Vortex dynamics in La1.86Sr0. 14CuO4 studied by magnetoresistivity

Abstract

Vortex dynamics in La_1.86Sr_0.14CuO₄ have been studied by the measurement of ρ_c ^//i (T, H), where ρ_c ^//i is the c-axis resistivity for H//i (i = c or a-b). We argue that, at temperatures higher than the irreversibility temperature T _irr, the usual vortex picture breaks down owing to the thermal motion of vortices, resulting in a T- and T _in-dependent anisotropic parameter γ. After taking into account the dependence of γ on T and T _irr, we show that at each given temperature we can rescale the ρ_c ^//a-b (T, H) data onto the corresponding ρ_c ^//c (T, H) curves. This scaling property clearly indicates that the Lorentz-force-free mechanism is responsible for ρ_c ^//a-b (T, H). Furthermore, we also show that the measured ρ_c ^//a-b (T, H) data can be explained in terms of the recently developed extended Josephson coupling model which is verified by rescaling ρ_c ^//a-b (T) data for various fields onto a single curve.     

Thermal stability and glass-forming ability of Se80− x Te20Ag x (x = 0, 3, 5, 7 and 9) chalcogenide glasses

The thermal stability and glass-forming ability (GFA) of Se_{80? x} Te₂₀Ag _x (x?=?0,?3,?5,?7 and 9) chalcogenide glasses have been investigated using differential scanning calorimetry (DSC). The DSC runs have been taken at five different heating rates (10, 20, 30, 40 and 50?K/min) under non-isothermal condition. The thermal stability and GFA are monitored through determination of the temperature difference ΔT?=?T _c???T _g, where T _c is the onset crystallization temperature, T _g is the glass transition temperature, H ^l is the stability parameter, ΔH _c is the enthalpy released during crystallization and F _i is the fragility index. The activation energy of crystallization E _c and crystallization rate factor K have also been determined as indicators of the thermal stability of the above-mentioned samples. It is found that Se₇₁Te₂₀Ag₉ is the most stable among all the samples of the series.     

The order–dsorder transition at twin boundaries in Cu3Au as studied by TEM

Abstract

The order-disorder phase transition at ∑ = 3{111}- and {211}-type twin boundaries has been studied in the L1²-ordered alloy Cu³Au employing in situ heating in a transmission electron microscope. Evidence is presented for an order-disorder phase transition occurring in these boundaries prior to the bulk transition. The temperature difference ΔT between the transition temperature of both boundary types and the bulk is estimated as 0.5K <ΔT<2K. No difference in T _c for the twin boundaries can be established as yet. The nature of the order-disorder transition in both twin boundaries is presumably a second-order phase transition.     

Analysis of the relation between structure and the superconducting transition in YBa2 Cu3 O∼7

Abstract

It is shown that in the high-T_c YBa₂ Cu₃ O_～7 superconductor the critical temperature is a function of the orthorhombic distortion (b–a)/a of the unit cell. From the extrapolation of the (b - a)/a ratio against T_c , a maximum critical temperature of 66 K for the tetragonal phase of YBa₂ Cu₃ O_～7 was predicted. From the correlation between the transition width δT_c and the orthorhombic distortion there was deduced an upper limit for T_c , in the orthorhombic phase of YBa₂ Cu₃ O_～7 of 94·5K.     

Ensuring Positiveness of the Scaled Difference Chi-square Test Statistic

A scaled difference test statistic [(T)\tilde]_d\tilde{T}{}_{d} that can be computed from standard software of structural equation models (SEM) by hand calculations was proposed in Satorra and Bentler (Psychometrika 66:507–514, 2001). The statistic [(T)\tilde]_d\tilde{T}_{d} is asymptotically equivalent to the scaled difference test statistic [`(T)]<sub>d</sub>\bar{T}_{d} introduced in Satorra (Innovations in Multivariate Statistical Analysis: A Festschrift for Heinz Neudecker, pp. 233–247, 2000), which requires more involved computations beyond standard output of SEM software. The test statistic [(T)\tilde]<sub>d</sub>\tilde{T}_{d} has been widely used in practice, but in some applications it is negative due to negativity of its associated scaling correction. Using the implicit function theorem, this note develops an improved scaling correction leading to a new scaled difference statistic [`(T)]_d\bar{T}_{d} that avoids negative chi-square values.     

Hybridization-induced wide-band bipolaron model for high-Tc superconductors

Abstract

A microscopic theory based on the idea of hybridization-induced wide-band bipolarons is proposed to explain the occurrence of high-temperature superconductors such as La_2?x-Ba_xCuO₄, and La_2?xSr_xCuO₄. In our view, these are such that bipolarons are formed whose singlet ground state possesses a large binding energy (Δ) with bandwidth W (>Δ) as a result of two distinct electron-phonon mechanisms and two types of hybridization between Cu²⁺ d electrons and other electrons. This wide-band bipolaron gas has features similar to Cooper pairs and leads to a superconducting state with high T_c in which all occupied electron states participate. The large electron-phonon coupling and a large W both cause the transition temperature T_c, to rise spectacularly.     

A 2-categorial Generalization of the Concept of Institution

After defining, for each many-sorted signature Σ = (S, Σ), the category Ter(Σ), of generalized terms for Σ (which is the dual of the Kleisli category for \mathbb T_S{\mathbb {T}_{\bf \Sigma}}, the monad in Set ^S determined by the adjunction T_S \dashv G_S{{\bf T}_{\bf \Sigma} \dashv {\rm G}_{\bf \Sigma}} from Set ^S to Alg(Σ), the category of Σ-algebras), we assign, to a signature morphism d from Σ to Λ, the functor d_à{{\bf d}_\diamond} from Ter(Σ) to Ter(Λ). Once defined the mappings that assign, respectively, to a many-sorted signature the corresponding category of generalized terms and to a signature morphism the functor between the associated categories of generalized terms, we state that both mappings are actually the components of a pseudo-functor Ter from Sig to the 2-category Cat. Next we prove that there is a functor Tr^Σ, of realization of generalized terms as term operations, from Alg(Σ) × Ter(Σ) to Set, that simultaneously formalizes the procedure of realization of generalized terms and its naturalness (by taking into account the variation of the algebras through the homomorphisms between them). We remark that from this fact we will get the invariance of the relation of satisfaction under signature change. Moreover, we prove that, for each signature morphism d from Σ to Λ, there exists a natural isomorphism θ ^d from the functor Tr^L °(Id ×d_à){{{\rm Tr}^{\bf {\bf \Lambda}} \circ ({\rm Id} \times {\bf d}_\diamond)}} to the functor Tr^S °(d^* ×Id){{\rm Tr}^{\bf \Sigma} \circ ({\bf d}^* \times {\rm Id})}, both from the category Alg(Λ) × Ter(Σ) to the category Set, where d* is the value at d of the arrow mapping of a contravariant functor Alg from Sig to Cat, that shows the invariant character of the procedure of realization of generalized terms under signature change. Finally, we construct the many-sorted term institution by combining adequately the above components (and, in a derived way, the many-sorted specification institution), but for a strict generalization of the standard notion of institution.     

Effect of network connectivity on thermal properties of As30Te70– x Tl x glasses

Alternating differential scanning calorimetry (ADSC) studies were undertaken to investigate the effect of Tl addition on the thermal properties of As₃₀Te_{70– x} Tl _x (6?≤?x?≤?22 at%) glasses. These include parameters such as glass-transition temperature (T _g), changes in specific heat capacity (ΔC _p) and relaxation enthalpy (ΔH ^NR) at the glass transition. It was found that T _g of the glasses decreased with the addition of Tl, which is in contrast to the dependence of T _g in As–Te glasses on the addition of Al and In. The change in heat capacity ΔC _p through the glass transition was also found to decrease with increasing Tl content. The addition of Tl to the As–Te matrix may lead to a breaking of As–Te chains and the formation of Tl⁺Te^?AsTe_2/2 dipoles. There was no significant dependence of the change of relaxation enthalpy, through the glass transition, with composition.     

Tension-compression-tension tertiary twins in coarse-grained polycrystalline pure magnesium at room temperature

Using electron backscatter diffraction, the microstructural features of tension–compression–tension (T–C–T) tertiary twins are studied in coarse-grained pure polycrystalline magnesium subjected to monotonic compression along the extrusion direction in ambient air. T–C–T tertiary twins are developed due to the formation of a compression–tension double twin inside a primary tension twin. All the observed T–C–T twin variants are of T_iC_jT_j type. T_iC_i+1T_i+1 (or T_iC_i?1T_i?1) variants are observed more frequently than T_iC_i+2T_i+2 (or T_iC_i?2T_i?2) variants. The number of tertiary twin lamellae increases with the applied compressive strain.     

Pressure-Induced transitions in amorphous TlxSe100−x alloys

Abstract

The electrical resistivity of bulk semiconducting amorphous Tl_xSe_100?x alloys with 0 ≤ x ≤ 25 has been investigated up to a pressure of 14 GPa and down to liquidnitrogen temperature by use of a Bridgman anvil device. All the glasses undergo a discontinuous pressure-induced semiconducting-to-metal transition. X-ray diffraction studies on the pressure-recovered samples show that the high-pressure phase is the crystalline phase. The pressure-induced crystalline products are identified to be a mixture of Se having a hexagonal structure with a = 4·37 Å and c = 4·95 Å and TlSe having a tetragonal structure with a = 8·0 Å and c = 7·0 Å     

Two simple approximations to the distributions of quadratic forms

Many test statistics are asymptotically equivalent to quadratic forms of normal variables, which are further equivalent to with z_i being independent and following N(0,1). Two approximations to the distribution of T have been implemented in popular software and are widely used in evaluating various models. It is important to know how accurate these approximations are when compared to each other and to the exact distribution of T. The paper systematically studies the quality of the two approximations and examines the effect of the λ_i and the degrees of freedom d by analysis and Monte Carlo. The results imply that the adjusted distribution for T can be as good as knowing its exact distribution. When the coefficient of variation of the λ_i is small, the rescaled statistic is also adequate for practical model inference. But comparing T_R against will inflate type I errors when substantial differences exist among the λ_i, especially, when d is also large.     

Effect of heterogeneous solute distribution on the anomalous thermomechanical response of Cu–Ni alloy single crystals below 50 K

The anomalous temperature dependence of the critical resolved shear stress (CRSS) of Cu–Ni alloys observed below a certain temperature, T _o?=?50?K, has been accounted for by introducing a stress-concentration factor f(T)?=?[(T?′?+?T _o)/(T?′?+?T)] in the monotonic CRSS–T formulation of the kink-pair nucleation model of solid-solution hardening. The empirical constant T?′ is found to depend not only on the solute concentration, c, but also on the nature of the solute distribution in the host lattice. It is found that the solute distribution is random for c?≤?14 at.% Ni in the Cu lattice and for c?≤?20 at.% Cu in the Ni lattice, whereas some sort of local ordering occurs for all other values of solute concentration.     

Approximant phases,phason planes and domain-boundary networks in Al−Ni−Rh alloys

Structurally complicated ξ′- and ξ-phases have been found, for the first time, in as-cast Al₇₃Ni₅Rh₂₂ and Al₇₅Ni₁₅Rh₁₀ alloys. The lattice parameters of these two phases were determined by means of electron diffraction and high-resolution transmission electron microscopy (HREM). These two phases have similar orthorhombic structures but with different lattice parameters of a?=?23.2?Å, b?=?16.4?Å, c?=?12.0?Å for the ξ′-phase and a?=?20.3?Å, b?=?16.4?Å, c?=?14.8?Å for the ξ-phase. A new two-dimensional domain-boundary network has also been observed in these two phases. Domain boundaries with normals closely parallel to the [001] direction are actually phason planes represented by a translation vector of r?=(1/2)a?+(1/2τ)c in the ξ′-phase and r=±(1/2τ²) a?+(τ/2)c in the ξ-phase, whereas the newly-found wide and zigzag boundaries perpendicular to the above set were attributed from the step-like boundary structures of domains related by a translation vector of r?=(1/τ)((1/2)a?+(1/2τ)c). The structural difference between the two types of planar faults is discussed.     

The temperature dependence of the optical dispersion parameters in Si and Ge

Abstract

In Si and Ge, the optical dispersion parameters (single-oscillator energy E_o , dispersion energy E_d and bond energy gap E_g developed by Wemple and DiDomenico, and Phillips) have been analysed in the temperature range 100-300 K using data obtained by Icenogle et al. E_o and E_g exhibit a very small temperature dependence in both materials. The thermal coefficients of the dispersion energy, dE_d/dT, have opposite signs (Si, –41·9 × 10^?4eVK^?1; Ge, +37·7 × 10^?4eVK^?1).     

Stability in ordered and icosahedral aluminium–transition metal alloys

Abstract

We present calculated electron state densities for A1T (T is a transition metal) compounds and icosahedral Al₈₆T₁₄ alloys which suggest that the relative stability of different short-range atomic arrangements varies inversely with the electron state density at the Fermi level. Using this argument, we show that the absence ofstable highly coordinated configurations is a necessary, but not sufficient, condition for the existence of icosahedral Al₈₆T₁₄ alloys.     

Virtual Modality

Model-theoretic 1-types overa given first-order theory T may be construed as natural metalogical miniatures of G. W. Leibniz' ``complete individual notions', ``substances' or ``substantial forms'. This analogy prompts this essay's modal semantics for an essentiallyundecidable first-order theory T, in which one quantifies over such ``substances' in a boolean universe V(C), where C is the completion of the Lindenbaum-algebra of T.More precisely, one can define recursively a set-theoretic translate of formulae _N of formulae of a normal modal theory T_m based on T, such that the counterpart `<sub>i</sub>' of a the modal variable `x_i' of L(T_m) in this translation-scheme ranges over elements of V(C) that are 1-types of T with value 1 (sometimes called `definite' C-valued 1-types of T).The article's basic completeness-result (2.13) then establishes that varphi; is a theorem of T<sub>m</sub> iff [[ <sub>N</sub> () is aconsequenceof <sub>N</sub> (T<sub>m</sub>) for each extension N of T which is a subtheory of the canonical generic theory (ultrafilter) u]] = 1 – or equivalently, that T<sub>m</sub> is consistent iff[[there is anextension N of T such that N is a subtheory of the canonical generic theory u, and <sub>N</sub>() for all in T<sub>m</sub>]] > 0.The proof of thiscompleteness-result also shows that an N which provides a countermodel for a modally unprovable – or equivalently, a closed set in the Stone space St(T) in the sense of V(C) – is intertranslatable with an `accessibility'-relation of a closely related Kripke-semantics whose `worlds' are generic extensions of an initial universe V via C.This interrelation providesa fairly precise rationale for the semantics' recourse to C-valued structures, and exhibits a sense in which the boolean-valued context is sharp.     

Causal inferences as perceptual judgments

We analyze how subjects make causal judgments based on contingency information in two paradigms. In the discrete paradigm, subjects are given specific information about the frequency a, with which a purported cause occurs with the effect; the frequency b, with which it occurs without the effect; the frequency c, with which the effect occurs when the cause is absent; and the frequency d, with which both cause and effect are absent. Subjects respond toP ₁ =a/(a+b) andP ₂ =c/(c+d). Some subjects’ ratings are just a function ofP ₁, while others are a function of ΔP =P ₁ -P ₂. Subjects’ postexperiment reports are accurate reflections of which model they use. Combining these two types of subjects results in data well fit by the weighted ΔP model (Allan, 1993). In the continuous paradigm, subjects control the purported causes (by clicking a mouse) and observe whether an effect occurs. Because causes and effects occur continuously in time, it is not possible to explicitly pair causes and effects. Rather, subjects report that they are responding to the rate at which the effects occur when they click versus when they do not click. Their ratings are a function of rates and not probabilities. In general, we argue that subjects’ causal ratings are judgments of the magnitude of perceptually salient variables in the experiment.     

Cohen's d Corrected for Case IV Range Restriction: A More Accurate Procedure for Evaluating Subgroup Differences in Organizational Research

Organizational and staffing researchers are often interested in evaluating whether subgroup differences exist (e.g., between Caucasian and African‐American individuals) on predictors of job performance. To investigate subgroup differences, researchers often will collect data from current employees to make inferences about subgroup differences among job applicants. However, the magnitude of subgroup differences (i.e., Cohen's d) within incumbent samples may be different (i.e., smaller) than the magnitude of subgroup differences in applicant samples because selection of applicants typically reduces the variance of scores on the predictors (i.e., because lower scoring applicants are not selected). If researchers seek to generalize a d value in an incumbent sample to the applicant population, they may use Bobko, Roth, and Bobko's (correcting the effect size of d for range restriction and unreliability, 2001) Case II or III correction. By extension, Hunter, Schmidt, and Le (implications of direct and indirect range restriction for meta‐analysis methods and findings, 2006) have proposed a Case IV correction, which is more realistic than Bobko et al.'s approach. Therefore, this paper develops a Case IV correction for d (i.e., d_c4). The simulation results showed that the d_c4 was generally accurate across 6,000 simulation conditions. Moreover, 2 published datasets were reanalyzed to show the influence of the Case IV correction on d. In addition, implications and future directions of the d_c4 are discussed.     

Size effects and Hall–Petch relation in polycrystalline cobalt

The mechanical behaviour of polycrystalline hexagonal close-packed cobalt was investigated over a large range of grain size d in order to examine the occurrence of size effects. Crystallographic texture and amount of face centred cubic allotropic phase were maintained unchanged thanks to appropriate heat treatment procedures. The Hall–Petch (HP) relation exhibits two distinct behaviours from the very beginning of plastic strain levels. The conventional HP law is fulfilled for a number of grains across the thickness t higher than a critical value (t/d)_c = 14. For t/d lower than (t/d)_c, a multicrystalline regime is evidenced highlighting a strong reduction in flow stress. The high value of (t/d)_c is related to the low-stacking fault energy of cobalt in the basal plane. The size effect is predominant in the first work hardening stage where slip mechanisms and stacking faults predominate. In the second stage, driven by mechanical twinning processes, this effect is less sensitive. Finally, the size effect could also affect the end of the elastic stage, in link with nonlinear elasticity mechanisms.