Dielectric relaxation in ternary systems of alcohols and nitriles in benzene at microwave frequency

The permittivity and the dielectric loss of ternary mixtures of equimolar concentrations of m-cresol, o-cresol with acetonitrile, acrylonitrile and benzonitrile in benzene have been measured at 8.33 GHz and 308 K. The distribution parameter α, the most probable relaxation time τ, the relaxation time for overall rotation of the molecule τ(1), the relaxation time for group rotation τ(2), and the excess dipole moment for various systems have been calculated by the Cole-Cole and Higasi methods. Data has been analyzed in terms of two-relaxation processes: overall rotation and group rotation.     

Dielectric and spectrometric investigations of binary mixtures of tetrahydrofuran with propionic acid

The static permittivity (ε_m ) and the permittivity at the high-frequency limit (ε_∞m ) of a binary mixture of propionic acid with tetrahydrofuran (THF) have been determined for different concentrations at temperatures of 303, 308, 313, and 318 K. The data have been used to compute the Kirkwood correlation factor, the excess permittivity, and the excess free-energy of the mixtures. The Kirkwood correlation factor is found to increase with increasing THF concentration. The mixture exhibited positive values of the excess permittivity and negative values of the excess free-energy of mixing, respectively. UV-Vis and FT-IR spectral measurements have also been carried out. The observed bathochromism and hypochromism in the UV-Vis spectra have been explained in terms of complex formation and ordering of dipoles of the complex. The FT-IR spectrum of the mixture shows considerable shifts in the positions of some of the absorption bands, indicating extensive hydrogen bonding between solute and solvent molecules.     

Dielectric relaxation study of mixtures of alkyl methacrylates and 1-alcohols using time-domain reflectometry

Dielectric relaxation measurements on alkyl methacrylates (methyl methacrylate, ethyl methacrylate and butyl methacrylate) with 1-alcohols (1-propanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) have been carried out using time-domain reflectometry (TDR) over the frequency range 10?MHz to 20?GHz at 303?K for different concentrations of alcohols. The dielectric parameters, namely the static dielectric constant (ε ₀), the dielectric constant at microwave frequencies (ε _∞) and the relaxation time (τ) were determined. The Kirkwood correlation factor, which contains information regarding solute–solvent interaction and corresponding structural information, the excess permittivity and the excess inverse relaxation time were also determined. The values of the static dielectric constant and the relaxation time increase with the percentage of alkyl methacrylates in the alcohol, whereas the static dielectric constant decreases and the relaxation time increases with an increase in the alkyl chain length of both the methacrylates and the alcohols.     

Static dielectric constants of the binary mixtures of N-methylformamide with water,ethyl alcohol,ethylene glycol,dimethylsulphoxide, acetone and 1,4-dioxane

The static dielectric constants of binary mixtures of N-methylformamide (NMF), used as a solute with the solvents water (W), ethyl alcohol (EA), ethylene glycol (EG), dimethyl sulphoxide (DMSO), acetone (Ac) and 1,4-dioxane (Dx), have been measured over the entire concentration range at 30°C. The negative values of excess dielectric constant and less-than-unity values of the corrective Kirkwood correlation factor of these binary mixtures are used to analyse the formation of H-bond complexes and molar ratio of the stable adduct. In these systems, the unassociated mixture constituents, DMSO, Ac and Dx, act as structure-breakers for self-associated linear structures of NMF, whereas, both the self-associated mixture constituents (W, EA and EG mixtures with NMF) act as structure-breakers to each other during the complexations. It is found that the large variations in the strength of H-bond complexation and the effective number of parallel aligned dipoles in the mixtures are governed by the dielectric constant of the solvents.     

A new type of defect on {1120} planes in ß-Si3N4 produced by neutron irradiation

Measurements of static permittivity, refractive index and density have been carried out to study possible H-bonded complexes in solutions of anisole diluted by benzene together with high-static-permittivity alcohols, i.e. cyclohexanol, n-butanol, tert-butanol, isopropyl alcohol and 1-hexanol. The experiments were performed at 303 K. Dipole moments of the mixtures are calculated from the experimental data and these are used to obtain dipolar increments. The concentration ratio of proton donor to proton acceptor is plotted against a parameter, Ω_B, which is determined from experimental data. From the plot, the dipole moment of the mixture and that of the component B are determined. The order of the complex can be obtained from the nature of the graph. The investigation shows that the interaction between the two components arises solely from a polarization effect.     

Preparation and properties of a left-handed metamaterial composite

A left-handed metamaterial (a YIG/Ag composite with adjustable negative permittivity and permeability) was prepared by an in situ synthesis process, and its characterisation, microstructure, electrical conductivity, dielectric loss and magnetic properties studied. A negative permittivity behaviour with a Fano-like resonance is ascribed to plasma oscillation of delocalised electrons from silver conducting networks. As the silver content increases, the turbine loss increases, which greatly enhances the electromagnetic wave consumption capacity inside the material and leads to a stronger electromagnetic absorption and shielding performance. The dielectric loss near the percolation threshold is due to the combined effects of polarisation and conduction. The capacitive character is responsible for positive permittivity, and the inductive character leads to negative permittivity. LC resonance results in the Fano-like resonance, leading to the permittivity changing from negative to positive. Gyromagnetic spin rotation, domain wall motion and percolation characteristic of YIG/Ag composites cause frequency dispersion of the permeability. The YIG/Ag composite with double negative characteristics provides prospects for electromagnetic shielding application.     

The temperature dependence of the optical dispersion parameters in Si and Ge

Abstract

In Si and Ge, the optical dispersion parameters (single-oscillator energy E_o , dispersion energy E_d and bond energy gap E_g developed by Wemple and DiDomenico, and Phillips) have been analysed in the temperature range 100-300 K using data obtained by Icenogle et al. E_o and E_g exhibit a very small temperature dependence in both materials. The thermal coefficients of the dispersion energy, dE_d/dT, have opposite signs (Si, –41·9 × 10^?4eVK^?1; Ge, +37·7 × 10^?4eVK^?1).     

Elemental and non-elemental olfactory learning in Drosophila

Brain complexity varies across many orders of magnitude between animals, and it is often assumed that complexity underpins cognition. It is thus important to explore the cognitive capacity of widely used model organisms such as Drosophila. We systematically investigated the fly’s ability to learn discriminations involving compound olfactory stimuli associated with shock. Flies could distinguish binary mixtures (AB+ CD-), including overlapping mixtures (AB+ BC-). They could learn positive patterning (AB+ A- B-) but could not learn negative patterning (A+ B+ AB-) or solve a biconditional discrimination task (AB+ CD+ AC- BD-). Learning about the elements of a compound (AB+) was not affected by prior conditioning of one of the elements (A+ AB+): flies do not exhibit blocking in this task. We compare these results with the predictions from simulation of several well-known theoretical models of learning, and find none are fully consistent with the overall pattern of observed behaviour.     

Effect of heterogeneous solute distribution on the anomalous thermomechanical response of Cu–Ni alloy single crystals below 50 K

The anomalous temperature dependence of the critical resolved shear stress (CRSS) of Cu–Ni alloys observed below a certain temperature, T _o?=?50?K, has been accounted for by introducing a stress-concentration factor f(T)?=?[(T?′?+?T _o)/(T?′?+?T)] in the monotonic CRSS–T formulation of the kink-pair nucleation model of solid-solution hardening. The empirical constant T?′ is found to depend not only on the solute concentration, c, but also on the nature of the solute distribution in the host lattice. It is found that the solute distribution is random for c?≤?14 at.% Ni in the Cu lattice and for c?≤?20 at.% Cu in the Ni lattice, whereas some sort of local ordering occurs for all other values of solute concentration.     

On excess,trauma and helplessness: Repetitions and transformations

Freud's work establishes a link between an excessive amount of excitation, the infant's experience of helplessness, and trauma. The idea of excess emphasises a quantitative element, not reducible to the field of representation. In this paper I explore the notions of excess and closure in relation to two clinical examples. A patient who lived through experiences of excess and flooding is contrasted with another patient whose experience of excess is expressed through withdrawal. The complex process of elaboration and working through in their analyses takes place by bringing together affect, representation, sensorial and somatic experiences, dreams, associations and enactments as they are gathered and given meaning après coup through analytic work. Two concepts were central to the understanding of what took place in the analyses: excorporation and figurability. The paper emphasizes the place of temporality in creating a triadic space in an analysis as it relates the here and now with the there and then in the work of après‐coup. The paper also traces the roots of this modern approach that relates the analyst's work of regression, time, and the creation of a triadic space to Freud's metapsychology.     

Quasi-two-dimensional or hcp palladium nanoparticles with host-guest interaction prepared at room temperature

Quasi-two-dimensional palladium nanoparticles with an average lateral dimension of 7 nm have been prepared by reduction of a PdCl₂ graphite intercalation compound precursor by lithium-diphenylide in tetrahydrofuran at room temperature. Selected-area electron diffraction patterns provide evidence that the palladium nanoparticles are hcp single-crystal particles. Owing to the template effect of the graphite lattice, the lattice parameter of palladium was found to have a strong relation with the graphite, and a 3a _graphite superstructure was inferred. The palladium structure is rotated by 30^o with regard to the carbon host lattice. Raman spectroscopy on this sample showed that a charge transfer between carbon and palladium occurs. The sample can be considered as a common Pd-graphite intercalation compound with palladium nanoparticles as guest. This behaviour is different from palladium nanoparticles prepared by hydrogen reduction at higher temperatures from the same precursor material. These particles may represent an early stage of nanoparticle formation.     

Ridge structural equation modelling with correlation matrices for ordinal and continuous data

This paper develops a ridge procedure for structural equation modelling (SEM) with ordinal and continuous data by modelling the polychoric/polyserial/product‐moment correlation matrix R . Rather than directly fitting R , the procedure fits a structural model to R _a= R +a I by minimizing the normal distribution‐based discrepancy function, where a > 0. Statistical properties of the parameter estimates are obtained. Four statistics for overall model evaluation are proposed. Empirical results indicate that the ridge procedure for SEM with ordinal data has better convergence rate, smaller bias, smaller mean square error, and better overall model evaluation than the widely used maximum likelihood procedure.     

Lottery attractiveness and presentation mode of probability and value information

The attractiveness of lotteries that vary in p (probability) and o (outcome) depends on the presentation mode of p and o information. Extending previous findings on temporally experienced p, we manipulate the numerically stated versus spatially experienced format of both p (graphical presentation of a distribution of lottery tickets in an urn) and o (distribution of money notes). Lottery attractiveness ratings were sensitive to the expected value (EV), but p received more weight than o at constant EV levels (p‐dominance). Both EV sensitivity and p‐dominance were enhanced for experienced p and numerical o. This format particularly revealed the unattractiveness of low‐p lotteries. Experiencing p was functional in terms of accuracy and high‐risk avoidance, but only when the task environments rendered p diagnostic of EV. The presentation mode manipulations did not affect the initial perception stage but the relative weighting of p and o in the final judgment integration stage. Copyright © 2010 John Wiley & Sons, Ltd.     

Characterization of PLZT ceramics modified by isovalent (Ba,Sr), donor (Nb) and acceptor (Zn) dopants for piezoelectric applications

This article describes the influence of microstructure on the dielectric and piezoelectric properties of isovalent- donor- and acceptor-modified lead lanthanum zirconium titanate (PLZT) ceramics. The ceramic compositions, with formula: [Pb_0.954La_0.016Ba_0.01Sr_0.02][Zr_0.525Ti_0.475]_{0.981?( m /2)}Nb_0.012Zn _m O₃ where m =?0, 0.2, 0.4, 0.6, 0.8 and 1.0 mol% Zn, were synthesized via a solid-state reaction method. X-ray diffraction studies are supported by tolerance factor and electronegativity difference measurements. Scanning electron microscopy studies reveal grain growth enhancement with increase of Zn concentration. As the Zn concentration increased from 0 to 0.8 mol%, the room-temperature dielectric constant increased while the Curie temperature decreased continuously. An increase in the Zn content had the most significant effect on the piezoelectric properties. The optimum piezoelectric properties were observed for 1 mol% Zn composition.     

Phonon renormalization,specific-heat anomaly and why some aspects of mean-field theory can be relevant for high-T c superconductivity

Abstract

Phonon anomalies due to superconductivity in YBa₂Cu₃O₇ are correlated with the superconducting order parameter. The phonon part of the excess specific heat follows the same temperature evolution as the measured macroscopic excess heat capacity. The electronic part of the transformation entropy corresponds to about 10% of the total carrier concentration. No excess entropy was found at temperatures well above T_c. The effect of phonon contributions to the stabilization energy of the superconducting phase is discussed.     

Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate

The Raman spectra and electronic spin resonance (ESR) parameters (spin-Hamiltonian parameter g factors, zero-field splitting parameter D, and hyperfine structure constant A) for the trigonal V³⁺ centers in salt guanidinium vanadium sulfate hexahydrate (GVSH) are calculated from the complete diagonalization (of energy matrix) method. The theoretical results are in agreement with the experimental findings and the trigonal crystal-field parameters are determined. The difficulty in explaining ESR parameters of V³⁺ in GVSH is removed.     

Electrical properties of thin films of a-Ga x Te100− x composed of nanoparticles

Thin films of Ga _x Te_{100? x} (x?=?3, 6, 9 and 12) have been synthesized by thermal evaporation. From SEM images, it is observed that all the films contain nanoparticles of sizes varying from 100 to 200?nm. The dc electrical conductivity of the as-deposited films of Ga _x Te_100?x nanoparticles is measured as a function of temperature range from 298 to 383?K, and increases exponentially with temperature. The value of the activation energy, calculated from the slope of ln?σ _dc versus 1000/T plots, is found to decrease with increase in the Ga content. On the basis of the value of the pre-exponential factor σ _o, it is suggested that the conduction is due to thermally assisted tunneling of carriers in localized states near the band edges. The optical measurements suggest an indirect optical band gap in this system. The value of the optical band gap decreases on increasing the Ga concentration.     

PbO compensation in the growth of PbWO4: Y3+ crystals

The light yield of Y³⁺-doped PbWO₄ crystals increases after low-dose-rate irradiation with?γ?rays, and the radiation hardness is sensitive to annealing temperature. In the PWO growth procedure, an excess of PbO in the starting materials is a convenient method of compensating for PbO volatility. The relationship between the excess of PbO and the abnormal radiation behaviour has been investigated. The mechanism of the normal excess of PbO in the growth of PWO: Y³⁺ is discussed.     

Frequency-temperature dependent dynamics of dielectrics in ferric oxoborate Fe3BO6 of cocktail structure of nanorods

Oxoborates have both dielectric and magnetic properties useful for magnetodielectric devices, sensors, or biological tools. Such compounds Fe₂BO₄, Fe₃BO₅, or Fe₃BO₆ are known to grow easily as single crystals in a liquid flux. A polycrystalline phase forms only on controlled conditions of a solid state reaction of the basic oxides. In this study, we report highly dielectric Fe₃BO₆ when grown in a specific shape of nanorods (～200?nm diameter and 50–100?µm length) from an iron borate glass, which offers devisable shapes of sheets, discs, and fibers. Frequency (f)-temperature reliant dynamics of dielectric constant ε_r is studied over 25–300°C at 0.1–10^3?kHz frequencies. At low frequency such as 100?Hz, a large ε_r -value 40,000, better than most of high ε_r -value ferroelectrics, incurs at room temperature. At f?≥?50?kHz, although only an order of diminished ε_r -value lasts, it increases steadily with temperature, possibly due to increasing electrical conductivity in a specific resistor–capacitor network. Suppressed dielectric relaxation and spin-flops share a merely weak spin-reorientation transition near 160°C. A stable power loss ≤0.5 lasts at f?>?10?kHz useful for possible applications of magnetodielectric materials.     

Informative Aboutness

Pretheoretically, (B) ‘all believers are immortal’ is about all believers, but (1) B is not about any unbeliever. Similarly, (M) ‘all mortals are unbelievers’ is not about any immortal, but (2) M is about all mortals. But B and M are logically equivalent universal generalizations, so arguably they are about exactly the same objects; by (2), they are about those mortals who are unbelievers, contradicting (1). If one responds by giving up (1), is there still a sense in which B treats unbelievers differently from believers? I argue that there is. B is uninformative about unbelievers but informative about believers, in the following sense: for any object o, the information that B provides only about o—namely, ‘o is a believer only if o is immortal’—is entailed (and thus rendered redundant) by ‘o is an unbeliever’ but not by ‘o is a believer’.