Effect of applied stress on precipitation of Guinier–Preston zones in a Cu–0.9 wt.% Be single crystal

A stress-oriented formation of plate-shaped Guinier–Preston (GP) zones in single crystals of a Cu–0.9?wt.%?Be alloy aged at 200°C has been found. A compressive stress applied in the [001] direction assists the formation of the GP zones perpendicular to the [001] axis, while a tensile stress results in the preferential formation of the GP zones parallel to the stress axis. The applied stress strongly affects the nucleation of the GP zones. Free ageing at 275°C after compressive-stress ageing at 200°C produces plate-shaped γ′′ precipitates perpendicular to the stress axis, indicating a continuous change in the structure of the GP zones into that of the γ′′ phase. From length-change measurements during ageing, the misfit strains of the GP zone or γ′′ precipitate in directions parallel and perpendicular to the plate plane are estimated, respectively, as ?0.01 and ?0.10 for the GP zone and ?0.01 and ?0.11 for the γ′′ precipitate.     

A first-principles study of the formation of θ′′ phase in Al–Cu alloys

The θ′′-Al₃Cu phase plays an important role in the precipitation process of Al–Cu alloys. This phase has a sandwich structure—every two {200}_Cu layers are separated by three {200}_Al layers. To analyse the formation mechanism of this structure, the elastic strain energy of the {200}_Cu and {200}_Al layers, and the chemical bonding energy that reflects the interaction between the electrons in Cu and neighbouring Al atoms are calculated and analysed by first-principles calculations, projected density of states and Bader analysis. Our computation results reveal that this sandwich structure is energetically preferred in the competition of elastic strain and chemical bonding energies. To minimise the elastic strain energy of {200}_Al and {200}_Cu layers, the {200}_Cu layers prefer being apart from each other, whereas the chemical bonding energy favours the opposite arrangement because the intermetallic bond between Al and Cu atoms may form through p-d hybridization.     

Effect of Si on the formation and stability of the icosahedral quasicrystalline phase in Al–Fe–Cr–Ti alloys

The formation and stability of the quasicrystalline icosahedral (i) phase in melt-spun Al_{93– x} Fe₃Cr₂Ti₂Si _x (x?=?0–5) ribbons are reported. Samples were characterized by X-ray diffraction, differential scanning calorimetry and transmission electron microscopy. Primitive (P-type) ordered i phase particles were found to be homogeneously distributed in an fcc α-Al matrix in the as-melt-spun ribbons. The size of the i phase particles decreased and their thermal stability increased with increasing substitution of Al by Si. The i phase had a decomposition temperature of approximately 480°C in an Al₉₃Fe₃Cr₂Ti₂ ribbon whereas that in an Al₉₂Fe₃Cr₂Ti₂Si₁ ribbon was approximately 500°C. The i phase particles are resistant to coarsening prior to decomposition into crystalline phases. The presence of a small quantity of Si (up to 1.0?at.%) is beneficial to both the thermal stability and the hardness of nanoquasicrystalline Al–Fe–Cr–Ti alloys.     

Glass formation in the Pd–Si-based alloys

Taking into account the importance of undercooling on glass formation, we propose a new criterion which allowed us to predict the best glass-forming composition, namely Pd₇₈Ag_5.5Si_16.5, among selected Pd–Si-based alloys ranging from binary to quaternary systems. The composition agrees well with that found experimentally. Using conventional copper mould casting, the Pd₇₈Ag_5.5Si_16.5 alloy is capable of forming fully amorphous rods with a diameter of 3 mm. The effects of Au and Ag additions on the glass-forming ability of the selected Pd–Si-based alloys have been investigated.     

Formation of plate-shaped Guinier–Preston zones during natural aging of an Al–Zn–Mg–Cu–Zr Alloy

Plate-shaped Guinier–Preston (G–P) zone formation in an Al–Zn–Mg–Cu–Zr alloy has been studied using transmission electron microscopy. The results provide, for the first time, direct evidence showing nucleation and growth of plate-shaped coherent G–P zones during natural aging.     

Effect of severe plastic deformation on the coercivity of Co–Cu alloys

Cast Co–5.6 wt% Cu and Co–13.6 wt% Cu alloys were subjected to severe plastic deformation (SPD) by high-pressure torsion (HPT). The HPT treatment drastically decreases the size of the Co grains (from 20 µm to 100 nm) and the Cu precipitates (from 2 µm to 10 nm). As a result, the coercivity H _c of both the alloys radically increases. The saturation magnetization, M _s, remains almost unchanged. Thus, SPD of the bulk samples opens the way for drastic increase in the coercivity for the Co-based alloys.     

Formation of Cu precipitates and vacancy clusters in neutron-irradiated Fe–Cu alloys

Two Fe–Cu binary model alloys, Fe–0.3Cu and Fe–0.6Cu, were irradiated with fission neutrons at doses ranging from 4?×?10^?6 to 0.16 dpa (displacements per atom) at ～573 K to investigate the formation of Cu precipitates and microstructural evolution. The Cu content only affected the formation of Cu precipitates and microvoids at low doses. In Fe–0.3Cu, the formation of microvoids and Cu precipitates initiated at doses of 1.2?×?10^?4 and 4?×?10^?5 dpa, respectively. On the other hand, the formation of microvoids started at a dose of 4?×?10^?4 dpa in Fe–0.6Cu, and Cu precipitates were formed even after irradiation to 4?×?10^?6 dpa. On further irradiation, the difference in the formation of Cu precipitates and microvoids was small. Microvoids grew with increasing irradiation dose up to 3?×?10^?3 dpa in both alloys. Prominent aggregation of Cu atoms occurred upon irradiation from 3?×?10^?3 to 1.6?×?10^?2 dpa and the microvoids shrank. The Cu precipitates no longer grew, and microvoids nucleated and grew in the matrix above a dose of 1.6?×?10^?2 dpa in both alloys. The present studies clearly reveal the relationships between the formation and growth of Cu precipitates and microvoids with irradiation dose.     

Reply to the comments on “Room-temperature precipitation in quenched Al–Cu–Mg alloys: a model for the reaction kinetics and yield-strength development”

We present transmission electron microscopy observations and a crystallographic analysis that show that the only significant report on the observation of {112} pseudotwins in B2 structures by Goo et al. (1985, Acta metall., 3, 1725) is a misidentification of the {114} true twins.     

On the role of Ag in enhanced age hardening kinetics of Mg–Gd–Ag–Zr alloys

The addition of Ag to the age hardenable Mg–Gd–Zr alloy system dramatically enhances early stage age hardening kinetics. Using atom probe tomography (APT), Ag-rich clusters were detected in a Ag-containing Mg–Gd–Zr alloy immediately after solution treatment and water quenching. During subsequent isothermal ageing at 200 °C, a high density of basal precipitates was observed during the early stages of ageing. These basal precipitates were enriched with Ag and Gd, as confirmed by APT. It is posited that Ag-rich clusters in the context of quenched-in vacancies can attract Gd atoms, increasing diffusion kinetics to facilitate the formation of the Ag + Gd-rich basal precipitates. The rapid formation of Ag + Gd-rich precipitates was responsible for accelerated ageing.     

Coexistence of adjacent vacancy-ordered and eutectic phases in Al–Cu–Ni alloys

ABSTRACT

Copper-mould-cast Al–Cu–Ni alloys show adjacent coexistence of in situ grown ordered and eutectic phases. A bimodal microstructure of α–Al and eutectic α-Al+θ-Al₂Cu phases with length-scale hierarchy evolves during solidification. Microstructural analysis through Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) shows the presence of Vacancy-ordered phases (VOPs) with different morphologies in two different compositions.     

Effects of Si addition on the microstructure evolution of Al–Cu–Mg alloys in the α + S + T phase field

The precipitation behaviour and age-hardening response of Al–1.5Cu–4.0Mg (wt.%) alloys microalloyed with Si have been investigated by means of hardness measurement, TEM and HRTEM. Compared to the ternary alloy, the quaternary alloys exhibit a higher hardness. It is found that the underaged microstructure in the Al–1.5Cu–4.0?Mg alloy contains some fine precipitates, which are identified as the T phase by FFT spectra. The peak-aged microstructures of the ternary alloy is dominated by the T phase, while the peak-aged microstructures of the Si-containing alloys are dominated by the S phase. The volume fraction of the S phase is found to increase as more Si is added.     

Transformation defects on θ′ precipitates in Al–Cu alloys

Growth defects in the form of transformation disconnections (TDs) are considered for the precipitation of θ′ in an Al–Cu αsolid solution. The minimum sized TDs are predicted to be 1–2?nm in height, in agreement with experimental observations. One type of TD is glissile and the other (more prevalent) type is sessile, requiring climb for motion. The presence of a fault plane on one side of the sessile TD does not impede its formation. The results are in accord with symmetry theory and with the topological model for precipitation.     

The coupled effect of grain size and solute on work hardening of Cu–Ni alloys

A modified grain size-dependent model developed to capture the combined effects of solute and grain size on the work hardening behaviour of fine-grained Cu–Ni alloys is provided. This work builds on a recent model that attributes the grain size-dependent work hardening of fine-grained Cu to backstresses. In the case of Cu–Ni alloys, unlike commercially pure Cu, a grain size-dependent separation between the Kocks–Mecking curves develops, this being explained here based on an extra contribution from geometrically necessary dislocations in the solid solution alloy. This is corroborated by strain-rate sensitivity experiments.     

Precipitate characteristics and selected area diffraction patterns of the β′ and Q′ precipitates in Al–Mg–Si–Cu alloys

In this study, the precipitate characteristics and selected area diffraction patterns (SADP) of the β?′ and Q?′ precipitates formed at the over-aged state of Al–Mg–Si–Cu alloys are systematically investigated by means of high-resolution transmission electron microscopy and transition matrix. The β?′ precipitates have two cross-sections, rectangle-shaped and round-shaped aligned with [0?0?1]_Al direction, but only rectangle-shaped cross-section exists for Q?′ precipitates. And, both of them have 12 variants and orientations with Al matrix. However, there are only three different zone axes, [0?0?0?1]_β?′, [1?4?5?0]_β?′, and [5?4?1?0]_β?′ for β?′ precipitates, and [0?0?0?1]_Q?′, [1?4?5?0]_Q?′, and [3?2 1?0]_Q?′ for Q?′ precipitates, parallel to the [0?0?1]_Al direction when they are precipitated from the Al matrix, respectively. Then, a new [0?0?1]_Al SADP model, which superposes diffraction patterns of the β?′ and Q?′ precipitates, is established. Furthermore, some “cross-shaped” diffraction streaks appeared at over-aged state can be explained reasonably by this model, which is good in agreement with the experimental data.     

Influence of auditory and audiovisual stimuli on the right–left prevalence effect

When auditory stimuli are used in two-dimensional spatial compatibility tasks, where the stimulus and response configurations vary along the horizontal and vertical dimensions simultaneously, a right–left prevalence effect occurs in which horizontal compatibility dominates over vertical compatibility. The right–left prevalence effects obtained with auditory stimuli are typically larger than that obtained with visual stimuli even though less attention should be demanded from the horizontal dimension in auditory processing. In the present study, we examined whether auditory or visual dominance occurs when the two-dimensional stimuli are audiovisual, as well as whether there will be cross-modal facilitation of response selection for the horizontal and vertical dimensions. We also examined whether there is an additional benefit of adding a pitch dimension to the auditory stimulus to facilitate vertical coding through use of the spatial-musical association of response codes (SMARC) effect, where pitch is coded in terms of height in space. In Experiment 1, we found a larger right–left prevalence effect for unimodal auditory than visual stimuli. Neutral, non-pitch coded, audiovisual stimuli did not result in cross-modal facilitation, but did show evidence of visual dominance. The right–left prevalence effect was eliminated in the presence of SMARC audiovisual stimuli, but the effect influenced horizontal rather than vertical coding. Experiment 2 showed that the influence of the pitch dimension was not in terms of influencing response selection on a trial-to-trial basis, but in terms of altering the salience of the task environment. Taken together, these findings indicate that in the absence of salient vertical cues, auditory and audiovisual stimuli tend to be coded along the horizontal dimension and vision tends to dominate audition in this two-dimensional spatial stimulus–response task.     

Influence of the median opening length on driving behaviors in the crossover work zone—A driving simulation study

Work zone safety has been a major concern for drivers and transportation agencies. Considering the severe consequences of crossover work zone crashes coupled with the limited literature on the median opening length, this paper aims to investigate the influence of the median opening length on driving behaviors from a behavioral perspective in crossover work zones. A driving simulation study with 32 participants was carried out to investigate the driving performance by metrics (speed, acceleration, maximum steering wheel speed, and lane-changing trajectory) with respect to five median opening lengths. The significant differences of each driving performance metric among various median opening lengths were found in the process of crossing through the median opening on the entrance by-pass and exit by-pass. The results indicated that drivers’ speeds were always higher than the speed limits for all median opening lengths. A narrower median opening may induce risky driving behaviors such as sharp deceleration and decelerating while lane-changing, which may increase speed variance. When crossing through the median opening with a larger length, high speed variance, sluggish lane-changing operations, and improper lane-using behaviors were observed because the excessive lane-changing space provided by the larger median opening length would decrease the situation awareness and increase the speed preference heterogeneity among drivers. Finally, some traffic management strategies were proposed, which can improve the safety and mobility of crossover work zones and further provide a basis for the formulation of related standards.     

Effect of thermoelectric magnetic force on the array of dendrites during directional solidification of Al–Cu alloys in a high magnetic field

By eliminating the effect of the magnetic moment arising from the magnetic crystalline anisotropy, the effect of the thermoelectric magnetic force on the array of dendrites during directional solidification of Al–35?wt%Cu and Al-40?wt%Cu alloys in a high magnetic field has been investigated experimentally. The results indicate that the dendrite array is essentially destroyed, a result that could have general significance for understanding the processes involved in the solidification of alloys in a magnetic field.     

Enhancement of hardening and thermal resistance of Mg–Sn-based alloys by addition of Cu and Al

Mg–Sn-based alloys are considered as a promising precipitation-hardening system for applications at elevated temperatures, but the hardening effect is not satisfactory owing to sluggish nucleation and rapid coarsening of the major Mg₂Sn lath precipitates. In this study, Cu and Al are added to a Mg–6Sn–1Mn base alloy. The age-hardening response and the microstructures of these modified alloys have been investigated and are compared to that of the base alloy. The additional elements are found to bring several beneficial effects to the alloys for applications at elevated temperatures. Firstly, a eutectic structure consisting of strong intermetallic phases, i.e. Mg₂Cu in the Mg–6Sn–1Mn–2Cu alloy and Al_0.93Cu_1.07Mg in the Mg–6Sn–1Mn–2Cu–2Al alloy, remains stable along the grain boundaries after solution and ageing heat treatments. Secondly, the precipitate density has been increased significantly and the precipitate size has been refined remarkably during ageing at 200?°C. Moreover, the growth of the precipitates is inhibited remarkably during the over-ageing period. Therefore, the age-hardening response and over-ageing resistance are notably improved.     

Interplay of diffusion and phase transformations in microstructural evolution of the interaction zone between U–9 wt.% Mo and Zr–1 wt.% Nb alloys

Metallurgical interaction between U–9?wt.% Mo metallic fuel alloy and Zr–1?wt.% Nb clad material has been assessed. Interdiffusion of constituent elements across their interface, together with the phase reactions occurring at high temperature and during subsequent cooling, resulted in development of a layered interaction zone where coexistence of a bcc solid solution phase with varying compositions, along with α-U, α-Zr and Mo₂Zr phases could be noticed.     

Influence of heat treatment on the microstructural evolution of Al–3 wt.% Cu during high-pressure torsion

Solution-treated, peak-aged and overaged samples of the model alloy Al–3?wt.% Cu, obtained by selective heat treatments of the pre-material, have been subjected to high-pressure torsion at room temperature and at 200?°C. The mechanical behaviour of the samples was investigated with torque measurements during deformation and microhardness measurements after deformation. Irrespective of the initial material condition, in the saturation regime a comparable equilibrium microstructure was found consisting of ultrafine aluminium grains stabilized by precipitates formed at grain boundaries.