Direct evidence that an apparent splitting pattern of gamma particles in Ni alloys is a stage of coalescence

High-resolution electron microscopy is used to determine the translation order domains of gamma particles in arrangements formed during Ostwald ripening in the alloy Ni-12at.%Al. Such arrangements have been often identified with the operation of a mechanism of particle splitting in the late stages of the coarsening process, that is when the elastic strain contribution becomes predominant. It is shown that the translation order domains are not identical in such a particle array. This leads to the conclusion that particle splitting is not necessarily the mechanism responsible for the formation of such characteristic particle arrangements. Instead, particle migration can also be considered to be the responsible mechanism for the formation of such a correlated gamma-particle spatial distribution observed in Ni-based alloys.     

Voids formed from solidifying tin particles in solid aluminium

In this study, voids commonly associated with tin particles in two aluminium alloys containing microalloying additions (0.01 at.%) of tin have been observed by transmission electron microscopy. The voids were generated by quenching the alloys at moderate rates (10²–10³ K s^?1) from a temperature (718 K) in excess of the melting temperature (501 K) of elemental tin in tin–microalloyed aluminium. Estimates of the void volume as a function of the volume of the associated tin particle reveal a linear relationship consistent with the excess volume resulting from the solidification of the tin particle. The formation and stabilisation of shrinkage voids in metallic alloys are suggested to arise from a combination of high vacancy supersaturation, the large volumetric misfit strain of the solidifying tin particle and a reduction in void surface energy associated with segregation of alloying elements.     

Site preference of refractory elements in γ′-Ni3Al alloyed with Ru

The influence of ruthenium (Ru) on the partitioning behavior of W, Re and Cr in γ′-Ni₃Al has been studied using the Dmol3 method based on the density functional theory. The calculated results show that W, Re and Cr have a preference for the Ni site in γ′-Ni₃Al alloyed with Ru. When Ru substitutes the central Ni atom, the site preference for W, Re and Cr varies. Furthermore, an electronic structure analysis of the alloy in terms of the Mulliken population and partial density of states was performed to elucidate the alloying mechanism of Ru in γ′-Ni₃Al. The results show that the strengthening effect of Ru in the alloy arises from a reduction in the binding energy of Ru as well as p-orbital hybridization between Ru and the host atoms.     

Interactions between interfacial dislocations and γ/γ′ interface during high temperature – low stress creep in nickel-based single crystal superalloy

ABSTRACT

The interaction between interfacial dislocations and γ/γ′ interface is critical to the high temperature creep properties of single crystal superalloys. However, only a few studies have paid attention to the detailed structure such as local interfacial morphologies and the elemental distribution around interfacial dislocations. In this paper, the interfacial protrusions and related dislocations in a single crystal superalloy after creep at high temperature – low stress have been investigated in detail. It is found that the morphology and size of the interfacial protrusions remain almost the same during the early and middle stages of high temperature creep, which indicates a local equilibrium at the interfacial protrusions. Steps at different height are formed at the γ/γ′ interface at the initial stage of high temperature creep since dislocations could move along the γ/γ′ interface, which indicates that dislocation motion at different creep stage may affect the morphology of γ/γ′ interface.     

Z-contrast imaging of the arrangement of Cu in precipitates in 6XXX-series aluminium alloys

High-resolution annular dark field imaging has been used to study small precipitates in the Al matrix of 6XXX-series aluminium alloys. Cu-containing columns in precipitates were imaged by atomic number contrast along a 〈100〉 matrix direction. At an under-aged condition, large, lath-shaped particles of the Cu-containing Q′-phase were observed at grain boundaries. At over-aged conditions, Q′ was the main matrix phase. In both cases the laths showed an Al {150} habit plane. A precursor phase was found, with different arrangement of Cu-rich columns from that of the Q′-phase and sharing Al {100} habit planes. Precipitates containing elements of both the Q′-phase and the precursor were found to be common. Annular dark field imaging can differentiate directly between phases. The method complements and aids interpretation of conventional high-resolution TEM images and nano beam diffraction observations. The results obtained contribute to an improved understanding of the crystallography of the precursor and details of the structural transformation taking place during the precipitation process.     

Extraordinary plastic behaviour of the γ′ precipitate in a directionally solidified nickel-based superalloy

The deformation behaviour of the γ′ precipitate in a directionally solidified nickel-based superalloy is investigated using microscopic observations after tensile testing at room temperature. It is found that coarse γ′ precipitates (604 nm) are sheared by strongly coupled dislocations, and some γ′ precipitates are elongated to approximately 3–6 times of their original lengths. It reveals that, at room temperature, the γ′ precipitate within the experimental superalloy has a significant plastic deformation capacity in comparison with Ni₃Al bulk alloys. Based on the experimental observations, the extraordinary plastic behaviour of the γ′ precipitate is analysed.     

Effect of Sb on coarsening of Fe particles in a Cu-Fe alloy

The influence of Sb on the coarsening behaviour of spherical α-Fe and γ-Fe particles in a Cu?Fe alloy has been investigated. The size of thparticles was determined by transmission electron microscopy and the Fe concentration in the Cu matrix by electric resistivity measurements. Adding Sb decreases the coarsening rate of the Fe particles, primarily via a reduction in the volume diffusivity of Fe in Cu. The pre-exponential factor and activation energy for volume diffusion are increased by the addition of Sb atoms in the matrix. The Sb addition changes the incoherent α-Fe?Cu interface energy by segregation of Sb at the incoherent interfaces but not the coherent γ-Fe?Cu interface energy.     

Ostwald ripening of spherical Fe particles in Cu-Fe alloys

The coarsening of spherical n -Fe and f -Fe precipitate particles in Cu-Fe alloys aged at 600, 650 and 700C has been studied by measuring both the particle size by transmission electron microscopy and the Fe concentration in the Cu matrix by electric resistivity. The average size of n -Fe and f -Fe particles increases with ageing time t as t 1/3, as predicted by the Lifshitz-Slyozov-Wagner theory. The kinetics of the depletion of supersaturation with t for n -Fe and f -Fe particles are consistent with the predicted t -1/3 time law. The solubilities of Fe in equilibrium with a n -Fe particle of infinite size are greater than those in equilibrium with an f -Fe particle of infinite size. The Fe-Cu interface energy and the diffusivity of Fe in Cu have been independently derived from the data on coarsening. The coherent n -Fe-Cu interface energy is estimated to be 0.25Jm -2, and the incoherent f -Fe-Cu interface energy 0.52Jm -2 . The preexponential factor and activation energy for diffusion are found to be 9.75 10 -5 m 2 s -1 and 213kJmol -1 respectively.     

Re-precipitation of coherent γ-Fe particles following annealing of equal-channel angular pressed Cu–Fe alloy

The transformation of second-phase particles in a Cu–Fe alloy following equal-channel angular extrusion and annealing has been determined by transmission electron microscopy. Equal-channel angular pressing of the Cu–Fe alloy transformed coherent γ-Fe particles in the Cu matrix into incoherent α-Fe. Upon annealing, numerous coherent γ-Fe particles were observed. A dislocation–particle interaction mechanism is suggested to explain the re-precipitation of coherent γ-Fe particles following annealing.     

Precipitation of γ’ during cooling of nickel-base superalloy Haynes 282

ABSTRACT

Cooling-induced precipitation of the strengthening γ’ phase is commonly investigated in Ni-base superalloys with a high γ’ volume fraction, where it is used to control the final microstructure and properties. Less is known about the phase separation in low-volume-fraction alloys during cooling, although the microstructural state after cooling from solution treatment is known to affect subsequent heat-treatment steps. We use atomic-scale characterisation of Ni-base superalloy Haynes 282 (equilibrium γ’ volume fraction around 20%) to show that air cooling after solution or carbide stabilisation results in precipitation of nm-sized γ’ particles, whereas precipitation was suppressed during water quenching. The solution treatment has a significant effect on the hardness and γ’ precipitation during air cooling from the subsequent carbide stabilisation temperature. Also, the carbide-stabilisation treatment itself affects the γ’ precipitation during subsequent air cooling.     

On the synthesis and characterisation of novel composite-structured high-entropy alloys

A study of novel composite-structured CoCrFeNi₃Si, CoCrFe₂Ni₂Si and Co₂CrFeNi₂Si high-entropy alloys, synthesised by vacuum arc melting, is presented. The designing criteria for the formation of such alloys were based on the enthalpy of mixing and the valence electron concentration. X-ray diffraction analysis revealed that all the alloys were composed of face-centered cubic and intermetallic phases. Scanning electron microscopy, along with elemental analysis, indicated that the face-centered cubic phase mainly contains Co, Cr, Fe and Ni, whereas, the intermetallic compound is Ni-Si rich. All the synthesised high-entropy alloys in the present investigation possess excellent compressive strength along with ductility at room temperature, suggesting significant potential application in the engineering field. Furthermore, enhanced hardness, wear resistance and corrosion resistance were achieved in all the designed high-entropy alloys. The previously given design parameters for the composite-structured high-entropy alloys are in good accord with the current research work.     

Derivation of the antiphase-boundary energy of L1 2 long-range-ordered precipitates from measurements of the minimum size of stable dislocation loops

In an alloy that is strengthened by long-range-ordered particles, a matrix dislocation generates an antiphase boundary (APB) when it cuts through such a particle. The specific energy n APB of this APB has been measured for two fcc alloys with spherical coherent L12 ordered particles: an Al-7.5at.%Li-alloy and the commercial Ni-base superalloy Nimonic PE16. Peak-aged specimens have been deformed and Orowan loops searched for using transmission electron microscopy. n APB has been derived from the radii of the smallest dislocation loops which have been left behind around particles. Such an approach had been used previously, for example, by Raynor and Silcock and by Nembach et al . Here an improved evaluation method has been applied; it is based on the results of computer simulations of the equilibrium configurations of dislocation loops.     

Polytypes of long-period stacking structures synchronized with chemical order in a dilute Mg–Zn–Y alloy

A series of structural polytypes formed in an Mg–1 at.%Zn–2 at.%Y alloy has been identified, which are reasonably viewed as long-period stacking derivatives of the hexagonal-close-packed Mg structure with alternate AB stacking of the close-packed atomic layers. Atomic-resolution Z-contrast imaging clearly revealed that the structures are long-period chemical-ordered as well as stacking-ordered; unique chemical order along the stacking direction occurs as being synchronized with a local faulted stacking of AB′C′A, where B′ and C′ layers are commonly enriched by Zn/Y atoms.     

A first-principles study of the formation of θ′′ phase in Al–Cu alloys

The θ′′-Al₃Cu phase plays an important role in the precipitation process of Al–Cu alloys. This phase has a sandwich structure—every two {200}_Cu layers are separated by three {200}_Al layers. To analyse the formation mechanism of this structure, the elastic strain energy of the {200}_Cu and {200}_Al layers, and the chemical bonding energy that reflects the interaction between the electrons in Cu and neighbouring Al atoms are calculated and analysed by first-principles calculations, projected density of states and Bader analysis. Our computation results reveal that this sandwich structure is energetically preferred in the competition of elastic strain and chemical bonding energies. To minimise the elastic strain energy of {200}_Al and {200}_Cu layers, the {200}_Cu layers prefer being apart from each other, whereas the chemical bonding energy favours the opposite arrangement because the intermetallic bond between Al and Cu atoms may form through p-d hybridization.     

Structural characteristics of a high-quality Al?Ni?Ru decagonal quasicrystal with 1.6nm periodicity,studied by atomic-scale electron microscopy observations

We report the structural characteristics of a high-quality stable decagonal quasicrystal (D phase) with 1.6nm periodicity, formed in Al₇₅Ni₁₅Ru₁₀ alloy annealed at 890°C for 24h. The tiling structure and the arrangement of transition-metal atoms (Ru and Ni) in this Al-Ni-Ru D phase have been clearly revealed by high-resolution electron microscopy (HREM) and by highangle annular detector dark-field (HAADF) scanning transmission electron microscopy (STM) respectively. On the basis of the HREM and HAADF STM observations, the relationship between the arrangement of local structural units and the formation of the long-range quasiperiodic tiling structure is discussed.     

Possible influence of electrostatics in molecular bonding at supported metal nanoparticles

A mechanism is proposed for interaction between gas molecules and supported metal nanoparticles. Hot electrons that are formed via electron–hole pair excitations caused by exothermic reactions on the particles, enter into the insulating support, thereby leaving a positive charge that is distributed over the volume of the nanoparticle. The lifetime of the charge depends on the size of the metal particle and on the electronic and dielectric properties of the support, and may be too short for equilibrium to be established between the particle and its surroundings on the time scale of the chemical reaction. The electrostatic potential of the particle depends on its size, and therefore the position of the d-density of states of the particle, and thus the interaction with adsorbed molecules may be tuned by changing particle size. Thus, catalytic activity and selectivity may be affected for chemical reactions.     

Indentation behaviour of ion-irradiated X-750 Ni-based superalloy

The mechanical properties of an ion-irradiated Ni-based superalloy have been evaluated using nano-indentation hardness tests. A high-energy Ni ion beam was employed for irradiation at room temperature up to different doses. Nano-indentation tests were carried out in the range of 100–1000 nm to measure hardness changes of the experimental alloy. The results show softening of the irradiated material compared to the un-irradiated material, with the softening being more pronounced at the higher dose. Cross-sectional transmission electron microscopy characterisation reveals that γ′-precipitate instability (disordering/dissolution) is the main reason for the softening behaviour and this outweighs the hardening effect of irradiation-induced defects.     

Very high temperature creep behavior of a single crystal Ni-based superalloy under complex thermal cycling conditions

Very high temperature thermal cycling has been performed on the single crystal superalloy MC2 to evaluate the effect of periodic overheating on creep behavior. The experiments consist of alternately performing 1 min dwell time at 1100°C and 1150°C for every 15 min during creep test at 1050°C/120 MPa. Both thermal cycling and prior γ′-rafting appear to be deleterious to the cyclic creep properties. The observed non-isothermal creep behavior is correlated with γ′-dissolution/coalescence processes, especially during overheatings where γ′ micro-rafts seem to play a significant role.     

Friction and wear behaviour of Inconel 718 alloy fabricated by selective laser melting after heat treatments

ABSTRACT

The effect of heat treatments (solution and double aging) on friction and wear behaviour of Inconel 718 (IN718) alloy fabricated by selective laser melting (SLM) were studied. After heat treatment of solution and double aging, the friction and wear of the alloy have been improved. The worn surfaces of heat-treated IN718 alloy became smoother, and micro-ploughing became shallower. After solid solution hearting, a portion of the Laves phase ((Ni, Fe, Co)₂(Nb, Ti, Mo)) dissolves into the matrix, after which the γ″ phase (Ni₃Nb) andthe equilibrium phase of the δ phase (Ni₃Nb) precipitates during double ageing. After solution and double aging, nano-scale γ′ (Ni₃(Al, Ti)) and γ″ phases distribute homogeneously in the matrix, which improves the material hardness and wear resistance of the SLMed IN718 alloy.