Amorphization of cubic zirconia by caesium-ion implantation

Stabilized cubic zirconia is a promising candidate material for use as an inert fuel matrix for 'burning' excess Pu in light-water nuclear reactors. Zirconia is also considered to be an excellent nuclear waste form for direct geological disposal. Both applications are based on zirconia's high solubility for actinides, high chemical durability and high stability under irradiation. We report the first evidence of solid-state amorphization of yttria-stabilized cubic zirconia (YSZ) by 400keV Cs-ion implantation to 1 x 10²¹ ions m^-2 at room temperature. Amorphization of YSZ is caused by the large size incompatibility and low mobility of Cs ions in the YSZ structure, reflecting a relatively low solubility of Cs in YSZ. Nevertheless, the Cs concentration at which amorphization of YSZ occurred (about 8at.%) is well above the value that will typically be reached in an inert fuel matrix.     

Structure of a phase induced with Xe-ion irradiation-implantation in γ-TiAl

A phase transformation in γ-TiAl intermetallic alloy was found to be induced with 50keV Xe-ion irradiation-implantation at doses larger than 2.2 x 10¹⁸ ions m^-2 at room temperature. The structure and the chemical composition of the induced phase were investigated with high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy. The zones of the induced phase have sizes up to about several tens of nanometres. The phase has a hexagonal structure with a = 0.286 nm and c = 0.462nm. The crystallographic orientation relationship between the phase (P) and the gamma-TiAl matrix is (001)_P//(111)_γ and \[100]_P//[011]_γ. The \[Al]/[Ti] atomic composition ratio in the phase is analysed to be 56/44, slightly different from that of the matrix, 51/49. These results suggest that the induced phase is an Al solid solution of α-Ti alloy phase, which has different structural parameters and chemical composition from those of the reported phase. It is suggested that the size of the ions is important in the phase transformation.     

Interpretation of the low-temperature photoconductivity in a-Si

Abstract

The paper is concerned with the interpretation of steady-state photoconductivity results on undoped a-Si at temperatures of 50K and below which lead to an essentially constant value of the (photogeneration efficiency x mobility x lifetime) product νμτ?10^?11 cm² V^?1. Measurements on p⁺-i-n⁺ junctions and Cr-i-n⁺ barriers were carried out to determine the above parameters separately: (i) steadystate reverse saturation currents gave a generation efficiency of ν? 5×10-² below 50K, suggesting that geminate recombination limits the generation process. (ii) the electron drift mobility μ_e through the tail states and the charge extracted from the absorption region of the incident light were investigated by transient experiments, these showed that μ_eτ_a is limited to about 3×10^?10cm²V^?1 at low T. The independent results account for the observed νμτ values and suggest that, contrary to the interpretation of Hoheisel, Carius and Fuhs (1984), the main contribution to the low-temperature photoconductivity arises from transport in tail states.     

Dislocation dissociation and stacking-fault energies in Ge1-xSix alloys

Dislocations in deformed Ge_1-xSi_x alloys in the whole range 0 < x < 1 have been investigated by means of weak-beam transmission electron microscopy. They are dissociated into Shockley partial dislocations bounding intrinsic stacking-faults. The intrinsic stacking-fault energy in the alloys decreases from 61 +/- 10 to 55 +/- 10 mJm^-2 with increasing Si content.     

Strain localization in nickel single crystals cyclically deformed at 77 K

Nickel monocrystals oriented for single slip have been cyclically deformed at 77 K at plastic strain amplitude between 5 x 10^-4 and 1 x 10^-2 up to saturation of the stress amplitude. After unloading from maximum compression, the slip markings on the surface of the specimens were removed and the deformation continued for one half cycle in tension. As previously observed for room-temperature deformation, the plastic strain was found to be localized in narrow slip bands (SBs). Using atomic force microscopy at a given imposed strain amplitude, a wide spectrum of local plastic strains was found. The averaged resolved shear strain of the SBs was found to be independent of the imposed plastic strain amplitude and turned out to be a factor of three larger than the upper plateau strain limit of the cyclic stress-strain curve.     

Simplified semantics for relevant logics (and some of their rivals)

This paper continues the work of Priest and Sylvan inSimplified Semantics for Basic Relevant Logics, a paper on the simplified semantics of relevant logics, such asB ⁺ andB. We show that the simplified semantics can also be used for a large number of extensions of the positive base logicB ⁺, and then add the dualising^* operator to model negation. This semantics is then used to give conservative extension results for Boolean negation.     

The Poznań school methodology of idealization and concretization from the point of view of a revised structuralist theory conception

My thesis is that some methodological ideas of the Pozna school, i.e., the principles of idealization and concretization (factualization), and the correspondence principle can be represented rather successfully using the relations of theoretization and specialization of revised structuralism.Let <n(i), t(j)> (i=1,...m, j=1,...k) denote the conceptual apparatus of a theory T, and a class M={} (i=1,...m, j=1,...k) the models of T. The n-components refer to the values of dependent variables and t-components to the values of independent variables of the theory. The n- and t-components in turn represent appropriate concepts. Consider T ^* as a conceptual enrichment of T with concepts <n(i ^*), t(j ^*)> (i<i ^* or j<j ^*) and models M ^*={<D ^*, n(i ^*), t(j ^*)>}. If the classes M and M ^* are suitably related, then the situation illustrates both the case of the theoretization-relation of (revised) structuralism and of the factualization-principle of the Pozna school.Assume now that the concepts n(i), t(j) of T for some i, j are operationalized using some special assumptions generating appropriate empirical values n and t for these concepts. Let M denote the class {<D,...n,...t,...>} which is formed by substituting n and t for values of concepts n(i), t(j) in the elements of M. If the classes M and M are related in a suitable way then the situation is an example of both the specialization-relation of (revised) structuralism and the concretization-principle of the Pozna school. The correspondence principle in turn can be represented as a limiting case of the theoretization-relation of (revised) structuralism.Many thanks to my anonymous referees for critical and fruitful comments and special thanks to Dr. Carol Norris for correcting the language of this paper.     

Many-Valued Points And Equality

In 1999, da Silva, D'Ottaviano and Sette proposed a general definition for the term translation between logics and presented an initial segment of its theory. Logics are characterized, in the most general sense, as sets with consequence relations and translations between logics as consequence-relation preserving maps. In a previous paper the authors introduced the concept of conservative translation between logics and studied some general properties of the co-complete category constituted by logics and conservative translations between them. In this paper we present some conservative translations involving classical logic, Lukasiewicz three-valued system L ₃, the intuitionistic system I ¹ and several paraconsistent logics, as for instance Sette's system P ¹, the D'Ottaviano and da Costa system J ₃ and da Costa's systems C _n, 1 n.     

Gleason's Theorem Has a Constructive Proof

Gleason's theorem for R ³ says that if f is a nonnegative function on the unit sphere with the property that f(x) + f(y) + f(z) is a fixed constant for each triple x,y,z of mutually orthogonal unit vectors, then f is a quadratic form. We examine the issues raised by discussions in this journal regarding the possibility of a constructive proof of Gleason"s theorem in light of the recent publication of such a proof.     

Dislocation arrangements and crystallographic characterization of deformation band in fatigued copper single crystal

This letter reveals the dislocation arrangements and crystallographic characterization of deformation bands (denoted DBII) in a copper single crystal fatigued at a high strain amplitude gamma_pl = 8 x 10^-3. The results show that the surface deformation morphology of the crystal displays the following features. (1) Primary slip bands (SBs) were formed after 2 x 10⁴ cycles and these carried a relatively homogeneous and small plastic strain. (2) Secondary slip bands did not operate during cyclic deformation. (3) Deformation bands (DBs) with a width of 50 mum were homogeneously distributed over the whole surface of the crystal and were perpendicular to the SBs. (4) Dislocation patterns within the SBs often consisted of irregular structures, which did not show a persistent feature. The results indicate that these SBs are not typical persistent slip bands (PSBs). (5) Within the DBII, the microstructure can be classified into two types. One type consists of regular 100% ladder-like parallel PSBs. The other type is full of dislocation walls parallel to DB direction, which have not been reported previously. By crystallographic analysis of the DBII, it is shown that the habit plane of the DBII should correspond to the (101) plane. Based on the observations above, it is suggested that the formation of DBII should be attributed to the local regularization of dislocation walls within primary slip bands.     

An effective fixed-point theorem in intuitionistic diagonalizable algebras

Summary Within the technical frame supplied by the algebraic variety of diagonalizable algebras, defined by R. Magari in [2], we prove the following:LetT be any first-order theory with a predicate Pr satisfying the canonical derivability conditions, including Löb's property. Then any formula inT built up from the propositional variables q, p₁, ..., p_n, using logical connectives and the predicate Pr, has the same fixed-points relative to q (that is, formulas (p₁ ..., p_n) for which for all p₁, ..., p_n T((p₁, ..., p_n), p₁, ..., p_n) (p₁, ..., p_n)) of a formula ^* of the same kind, obtained from in an effective way.Moreover, such ^* is provably equivalent to the formula obtained from substituting with ^* itself all the occurrences of q which are under Pr. In the particular case where q is always under Pr in , ^* is the unique (up to provable equivalence) fixedpoint of .Since this result is proved only assumingPr to be canonical, it can be deduced that Löb's property is, in a sense, equivalent to Gödel's diagonalization lemma.All the results are proved more generally in the intuitionistic case.The algebraization of the theories which express Theor, IXAllatum est die 19 Decembris 1975     

Graded modalities. III (the completeness and compactness of S40)

We go on along the trend of [2] and [1], giving an axiomatization of S4 ⁰ and proving its completeness and compactness with respect to the usual reflexive and transitive Kripke models. To reach this results, we use techniques from [1], with suitable adaptations to our specific case.The present work was carried out while the author had a grant of the Foundation U. Bordoni.     

Effects of Ag and Pd on the nucleation and growth of the nano-icosahedral phase in Zr65Al7.5Ni10Cu7.5M10 (M = Ag or Pd) metallic glasses

The nucleation and growth of a nano-icosahedral phase from a supercooled liquid region of Zr₆₅Al_7.5Ni₁₀Cu_7.5M₁₀ (M = Ag or Pd) glasses have been examined by differential scanning calorimetry and transmission electron microscopy. The growth rate of the icosahedral phase is nearly constant at the initial stage and much slower than that of the Zr₂Ni phase in the Zr₆₅Al_7.5Ni₁₀Cu_17.5 metallic glass. The homogeneous nucleation rate has a maximum value of 4.4 x 10²⁰ m^-3 s^-1 at 695 K in the Zr₆₅Al_7.5Ni₁₀Cu_7.5Ag₁₀ glass, which is approximately 10² times higher than that for the formation of quasicrystalline phase in the Zr_69.5Al_7.5Ni₁₁Cu₁₂ glass and 10⁴ times higher than that of the Zr₂Ni phase in the Zr₆₅Al_7.5Ni₁₀Cu_17.5 glass. With increasing Pd content, the nucleation rate of the primary phase increases significantly and the growth rate decreases at the crystallization temperature. Thus, the addition of Ag and Pd is effective for an increase in the number of nucleation sites and the suppression of grain growth, which is the main reason for the formation of icosahedral nanoparticles. The significant increase in the nucleation rate is due to an increase in the number of nucleation sites resulting from the short-range ordering consisting of Zr-(Ag or Pd) strong pairs. It is implied that the strong pair Zr-(Ag or Pd) also contributes to the restraint of the long-range rearrangements of the constitutional elements. The formation of the nanoicosahedral phase suggests that icosahedral short-range order exists in the glassy state in the present alloys.     

Strain rate response of a Ni–Ti shape memory alloy after hydrogen charging

In this work, we investigate the susceptibility of Ni–Ti superelastic wires to the strain rates during tensile testing after hydrogen charging. Cathodic hydrogen charging is performed at a current density of 10?A/m² during 2–12?h in 0.9% NaCl solution and aged for 24?h at room temperature. Specimens underwent one cycle of loading-unloading reaching a stress value of 700 MPa. During loading, strain rates from 10^?6 to 5?×?10^?2?^?s^?1 have been achieved. After 8?h of hydrogen charging, an embrittlement has been detected in the tensile strain rate range of 10^?6 to 10^?4?s^?1. In contrast, no embrittlement has been detected for strain rates of 10^?3?s^?1 and higher. However, after 12?h of hydrogen charging and 24?h of annealing at room temperature, the embrittlement occurs in the beginning of the austenite-martensite transformation for all the studied strain rate values. These results show that for a range of critical amounts of diffused hydrogen, the embrittlement of the Ni–Ti superelastic alloy strongly depends on the strain rate during the tensile test. Moreover, it has been shown that this embrittlement occurs for low values of strain rates rather than the higher ones. This behaviour is attributed to the interaction between the diffused hydrogen and growth of the martensitic domain.     

Mindfulness on Daily Life Coping in People Experiencing Psychosis: A Randomized Controlled Trial

Background/ObjectiveCognitive Behavior Therapy for psychosis (CBTp) is a recommended treatment for psychoses whose effect is mediated by coping. Mindfulness (MBI) have shown positive effects in psychosis. This study examines the hypothesis that combining CBTp+MBI could improve coping with day-to-day life in psychosis better than CBTp alone in people attending a public community rehabilitation center.MethodFifty-six outpatients were recruited and randomly allocated either to CBTp or CBTp+MBI. Measures comprised PANSS interview and COPE Inventory. Data were analyzed using a repeated measures ANOVA and RCI calculation.ResultsThere were no statistical differences between groups at pre-treatment. Significant statistical differences were found for the interaction Treatment x Time in Mental disengagement (F = 5.65, p = .021, η² = .102), Acceptance (F = 7.69, p = .008, η² = .133), and Suppressing competing activities (F = 4.62, p = .037, η² = .085).ConclusionsMBI promotes specific coping styles in people who experience psychosis that otherwise are not improved with CBTp. Only the MBI group improved acceptance of the presence of the stressor and reduced mental disengagement from the context. The intervention is feasible and effective for public healthcare settings.     

Stable icosahedral quasicrystals in the Ag-In-Ca,Ag-In-Yb,Ag-In-Ca-Mg and Ag-In-Yb-Mg systems

On the basis of the idea that a quasicrystal is a compound in which the average number of valence electrons per atom is around 2.0 and that its formation is dominated by atom size, stable icosahedral quasicrystals have been successfully synthesized in Ag-In-Ca, Ag-In-Yb, Ag-In-Ca-Mg and Ag- In-Yb-Mg systems. The Ag-In-Ca and Ag-In-Yb icosahedral quasicrystals have stoichiometry around Ag 42 In 42 Ca 16 and Ag 42 In 42 Yb 16 . The Ag-In-Ca-Mg and Ag-In-Yb-Mg quasicrystals form in the composition ranges Ag42 x /2 In 42 x /2 Ca 16 Mg x ( x =0-7.5 at.%) and Ag 42 x /2 In 42 x /2 Yb 16 Mg x ( x =0-10 at.%). Electron diffraction studies confirmed that the icosahedral quasicrystals have a primitive lattice. The average number of valence electrons per atom in all these quasicrystals is 2.0.     

Neural substrates of reduced walking activity after supratentorial stroke: A voxel-based lesion symptom mapping study

BackgroundMost stroke patients exhibit low levels of walking activity, a key component of secondary stroke prevention. The predictors of walking activity may be multifactorial and are thus far partially understood. We aimed to study the neuroanatomic correlates of low levels of daily walking activity following hemispheric stroke.MethodsIn this cross-sectional study, 33 community-dwelling stroke survivors (age: 63.9 ± 12.9 years; % female: 36.4%; NIHSS at admission: 3.3 ± 4.0) were prospectively recruited at least 3 months after a first ever, unilateral, supratentorial stroke confirmed by brain magnetic resonance imaging. Walking activity was measured by daily step counts (steps∙day⁻¹), recorded using an Actigraph GT3x+ triaxial accelerometer over 7 consecutive days. Voxel-based lesion-symptom mapping was performed to identify brain areas associated with walking activity following stroke.ResultsParticipants presented 4491.9 ± 2473.7 steps∙day⁻¹. Lower levels of walking activity were related to lesions of the posterior part of the putamen, of the posterior limb of the internal capsule and of the anterior part of the corona radiata. No cortical region was associated with walking activity.ConclusionsOur preliminary results identify subcortical neuroanatomical correlates for reduced walking activity following stroke. If confirmed, these results could serve as a rationale for the development of targeted rehabilitative strategy to improve mobility after stroke.     

Hopping in a Gaussian distribution of energy states: Transition from dispersive to non-dispersive transport

Abstract

By means of Monte Carlo simulation techniques the relaxation of a packet of charge carriers migrating in a Gaussian density of states of width σ has been studied. The relaxation time determines the transition from dispersive to non-dispersive transport seen in a time-of-flight signal. For a 10 μm thick sample under a bias field of 10⁵ V cm^?1 the critical disorder parameter σ/kT turns out to be 4·4. Consistency with experimental results from polymers is found.