Adoption of near-coincident-site lattice orientations by contacting monolayer rafts of metallic nanoparticles with different superlattice periodicities

A hexagonal raft of monodisperse alkane-thiol-stabilized Au nanoparticles has been self-assembled from solution on to an amorphous C substrate and then subsequently a second layer of monodisperse but differently sized gold nanoparticles deposited on top of the first. Detailed analysis of electron micrographs obtained from various regions of this bilayer revealed the presence of several distinct epitaxial interface structures. A simple near-coincident-site lattice model is used to rationalize the existence of the observed characteristic nanoparticle interface structures.     

Voidites in pure type IaB diamonds

Abstract

Electron microscopy of five pure type IaB diamonds (showing no trace whatever of a B′ infrared absorption peak due to {001} platelets) reveals voidite distributions unlike any reported before. In three of the crystals the voidites are distributed at random, and are not associated with degraded platelets, which themselves are not present in these specimens. These observations show that voidite formation and platelet degradation are distinct independent phenomena. The other two speamens showed only arrays of dislocations that patently resulted from plastic deformation: no voidites were seen. The non-formation of platelets in diamonds showing such an advanced stage of nitrogen aggregation is unexpected, and places these diamonds in a category distinct from that called ‘irregular’, in which platelets have indeed formed, but then experienced, to some degree, a process of transformation to perfect dislocation loops.     

Meta-Invariant Structure in Stimulus Arrays: A Response to Mace's Zetetic Challenge to Ecological Perceptual Researchers

ABSTRACT

Ecological perception, per James Gibson's theory, avows that perception depends on informative structure in stimulus arrays, where information is defined as stimulus array invariants. Gibson, however, was somewhat vague about the nature of such structure. Consequently, ecological perceptual research—even acknowledging some remarkable successes—has generally been ad hoc: Lacking principled heuristics, researchers examine array structure, which, by some means, they have come to discover as (or believe to be) informative. Here, I propose a series of heuristic principles potentially useful for the discovery of informative structure in stimulus arrays, with examples to suggest how those principles might apply. The major benefit of principled search for stimulus array invariants is more efficient elaboration of their function in perception. While admittedly preliminary, the principles outlined may both guide perceptual investigations and prompt additional consideration of how to approach the search for stimulus array invariants.     

Inhibitory Control of Lexical Selection in Adults who Stutter

PurposeBased on previous evidence that lexical selection may operate differently in adults who stutter (AWS) versus typically-fluent adults (TFA), and that atypical attentional processing may be a contributing factor, the purpose of this study was to investigate inhibitory control of lexical selection in AWS.Method12 AWS and 12 TFA completed two tasks. One was a picture naming task featuring High and Low Agreement object naming. Naming accuracy and reaction times (RT), and event-related potentials (ERPs) time-locked to picture onset, were recorded. Second was a flanker task featuring Congruent and Incongruent arrow arrays. Push-button accuracy and RTs, and ERPs time-locked to arrow array onset, were recorded.ResultsLow Agreement pictures were named less accurately and slower than High Agreement pictures in both Groups. The magnitude of the Agreement effect on naming RTs was larger in AWS versus TFA. Delta-plot analysis revealed that the Agreement effect was positively correlated with individual differences in inhibition in TFA but not in AWS. Moreover, Low Agreement pictures elicited negative-going ERP activity relative to High Agreement pictures in both Groups. However, the scalp topography of this effect was markedly reduced in AWS versus TFA. For the Flanker task, Congruency affected push-button accuracy and RTs, and N2 amplitudes, similarly between groups.ConclusionsResults point to a selective deficit in inhibitory control of lexical selection in AWS. Potential pathways between diminished inhibitory control of lexical selection, speech motor control and stuttering are discussed.     

Ordered nanostructures by site-specific heterogeneous nucleation

Highly site-specific heterogeneous nucleation from the vapour phase has been exploited to produce metallic nanostructures on reconstructed ceramic surfaces. The site-specificity arises from the fact that nucleation takes place under highly undersaturated conditions and hence occurs only on specific favourable sites. This approach has been used to produce ordered arrays of nanoparticles, nanorods and nanowires of different metals. The experimental conditions needed to produce different nanostructures are elucidated.     

Revealing texture architecture in a surface gradient nanostructured Al-Cu-Mg alloy

ABSTRACT

A multiscale crystallographic texture architecture in a surface gradient nanostructured Al-Cu-Mg alloy after surface sliding friction treatment (SSFT) has been revealed by a combination of electron backscatter diffraction and precession electron diffraction (PED)-assisted transmission electron microscopy (TEM) orientation mapping. Accompanying a grain structure variation from lamellar coarse grains to equiaxed nanograins, the major texture components evolve from brass {110}<112> in the coarse-grain matrix, Goss {110}<001> at a depth of ～80?μm, E {111}<011> and F {111}<112> at a depth of ～20?μm, to a mixture of rotated cube {001}<110>, E and F in the topmost surface layer. The through-thickness textural development and evolution are attributed to the cyclic loading of concurrent shear and compression during the SSFT processing. The PED-assisted orientation mapping shows good capability in mapping severe plastic-deformation-induced nanostructures with large residual strains and high defect density.     

Positive and Negative Hypothesis Testing by Cooperative Groups

In a rule induction problem positive hypothesis tests select evidence that the tester expects to be an example of the correct rule if the hypothesis is correct, whereas negative hypothesis tests select evidence that the tester expects to be a nonexample if the hypothesis is correct. Previous research indicates the general effectiveness of a positive test strategy for individuals, but there has been very little research with cooperative groups. We extend the analysis of Klayman and Ha (Psychological Review, 1987) of ambiguous verification or conclusive falsification of five possible types of hypotheses by positive and negative tests by emphasizing the importance of further examples following hypothesis tests. In two experiments four-person cooperative groups solved rule induction problems by proposing a hypothesis and selecting evidence to test the hypothesis on each of four arrays on each trial. In different conditions the groups were instructed to use different combinations of positive and negative tests on the four arrays. Positive tests were more likely to lead to further examples than negative tests, and the proportion of correct hypotheses corresponded to the proportion of positive tests, in both experiments. We suggest that positive tests are more effective than negative hypothesis tests in generating further evidence, and thus in inducing the correct rule, in experimental rule induction tasks with a criterion of certainty imposed by the researcher.     

An efficient algorithm for PARAFAC of three-way data with large numbers of observation units

The CANDECOMP algorithm for the PARAFAC analysis ofn×m×p three-way arrays is adapted to handle arrays in whichn>mp more efficiently. For such arrays, the adapted algorithm needs less memory space to store the data during the iterations, and uses less computation time than the original CANDECOMP algorithm. The size of the arrays that can be handled by the new algorithm is in no way limited by the number of observation units (n) in the data.The authors are obliged to Jos ten Berge for his comments on an earlier version of this paper. The research of Henk A. L. Kiers has been made possible by a fellowship of the Royal Netherlands Academy of Arts and Sciences.     

Masked constituent letter priming in an alphabetic decision task

Abstract

The experiments presented here were designed to test whether the prior presentation of a letter in a word, nonword or a string of Xs facilitates the subsequent identification of this letter. Using briefly presented masked primes, clear facilitatory constituent priming effects were obtained in an alphabetic decision task (letter/non-letter classification) when prime letters were flanked by Xs, but the effects disappeared or were greatly reduced when the prime letter formed part of a consonant array (nonword primes). Evidence for word-letter constituent priming was also obtained but almost only for word-initial letten. These facilitatory constituent priming effects were strongest when the target letter was embedded in a string of hash marks and occupied the same relative position in this string as the prime letter in the prime string. The mediating role of letter representations in word recognition and the position-specific coding of character arrays are discussed in the light of these results.     

Degeneracy in Candecomp/Parafac and Indscal Explained For Several Three-Sliced Arrays With A Two-Valued Typical Rank

The Candecomp/Parafac (CP) method decomposes a three-way array into a prespecified number R of rank-1 arrays, by minimizing the sum of squares of the residual array. The practical use of CP is sometimes complicated by the occurrence of so-called degenerate sequences of solutions, in which several rank-1 arrays become highly correlated in all three modes and some elements of the rank-1 arrays become arbitrarily large. We consider the real-valued CP decomposition of all known three-sliced arrays, i.e., of size p×q×3, with a two-valued typical rank. These are the 5×3×3 and 8×4×3 arrays, and the 3×3×4 and 3×3×5 arrays with symmetric 3×3 slices. In the latter two cases, CP is equivalent to the Indscal model. For a typical rank of {m,m+1}, we consider the CP decomposition with R=m of an array of rank m+1. We show that (in most cases) the CP objective function does not have a minimum but an infimum. Moreover, any sequence of feasible CP solutions in which the objective value approaches the infimum will become degenerate. We use the tools developed in Stegeman (2006), who considers p×p×2 arrays, and present a framework of analysis which is of use to the future study of CP degeneracy related to a two-valued typical rank. Moreover, our examples show that CP uniqueness is not necessary for degenerate solutions to occur. The author is supported by the Dutch Organisation for Scientific Research (NWO), VENI grant 451-04-102.     

Power-law island size distributions and the Avrami model

The island size distribution in the early stages of thin-film deposition is simulated using the Avrami model and is shown to follow closely a power-law form for both two- and three-dimensional island growth. This model applies to systems where the time-averaged monomer density is constant across the substrate, as occurs for example when the mean free path of the diffusing monomers is limited. It offers a possible explanation for recently observed island size distributions which are continuously decreasing functions of size in certain systems. The distribution of nearest-neighbour separations of the islands is also considered and it is shown that this distribution can be used to distinguish between island arrays formed in the Avrami model and those of deposition-diffusion-aggregation models.     

Transforming three-way arrays to maximal simplicity

Transforming the core array in Tucker three-way component analysis to simplicity is an intriguing way of revealing structures in between standard Tucker three-way PCA, where the core array is unconstrained, and CANDECOMP/PARAFAC, where the core array has a generalized diagonal form. For certain classes of arrays, transformations to simplicity, that is, transformations that produce a large number of zeros, can be obtained explicitly by solving sets of linear equations. The present paper extends these results. First, a method is offered to simplifyJ ×J × 2 arrays. Next, it is shown that the transformation that simplifies anI ×J ×K array can be used to also simplify the (complementary) arrays of order (JK −I) ×J ×K, of orderI × (IK −J) ×K and of orderI ×J × (IJ −K). Finally, the question of what constitutes the maximal simplicity for arrays (the maximal number of zero elements) will be considered. It is shown that cases of extreme simplicity, considered in the past, are, in fact, cases of maximal simplicity.     

Spontaneous visual search during the first two years: Improvement with age but no evidence of efficient search

Efficient visual search, wherein reaction times to acquire targets are largely independent of array size, is commonly observed in adults. Evidence for efficient search in infants may imply that selective attention to visual features is similar across development. In the current cross-sectional eye-tracking study, we examined spontaneous visual search at 6, 12, 18, and 24 months. Infants were presented with Random arrays (one target among 7, 13, or 26 pseudorandomly distributed elements) and Circle arrays (one target among 4, 7, or 13 elements arranged in a circle). Contrary to predictions, we did not find evidence of efficient search among infants. With increasing array size, time-to-target increased, the proportion of targets fixated (analogous to accuracy) decreased, and the proportion of first looks to the target decreased for both types of array (ps < .001). For Random arrays, the proportion of first looks to the target was similar to chance for all ages and array sizes; for Circle arrays, it exceeded chance for some ages and array sizes. The proportion of targets fixated and first looks to target increased with age across display types (ps < .05). We also tested adults with the same stimuli under similar conditions; the adults showed evidence of efficient visual search. Possible explanations and implications are discussed.     

The dimensionality of the flanker compatibility effect: A psychophysiological analysis

The psychophysiological approach was used to evaluate the effects of feature similarity and intrinsic response mapping on the flanker compatibility effect. Symbol (e.g., < > < and < / <) and letter arrays (e.g., HCH and SCS) were used. Results showed that delays in stimulus evaluation and both peripheral and central response competition contributed to the compatibility effect, with the contribution of these processes depending on feature similarity and the intrinsic response mapping of the stimuli. For letter stimuli, the difference in the size of the compatibility effect for similar and dissimilar arrays could be accounted for in terms of stimulus evaluation. For symbol arrays, differences in size of the compatibility effect could be accounted for by response competition. Thus, symbol and letter arrays do not appear to be processed differently; what is different is the degree to which stimulus and response-related processes are affected by incompatibility.     

Proof theory and mathematical meaning of paraconsistent C-systems

A proof-theoretic analysis and new arithmetical semantics are proposed for some paraconsistent C-systems, which are a relevant sub-class of Logics of Formal Inconsistency (LFIs) introduced by W.A. Carnielli et al. (2002, 2005) [8] and [9]. The sequent versions BC, CI, CIL of the systems bC, Ci, Cil presented in Carnielli et al. (2002, 2005) [8] and [9] are introduced and examined. BC, CI, CIL admit the cut-elimination property and, in general, a weakened sub-formula property. Moreover, a formal notion of constructive paraconsistent system is given, and the constructivity of CI is proven. Further possible developments of proof theory and provability logic of CI-based arithmetical systems are sketched, and a possible weakened Hilbert?s program is discussed. As to the semantical aspects, arithmetical semantics interprets C-system formulas into Provability Logic sentences of classical Arithmetic PA (Artemov and Beklemishev (2004) [2], Japaridze and de Jongh (1998) [19], Gentilini (1999) [15], Smorynski (1991) [22]): thus, it links the notion of truth to the notion of provability inside a classical environment. It makes true infinitely many contradictions B∧¬B and falsifies many arbitrarily complex instances of non-contradiction principle ¬(A∧¬A). Moreover, arithmetical models falsify both classical logic LK and intuitionistic logic LJ, so that a kind of metalogical completeness property of LFI-paraconsistent logic w.r.t. arithmetical semantics is proven. As a work in progress, the possibility to interpret CI-based paraconsistent Arithmetic PACI into Provability Logic of classical Arithmetic PA is discussed, showing the role that PACIarithmetical models could have in establishing new meta-mathematical properties, e.g. in breaking classical equivalences between consistency statements and reflection principles.     

Interfacing the Somatosensory System to Restore Touch and Proprioception: Essential Considerations

ABSTRACT

State-of-the-art upper extremity prostheses include anthropomorphic hands with dexterity that approximates that of a human. To be fully useful, these devices will require an advanced somatosensory neural interface to convey tactile and proprioceptive feedback to the user. To this end, microstimulation methods are being developed using microelectrode arrays implanted at various locations along the somatosensory neuraxis, from peripheral nerves to primary somatosensory cortex. There is presently no consensus as to the best approach, although results from animal and human studies lend support for each. The purpose of this review is to outline practical considerations for the design of a somatosensory interface based on present knowledge of the anatomy and physiology, prior attempts to elicit somatic sensations using electrical stimulation, and lessons learned from successful sensory neuroprostheses such as the cochlear implant.     

Tilted InSb nanostructures fabricated by off-normal ion beam irradiation

ABSTRACT

Using a two-step focused ion beam irradiation process, tilted InSb nanostructures have been fabricated using a off-normal angle of irradiation. In the first step, a well-focused ion beam was used to irradiate the surface of the structure to achieve top-down sputtering. In the second step, the ion beam was used to irradiate the entire surface to promote bottom-up nanostructure growth through the migration of ion-beam-induced interstitial atoms. The formation of a nanostructure with a 46° tilt and an aspect ratio of 0.5 was achieved using ion beam irradiation at an angle of 45° in both steps of the process. The 2% concentration of point defects obtained by changing the volume of the nanostructure before and after irradiation contributed to the growth of the structure. The results showed that many point defects did not recombine, and survived to contribute toward the growth of the wall structure.     

An object-based template for rejection effect

ABSTRACT

In the process of searching for targets, our visual system not only prioritizes target-relevant features, but can also suppress nontarget-related features. Although this template for rejection has been well demonstrated, whether the features (i.e. the objects) or locations are suppressed remains unresolved due to the experimental paradigms in previous studies: in particular, object-based templates for rejection were confounded with location-based inhibition in visual search paradigms. The present study examined an object-based template for rejection by introducing search arrays comprised of two overlapping shapes with search items distributed along the shape's contours. To discourage location-based inhibition, the two shapes were spatially intermingled (Experiment 1), rotated (Experiment 2), or jiggled (Experiment 3). Participants identified the colour of a target cross. The pre-cue indicated the shape in which the target would appear (positive cue condition), the shape in which only distractors would appear (negative cue condition), or the shape that was irrelevant to the current search array (neutral cue condition). In all three experiments, the reaction times for the negative cue condition were shorter than those for the neutral cue condition, which is a hallmark of the object-based template for rejection effect, even under conditions in which location-based inhibition was discouraged.     

One ‘knows’: self-rated health and telomere length among ex-prisoners of war

Abstract

Objective: Ill-health and early mortality are amongst the most significant ramifications of trauma. Furthermore, trauma alters the subjective perception and experience of the body. The aim of this study is to examine the extent to which deteriorations in perceived health among traumatised individuals are associated with cellular health as manifested in telomere length.

Methods: Specifically, 88 former prisoners of war (ex-POWs) evaluated their health (self-rated health; SRH) at 18 (T1), 35 (T2) and 42 (T3) years after the war, and were assessed for telomere length at T3. Health behaviour, BMI, morbidity and PTSD were also examined at T3.

Results: The findings demonstrated that SRH was cross-sectionally correlated with telomere length. Furthermore, a significant sequential indirect effect was found, in which worse SRH in T1 was associated with shorter telomere length at T3, through worse SRH at T2 and at T3.

Conclusions: These findings demonstrate that long-term deteriorations in the subjective evaluations of health are implicated in actual cellular health among individuals exposed to trauma.     

Less is not more: Further observations on nonlinguistic strategies

In an attempt to clarify the role of nonlinguistic preferences in children's responses to the words more and less, children 3–4 years of age were administered three tasks. Two of these required the child to indicate which of two arrays had more or less items, as instructed; the third task required the child to point to any one of two arrays. Children consistently selected the arrays with more items on all three tasks. The present finding of a response bias necessitates a reinterpretation of earlier studies of more and less. The results are discussed in terms of the full and partial semantics hypotheses as articulated by E. Clark.