Nature of shear flow lines in equal-channel angular-pressed metals and alloys

The nature of shear flow lines in equal-channel angular-pressed (ECAPed) metals has been investigated experimentally and theoretically. Experimental results indicate that, for metals pressed in a right-angle die, the shear flow lines often have an angle of ～27° with respect to the extrusion direction. It is suggested that the shear flow lines are composed of a group of elongated grains with an elongation direction that deviates slightly from that of the shear flow lines.     

Characterization of room-temperature plastic deformation of ß-Si3N4 by atomic force microscopy and transmission electron microscopy

Dislocation microstructures induced by room-temperature microhardness tests have been investigated in silicon nitride. Surface analysis of the residual indent by atomic force microscopy reveals intragranular slip bands and demonstrates that room-temperature plastic deformation involves dislocation motion as well as cross-slip events. Cross-slip events have been found to occur between {1010} prismatic planes. Transmission electron microscopy shows that dislocations have a Burgers vector b = [0001] and are located along the screw direction. Based on these observations, specific dislocation core configurations are discussed.     

Thermophysical properties of undercooled liquid cobalt

The surface tension of undercooled liquid cobalt has been measured by the oscillating-drop technique combined with electromagnetic levitation. The accuracy of the method was verified by measurements of the surface tension of liquid nickel. The liquid cobalt was undercooled by up to 231K (0.13T _m), and its surface tension determined to be σ_Co =1875 0.348(T-T _m)mNm^-1. From this result, the viscosity, self-diffusion coefficient, density and thermal diffusivity of undercooled liquid cobalt were derived. Using these thermophysical parameters, the growth velocity of cobalt dendrite is calculated and shown to agree well with experimental results. Furthermore, the Marangoni number and the Rayleigh number are calculated; these increase slowly with increasing degree of undercooling.     

Two different types of shear-deformation behaviour in Au–Cu multilayers

Localised shear deformation of a material is usually identified as a particular feature of deformation inhomogeneity. Here, we show two different types of shear deformation-behaviour that occurred in Au–Cu multilayers subjected to microindentation load, namely, a cooperative-layer-buckling-induced shear banding in a nanoscale multilayer and a direct localised shearing across a layer interface along a shear plane in a submicron-scale multilayer. Theoretical analysis indicates that the formation of the two different types of shear deformation in the multilayers depends on a competition between the dislocation-pile-up-induced stress concentration at the layer interface and the barrier strength of the layer interface for glissile dislocation transmission.     

Amorphization of TiNi induced by high-pressure torsion

Using high-resolution electron microscopy, we investigated the initial stages of high-pressure-torsion-induced crystalline-to-amorphous transformation of TiNi. It is found that the deformation-induced amorphization initiated from dislocation core regions in the interior of grains and from grain boundaries. It is believed that both the energy stored in the dislocations and the energy stored in the grain boundaries contribute significantly to driving the crystalline-to-amorphous transformation.     

High-resolution electron microscopy observations of microplastic fracture in SiC under ball milling at room temperature

Nanometre-sized kinks and cracks formed in 6H SiC under ball milling (BM) at room temperature have been observed and characterized on the atomic scale using high-resolution electron microscopy (HREM). Observations of the kinks show that numerous positive and negative partials are aligned at either of the kink boundaries, and the stacking sequences in the kink band are considerably different from those in the other areas. It was also observed that the (0001) lattice planes in the kink band are kinked, indicating that microplasticity occurs in the normally brittle material SiC under BM even at room temperature. HREM observations of cracks show that cracks previously observed by transmision electron microscopy are not completely open but are at the initiation stage of fracture. Inside a crack, one residual kink region can be clearly observed, which indicates a correlation between kink and crack, that is a crack evolves from a kink.     

Valence band structure of the NiAl–Mo alloy from the photoelectron spectrum

The valence band structures of the NiAl–Mo alloy was investigated by photoelectron spectroscopy. The valence band spectra of the NiAl–Mo alloy was shifted away from the Fermi level so that the Ni-d-band centroid moved to a higher energy by 0.22 eV as Mo was added. A possible explanation lied in the overlap of Ni-d bands in the energy with Mo-d and Al-p bands. The participation of Mo-d bands was correlated with the site preference of Mo in NiAl alloys.     

PbO compensation in the growth of PbWO4: Y3+ crystals

The light yield of Y³⁺-doped PbWO₄ crystals increases after low-dose-rate irradiation with?γ?rays, and the radiation hardness is sensitive to annealing temperature. In the PWO growth procedure, an excess of PbO in the starting materials is a convenient method of compensating for PbO volatility. The relationship between the excess of PbO and the abnormal radiation behaviour has been investigated. The mechanism of the normal excess of PbO in the growth of PWO: Y³⁺ is discussed.     

Structural phase transitions in epitaxial SrRuO3 thin films

The microstructural evolution of epitaxial SrRuO₃ thin films from ambient temperature (about 293K) to about 900K has been studied by in-situ transmission electron microscopy. Upon heating from the ambient temperature, the intensities of h, k, 2n+1 and h, -h+2n+1, 0 reflections in selected-area electron diffraction patterns decrease with increasing temperature. Two structural phase transitions were observed at about 673and about 783K, revealed by the vanishing of the h, k, 2n+1 and h,-h+2n+1, 0 reflections respectively. The examination of electron diffraction patterns along several different zone axes, taking into account the possible tilting configurations of RuO₆ octahedra, indicates that, upon heating, the orthorhombic structure of SrRuO₃ transforms into a tetragonal structure at about 673K, and further transforms into a cubic structure at about 783K. Possible structural models for the high-temperature phases are considered.     

Dislocation evolution in twins of cyclically deformed copper

The evolution of dislocation structure in twins of different thicknesses has been investigated in polycrystalline copper fatigued at room temperature under constant plastic axial strain amplitude control. The dislocation structure and its evolution strongly depend on twin thickness. Three critical thicknesses must be distinguished, i.e. (i) characteristic size of fatigue dislocation structures, about 1?µm; (ii) critical height of stable dislocation wall structure, about 200?nm; (iii) critical spacing of dislocation dipole, about 20?nm. It is considered that the size effect is mainly caused by twin boundaries (TBs) which play different roles on slip behaviors in twins.