómeno psicoanalítico: analítico-biográfico, socio-cultural, institucional-profesional y epistemológico, señalando los principales intereses temáticos y problemas que incluye cada uno y ofreciendo una selección de fuentes bibliográficas según tres criterios combinados: el mantenimiento de las obras clave clásicas, el carácter contemporáneo de las fuentes y el acceso a las mismas.     

Will you thrive under pressure or burn out? Linking anxiety motivation and emotional exhaustion

Can individual differences in the tendency to use anxiety as a source of motivation explain emotional exhaustion? We examined the effects of using anxiety as a source of energy or as a source of information (viewed here as two forms of anxiety motivation) on emotional exhaustion. In Study 1, the use of anxiety as a source of energy predicted decreased emotional exhaustion one year later. Moreover, both forms of anxiety motivation buffered people from the detrimental effects of trait anxiety on later emotional exhaustion. In Study 2, an experiment, participants who were instructed to use anxiety as a source of energy reported lower emotional exhaustion following a stressful task, compared to those instructed to focus on the task or to simply do their best. These findings suggest that using anxiety as a source of motivation may protect people against emotional exhaustion.     

Evaluating the Psychometric and Measurement Characteristics of a Measure of Sexual Orientation Harassment

We use classical test theory (CTT) and item response theory (IRT) methodologies to examine the psychometric and measurement properties of an instrument designed to assess sexual orientation harassment among military personnel (N?=?71,989). CTT analyses indicated that items were unidimensional and exhibited adequate levels of reliability. IRT analyses demonstrated that the items functioned similarly and exhibited appropriate levels of item discrimination. However, the analyses also suggested that the sensitivity of the items may be limited. Differential test functioning analyses provided evidence of the measurement equivalence of the instrument across male and female respondents. The findings provide support for the psychometric properties and measurement equivalence of the instrument for measuring sexual orientation harassment among male and female military personnel. We discuss the implications of our findings for future research on sexual orientation harassment in the workplace.     

Exaggerated grain growth and improved properties of Y1 Ba2 Cu3 O7-x by Pt addition

Abstract

Superconducting and mechanical properties of Y₁ Ba₂Cu₃ O₇ can be improved by the use of sintering aids. 0·2 wt% of finely divided laser-ablated platinum powder has been mixed with the parent material and produced a dense product with exaggerated grain growth and improved critical current density and Vickers hardness. At higher concentrations of platinum, while the mechanical properties are further improved, the increased density appeared to inhibit access of oxygen for the tetragonal to orthorhombic phase transition and the current density was reduced.