An experimental investigation on a nanoporous carbon functionalized liquid damper

The behaviour of a p-xylene-based lyophobic nanoporous carbon system under high hydrostatic pressures is investigated. As the pressure is increased to a critical value, the nanopore surfaces between graphene layers are exposed to the liquid phase, leading to a considerable increase in solid–liquid interfacial energy. During unloading, defiltration does not occur until the pressure is much lower. Thus, the system is energy absorbing. Owing to the large solid–liquid contact area, the energy absorption efficiency is much higher than that of conventional dampers.     

Thermal effects on infiltration of a solubility-sensitive volume-memory liquid

As the ion density at a solid–liquid interface changes, the interfacial tension varies accordingly, which can lead to a large energy density output, particularly when amplified by the high specific surface area of a nanoporous material. This concept is validated by the results of a controlled-temperature infiltration experiment on a hydrophobic zeolite immersed in a saturated aqueous solution of sodium acetate. As the temperature changes, the sodium acetate concentration varies significantly, which in turn causes a variation in infiltration pressure. Since the infiltration and defiltration are reversible, under the working pressure, this system exhibits a volume memory characteristic, with a non-monotonic temperature–volume relationship.     

Electromechanical behaviour of nanoporous metallic glass

Understanding the electrical and mechanical behaviour of nanoporous materials is critical for their use in energy applications. A palladium-rich nanoporous film, 500 nm thick with pore size ranging from 10 to 50 nm, was obtained by electrochemical dealloying of a Ni–Pd–P–B metallic glass. Nanomechanical and electrical properties were measured simultaneously, as a function of depth, for the nanoporous structure as well as the unaltered metallic glass substrate. The elastic modulus for the nanoporous structure was found to be 22 GPa compared to 131 GPa for the metallic glass substrate. The ratio of moduli scales with the square of the relative density in agreement with linear elasticity models for cellular materials. The electrical resistivity of the nanoporous layer was found to be 2.2 times higher compared to the metallic glass substrate, which was attributed to the tortuosity of current path in cellular structures.     

Effect of a nanoporous surface on photoluminescence from nanopatterned GaN thin films fabricated by anodic alumina templates

GaN photonic crystal slabs on InGaN/GaN multi-quantum well light-emitting diodes have been formed by dry etching using nanoporous anodic alumina templates, which have a periodic lattice constant of 105 nm and a hole diameter of 45 nm. The photonic crystal slab shows an enhanced intensity of photoluminescence due to the nanohole pattern array producing Fabry–Perot like interference. A rough surface of nanoholes results in a broad spectrum with a small oscillation, and well-ordered multiple facets of nanoholes results in a relatively sharp spectrum with a large oscillation.     

The relative energy of fcc and hcp foams

The energies of face-centred cubic (fcc) and hexagonal close-packed (hcp) monodisperse foams, associated with their total surface area, are equal in the wet and dry limits, in the usual model. We prove that for all intermediate values of liquid fraction, hcp has lower energy. Energy considerations are thus not sufficient to explain the observed preference for crystallization into fcc over hcp in experiments using monodisperse bubbles.     

The “pill popper”: A device for drug capsule self-administration by primates

An apparatus for establishing self-administration of drugs in capsule preparation form by nonhuman primates is described. The system includes a capsule loading unit combined with a pressurized liquid dispenser and mouth-operated drinking tube lever. Operation of the mouth lever results in forced ingestion of a capsule or other solid substance and a measured quantity of liquid. The components of the system are separately programmable and adjustable to permit shaping of pressurized liquid and capsule ingestion through successive approximations. Examination of absorption factors and temporal variables associated with delay of drug reinforcement onset, as well as precision in oral dosage, are thus possible in a model which approximates the most common method and features of drug self-administration in humans.     

Surface tension of substantially undercooled liquid Ti–Al alloy

It is usually difficult to undercool Ti–Al alloys on account of their high reactivity in the liquid state. This results in a serious scarcity of information on their thermophysical properties in the metastable state. Here, we report on the surface tension of a liquid Ti–Al alloy under high undercooling condition. By using the electromagnetic levitation technique, a maximum undercooling of 324 K (0.19 T _L) was achieved for liquid Ti-51 at.% Al alloy. The surface tension of this alloy, which was determined over a broad temperature range 1429–2040 K, increases linearly with the enhancement of undercooling. The experimental value of the surface tension at the liquidus temperature of 1753 K is 1.094 N m^?1 and its temperature coefficient is ?1.422 × 10^?4 N m^?1 K^?1. The viscosity, solute diffusion coefficient and Marangoni number of this liquid Ti–Al alloy are also derived from the measured surface tension.     

Thermophysical properties of undercooled liquid cobalt

The surface tension of undercooled liquid cobalt has been measured by the oscillating-drop technique combined with electromagnetic levitation. The accuracy of the method was verified by measurements of the surface tension of liquid nickel. The liquid cobalt was undercooled by up to 231K (0.13T _m), and its surface tension determined to be σ_Co =1875 0.348(T-T _m)mNm^-1. From this result, the viscosity, self-diffusion coefficient, density and thermal diffusivity of undercooled liquid cobalt were derived. Using these thermophysical parameters, the growth velocity of cobalt dendrite is calculated and shown to agree well with experimental results. Furthermore, the Marangoni number and the Rayleigh number are calculated; these increase slowly with increasing degree of undercooling.     

Surface energy of free clusters of bubbles: An estimation

We propose an approximate equation for the surface energy of two-dimensional free bubble clusters which we compare with exact calculations of the surface energy of symmetrical clusters consisting of a central bubble surrounded by one or two shells of bubbles of two different areas. The accuracy of the equation is good for relatively narrow distributions of the areas and of the number of sides of the bubbles but underestimates the energy for large widths of those distributions. We propose a similar approximate equation for the surface energy of three-dimensional clusters.     

Observation of a threshold impact energy required to cause passive film rupture during slurry erosion of stainless steel

The impact of solid particles during the erosion of stainless steel by a slurry jet reveals a sequence of anodic current transients due to individual impacts. Measurement of these current transients shows that there is a minimum particle energy below which no transients can be detected. The result is interpreted as a threshold energy required to rupture the passivating oxide film on the metal surface. If this energy is exceeded, the current transients arise from electrochemical reaction of the depassivated metal surface after denudation. Below this threshold no rupture occurs and there are no current transients.     

THE PRICE OF EXPERTISE:

Abstract— When shown a idled container, people often fail to appreciate that the surface of the liquid contained within should remain horizontal with respect to the ground. This study investigated how amenable this bias is to experience in relevant everyday situations. Surprisingly, liquid surfaces that waitresses and bartenders considered natural deviated even more from horizontal than was the case for comparison groups. This finding is, to our knowledge, the only documented case in which performance declines with experience. We suggest that practical experience promotes a functionally relative perspective, in which the orientation of the liquid's surface is evaluated relative to that of its container as opposed to being related directly to the surrounding environment. The container-relative perspective, in turn, evokes a perceptual bias that is responsible for the systematic errors observed on this task.     

Mixed-valence impurity in a nanoscale particle

We consider a mixed-valence Anderson impurity with infinite U embedded into a small metallic particle. The nanosize of the system leads to discrete energy levels rather than to a continuum of energy eigenstates for the host. Using the Brillouin-Wigner approximation we show that the magnetic susceptibility, which arises from the van Vleck admixing of the magnetic configuration into the ground state, is only weakly affected by the finite spacing of energy levels, while the specific heat and the entropy display an exponential activation at low temperatures, that is have properties deviating from a Fermi liquid.     

A structural model for surface-enhanced stabilization in some metallic glass formers

A structural model for surface-enhanced stabilization in some metallic glass formers is proposed. In this model, the alloy surface structure is represented by five-layer Kagomé-net-based lateral ordering. Such surface structure has intrinsic abilities to stabilize icosahedral-like short-range order in the bulk, acting as ‘a cloak of liquidity’. In particular, recent experimental observations of surface-induced lateral ordering and a very high glass forming ability of the liquid alloy Au₄₉Ag_5.5Pd_2.3Cu_26.9Si_16.3 can be united using this structural model. This model may be useful for the interpretation of surface structure of other liquid alloys with a high glass forming ability. In addition, it suggests the possibility of guiding the design of the surface coating of solid containers for the stabilization of undercooled liquids.     

Spectroscopic studies of a thermochromic centre in synthetic diamonds grown by the temperature-gradient method

Abstract

Synthetic diamonds grown by the temperature-gradient method at temperatures just above the melting point of the solvent-catalyst often have an unattractive dull-green colour. This green colour, which is prominent at room-temperature, disappears if the diamond is cooled to below 120 K and is restored on warming the crystal back to room temperature. We show that the behaviour of the absorption band responsible for the colour is consistent with the transition occurring from the upper level of a centre with a split ground state, for which transitions from the lower level are forbidden. Temperature-dependence measurements indicate that the energy splitting in the ground state is about 50 meV. The broad featureless absorption band, with a maximum near 1·9eV, is assumed to be vibronic in origin. The absence of structure in the band indicates that the electronic transition is strongly coupled to the lattice and, as expected, the zero-phonon line, estimated to be at around 1eV, is too weak to detect. The same absorption band is also shown to be present in some individual crystals of synthetic diamond abrasive grit.     

Temperature-dependent crack surface tension

The fracture surface energy is calculated for a one-dimensional, exactly solvable model of a crack. The temperature dependence of the crack surface tension is determined on the basis of a self-consistent Einstein approach. It is found that lattice vibrations result in a strong reduction in the crack surface tension.     

The Young-Laplace equation associated with transverse shear stress within the surface layer of a solid

ABSTRACT

The Young-Laplace equation was firstly established based on a liquid film without shearing resistance. It is not valid for a solid. By taking into account the in-plane shearing and transverse shearing within a surface layer, we reconstruct the Young-Laplace equation for a solid. This new version shows that the equilibrium of a solid surface is determined by the bulk stress, the surface membrane stress and the transverse shear stress acting together. The transverse shear stress depends on the gradient of the Gaussian curvature of the surface and the strain. The intrinsic membrane stress and transverse shear stress cause residual stresses to appear in the interior of the solid. The intrinsic transverse shear stress occurs only in a non-spherical shaped body.     

Loss of coherency of the alpha/beta interface boundary in titanium alloys during deformation

The loss of coherency of interphase boundaries in two-phase titanium alloys during deformation was analyzed. The energy of the undeformed interphase boundary was first determined by means of the van der Merwe model for stepped interfaces. The subsequent loss of coherency was ascribed to the increase of interphase energy due to absorption of lattice dislocations and was quantified by a relation similar to the Read–Shockley equation for low-angle boundaries in single-phase alloys. It was found that interphase boundaries lose their coherency by a strain of approximately 0.5 at T = 800°C.     

Sensory and Postural input in the Occurrence of a Gender Difference in Orienting Liquid Surfaces

The Psychological Record - In the water-level task, both spatial skill and physical knowledge contribute to representing the surface of a liquid as horizontal irrespective of the container’s...     

Thanks to 2010 Reviewers

Abstract

The electronic conductivity, diffusion coefficient and the self-energy in the vicinity of the energy gap of amorphous Si at T=0K have been computed as a function of energy for a fully bonded model of Si. We have used the equation-of-motion method in κ-space to show, for the first time, the probable position and existence of mobility edges. The conductivity rises rapidly away from the mobility edges to take values typical of those found in liquid metals. The behaviour of the self-energy indicates that a resonance phenomenon is responsible for the formation of a gap.     

Surface tension measurement of undercooled liquid Ni-based multicomponent alloys

The surface tensions of liquid ternary Ni–5%Cu–5%Fe, quaternary Ni–5%Cu–5%Fe–5%Sn and quinary Ni–5%Cu–5%Fe–5%Sn–5%Ge alloys were determined as a function of temperature by the electromagnetic levitation oscillating drop method. The maximum undercoolings obtained in the experiments are 272 (0.15T _L), 349 (0.21T _L) and 363?K (0.22T _L), respectively. For all the three alloys, the surface tension decreases linearly with the rise of temperature. The surface tension values are 1.799, 1.546 and 1.357?N/m at their liquidus temperatures of 1719, 1644 and 1641?K. Their temperature coefficients are ?4.972?×?10^–4, ?5.057?×?10^?4 and ?5.385?×?10^?4?N/m/K. It is revealed that Sn and Ge are much more efficient than Cu and Fe in reducing the surface tension of Ni-based alloys. The addition of Sn can significantly enlarge the maximum undercooling at the same experimental condition. The viscosity of the three undercooled liquid alloys was also derived from the surface tension data.