Microstructural evolution of single-walled carbon nanotubes under electron irradiation

A sample containing single-wall carbon nanotubes (SWCNTs) has been annealed at 900°C and then irradiated by high-energy electrons in an ultrahigh-vacuum transmission electron microscope. Sequential high-resolution images showed that the structures of SWCNT bundles and individual SWCNT segments first collapsed into disordered and fullerene-like carbon materials and then reorganized into graphitic particles under continuous electron irradiation. The speed of structural evolution is dependent on the flux density of the electron irradiation.     

Anisotropic thermal properties of single-wall-carbon- nanotube-reinforced nanoceramics

Dense single-wall-carbon-nanotube-(SWCNT)-reinforced alumina nanocomposites have been fabricated by a novel spark-plasma-sintering technique. Anisotropic thermal properties have been found in carbon nanotube composites. The introduction of ropes of SWCNTs gives rise to a decrease in the transverse thermal diffusivity with increasing carbon nanotube content while it does not change the in-plane thermal diffusivity. This is scientifically interesting and technologically important for the development of materials for novel thermal barrier coatings.     

Infiltration behaviour of water in a carbon nanotube under external pressure

The wetting behaviour and associated pressure effect of water in single-walled carbon nanotubes (SWCNTs) are investigated through molecular dynamics (MD) simulations. It is found that water molecules can enter SWCNTs via surface diffusion, and the effective infiltration rate increases with pressure. The effect of pressure on infiltration rate is highly non-linear, exhibiting characteristics of both hydrophilic and hydrophobic surfaces. There exists a nominal infiltration pressure that is dependent on the SWCNT size, above which the water flux is significantly increased.     

Effects of annealing temperature on structural,optical, and electrical properties of antimony-doped tin oxide thin films

Antimony-doped tin oxide (ATO) films, approximately 320 nm in thickness, have been prepared by electron beam evaporation onto glass substrates. The films were annealed at temperatures between 400°C and 550°C in air and their structure and surface morphologies were observed by X-ray diffraction (XRD) and atomic force microscopy (AFM) after the different annealing treatments. XRD patterns of the ATO thin films as-deposited and annealed at 400°C showed that they were amorphous, but annealing beyond 400°C caused the films to become polycrystalline with tetragonal structure and orientated in the (1 1 0) direction. The grain size in the annealed films, obtained from the XRD analysis, was in the range 146–256 Å and this increased with the annealing temperature. The dislocation density, cell volume and strain were found to decrease gradually with increasing annealing temperature. Photoluminescence spectra revealed an intensive blue/violet peak at 420 nm, which increased gradually in height with annealing. It is suggested that an increase in the population of Sb⁺⁵ ions might be the reason for the enhancement of the blue/violet emission. The optical properties of the films were also investigated in the UV-visible-NIR region (300–1000 nm). The optical constants, namely the refractive index n and the extinction coefficient k in the visible region were calculated. The optical energy band gap, as determined by the dependence of the absorption coefficient on the photon energy at short wavelengths, was found to increase from 3.59 to 3.76 eV with annealing temperature.     

Contextual cueing is not flexible

Target detection is faster when search displays repeat, but properties of the memory representations that give rise to this contextual cueing effect remain uncertain. We adapted the contextual cueing task using an ABA design and recorded the eye movements of healthy young adults to determine whether the memory representations are flexible. Targets moved to a new location during the B phase and then returned to their original locations (second A phase). Contextual cueing effects in the first A phase were reinstated immediately in the second A phase, and response time costs eventually gave way to a repeated search advantage in the B phase, suggesting that two target-context associations were learned. However, this apparent flexibility disappeared when eye tracking data were used to subdivide repeated displays based on B-phase viewing of the original target quadrant. Therefore, memory representations acquired in the contextual cueing task resist change and are not flexible.     

Implementing innovative flexible work practices in Nigerian local firms: Implications for management of change in less‐developed countries

There is an increasing interest in Africa as a potential sourcing location and a target for foreign direct investment (FDI). However, because of the uniqueness of the African context, there is a need to investigate whether management theories that have worked effectively in organizations in developed countries may be applicable within the African context. In this study, using a multiple case study approach, we investigated change implications and the effectiveness of implementing flexible work practices in local firms in Nigeria. Our results revealed that employees in local firms in Nigeria were compliant with the introduction of the practices, despite their negative perceptions about the potential impact of implementing the change and the ‘management of change’ process. Our study revealed that social, cultural, and religious factors, along with the value systems of the Nigerian context played a major role in influencing employees’ reaction to the successful implementation of the flexible work practices. The implications of the study for theory and practice within the broader African context are discussed.     

On the length scale of cyclic strain localization in fine-grained copper films

Fine-grained copper films on a flexible substrate were cyclically deformed under constant strain range control. It was found that cyclic dislocation plasticity through individual dislocation glide is still dominant at the submicrometer scale, while the ability of irreversible slip of dislocations gradually decreases and the damage was changed from extrusion-induced localization to cracking along grain boundary. Statistical evaluation of the mean spacing between slip bands and/or lines leads to a critical scale (～28 nm) below which dislocation-controlled cyclic strain localization would be shut down.     

Reversible phase transition in vanadium oxide films sputtered on metal substrates

Vanadium oxide films, deposited on aluminium (Al), titanium (Ti) and tantalum (Ta) metal substrates by pulsed RF magnetron sputtering at a working pressure of 1.5 x10^?2 mbar at room temperature are found to display mixed crystalline vanadium oxide phases viz., VO₂, V₂O₃, V₂O₅. The films have been characterized by field-emission scanning electron microscopy, X-ray diffraction, differential scanning calorimetry (DSC) and X-ray photoelectron spectroscopy, and their thermo-optical and electrical properties have been investigated. Studies of the deposited films by DSC have revealed a reversible-phase transition found in the temperature range of 45–49 °C.     

Effect of grain orientation and local strain on the quality of polycrystalline YBa 2 Cu 3 O 7 superconductive films

The critical current densities of superconducting thin films and their dependence on the film structural characteristics has been a major research interest for more than a decade. Controlling this relationship is crucial if large-scale high-quality YBa 2 Cu 3 O 7 (YBCO) tapes are to be produced. Two major keystones of information have been established in this field. Firstly, there is a direct relationship between the critical current density and the grain-boundary angle in polycrystalline YBCO films. Grain boundaries with a mismatch angle higher than 5° usually result in reduced critical current densities. This detrimental effect of large-angle grain boundaries to the quality of YBCO films has been attributed to strain fields resulting from such grain boundaries. Secondly, the quality of the YBCO film can be enhanced by straining its lattice in specific direction. Here, we report, for the first time, direct experimental results coupling local grain orientation and local strain maps of thin YBCO films deposited on a (001) biaxially textured nickel substrate. These results were correlated to the quality of the film and showed how grain structure in the nickel substrate affects the grain structure in the YBCO films even in the presence of several buffer layers. More importantly, the data show that highquality films with high critical current densities can be produced, in spite of large-angle grain boundaries, if the film is compressed in the range of 0.5% strain normal to the a axis.     

Microplasticity of copper thin films on silicon substrates

Internal friction in polycrystalline copper films 0.2-1.5 w m thick on silicon substrates has been measured as a function of strain amplitude. The internal friction in the films increases with increasing strain amplitude but at a value of the strain amplitude that is at least two orders of magnitude greater than the similar increase in bulk copper. Analysis of the amplitude-dependent internal friction provides the plastic strain of the order of 10 -9 as a function of effective stress on dislocation motion. Since the grain size is larger than the film thickness, the microflow stress at a constant level of plastic strain varies inversely with the film thickness. The film thickness effect in the microplastic range can be explained on the basis of a dislocation-bowing model.     

Effect of heat treatment on the NO2-sensing properties of sputter-deposited indium tin oxide thin films

Transparent conducting indium tin oxide (ITO) films were deposited onto glass substrates by radio-frequency magnetron sputtering at 648?K, under an oxygen partial pressure of 1?Pa. The effect of annealing on the electrical properties of the films was studied. Characterization of the coatings revealed an electrical resistivity below 6.5?×?10^??3?Ω?cm. The ITO films deposited at 648?K were amorphous, while the crystallinity improved after annealing at 700?K. The surface morphology examined by scanning electron microscopy appears to be uniform over the entire surface area after annealing. The NO₂-sensing properties of the ITO films were investigated and showed sensitivity at concentrations lower than 50?ppm, at a working temperature of 600?K.     

Optical characterization of spin-coated cobalt porphyrazine thin films: effect of annealing temperature

Cobalt porphyrazine thin films were prepared by the spin-coating technique. The coated substrates were annealed at different temperatures (373, 423 and 523 K). The optical properties of the films were investigated by measuring the transmittance and reflectance spectra. The refractive index, extinction coefficient, optical band gap, dielectric constant values and thickness of the films were determined. Results showed that the refractive index, the extinction coefficient and the dielectric constants increased on annealing the films at 373 K in comparison with films annealed at other temperatures. On the other hand, the values of the band gap energy and thickness of the annealed film at 373 K were found to be the lowest in comparison with films annealed at different temperatures.     

Potential fluctuations in phase change memory materials

Long-range potential fluctuations have been quantified in amorphous and crystallised thin films of a family of Ge–Sb–Te (GST) chalcogenide glasses. Among the compositions studied, the width of the potential fluctuations is the smallest for amorphous Ge₂Sb₂Te₅. This is also the most robust material in terms of the number of write–erase cycles for GST films when used as phase change memory materials. A plausible explanation for this observation is given and a criterion for selecting suitable compositions in optical memory devices is proposed.     

Sol-gel-hydrothermal growth of oxide thin films at low temperatures

Lead zirconate titanate (PZT) (Pb(Zr_0.52Ti_0.48)O₃) and barium titanate (BaTiO₃) thin films have been successfully prepared using a novel sol-gel- hydrothermal (SG-HT) technique at low temperatures, which involves a combination of the conventional sol-gel process and a hydrothermal method. Highly (111)-oriented PZT thin films with a single perovskite phase and polycrystalline BaTiO thin films with well developed crystallites were obtained at a processing temperature as low as 160⁰C. The microstructural characteristics demonstrate that the SG-HT-derived PZT and BaTiO₃ thin films with good crystallinity and surface morphology are converted from the amorphous phase to the desired perovskite phase on platinum-coated and bare silicon substrates at a low processing temperature of 100-200 C. These results suggest that the SGHT technique, which is of great significance because of its low processing temperature, will become a potential and promising process for fabricating PZT, BaTiO₃ and other oxide thin films.     

Influence of properties of layered silicate minerals on adsorbed DNA surface affinity,self-assembly and nanopatterning

We report on the specific interaction between DNA and some mica-family minerals and other layered silicate structures. The interaction depends on mineral surface's crystallography, chemistry and potential. These properties are responsible for a remarkable variety of adsorption mechanisms and can be used to modulate surface self-assembly and nanopatterning of DNA. The controlled deposition of DNA onto non-conductive mineral regions with atomically flat boundaries has very attractive applications in nano-biotechnology (for example, microelectronics, microarrays and sensors). In addition, the extreme affinity discovered for some mineral surfaces, together with their ability to organize the DNA molecules, could be an indication of their catalytic potential. It may also have had relevance in the prebiotic environment, with important implications for the earth and life sciences.     

Structural support for the perception of growth

Previous studies have shown that the effects of a particular class of geometric transformations, known as cardioidal strain, are perceived as growth when applied to a variety of animate and even inanimate objects. The current study demonstrates that the effects of these growth transformations are not completely independent of the object undergoing change, but depend critically on certain structural characteristics. When cardioidal strain is applied to a straight-line, right-angle, robotlike structure, there is no consistent effect on the age level of the figure. However, as the structural contours become more curved and less angular, the effects of this transformation are seen as increasingly more like growth. In contrast, the effects of a shear transformation are not perceived as growth on any of the profiles. These findings are examined in light of the critical physical properties that may be responsible for this notion of biological forms as well as their implications for our understanding of the information about events.     

Density-functional and shell-model calculations of the energetics of basal-plane stacking faults in sapphire

We report the generation of fullerenes and nanotubes using an arc discharge on graphite in a high-pressure nozzle. The vapour from the arc is quenched via collisions with helium gas, forming carbon clusters within a localized highpressure region. The carbon molecules are entrained in the gas jet as it expands into the vacuum and deposited onto a silicon substrate in a low-pressure (6 mT) environment. Mass spectroscopy measurements of the plasma reveal the presence of C molecules in the expanding plume. Microstructural examination of films deposited using this method revealed clustered regions of larger fullerenes and nanotubes surrounded by an amorphous matrix. Films containing fullerenes and nanotubes were found to be significantly harder and more elastic than amorphous carbon films deposited under identical parameters but without conditions for fullerene and/or nanotube formation.     

From Passive to Proactive Motivation: The Importance of Flexible Role Orientations and Role Breadth Self-efficacy

Despite the widely held belief that a proactive workforce is necessary for competitive advantage, research investigating how to assess and promote such change is limited. Two potentially important precursors to proactivity include flexible role orientation (FRO) and role breadth self-efficacy (RBSE). These concepts have been shown to have construct validity and to be distinct from related dispositional variables, but their discriminant validity in terms of outcome variables has not been demonstrated. In this article, I show that FRO and RBSE are factorially distinct from outcomes commonly used in organisational research (job satisfaction, organisational commitment, and job strain). I also show that, as expected, the proactive motivation and traditional outcome variables have different relationships with various predictor variables. I outline the study implications, and suggest a broader research agenda on proactive motivation.     

Fourier transform infrared and Raman spectroscopy studies on a - and ß-C3N4 films

Crystalline carbon nitride films have been synthesized on Si(100) substrates by the microwave plasma chemical vapour deposition technique. In order to understand their structure, Raman and Fourier transform infrared spectra of aand b-C3N4 were calculated using a scale factor and the observed Raman and infrared spectra of a- and b-Si N . A scale factor (1.47) for the stretching 3 4 frequencies from the tetrahedral C-N to Si-N bonds was calculated through Hooke's law. Experimental Raman and infrared spectra conform to the calculated results: so we conclude that the film contain a-C3N4 and b-C3N4     

A new approach to surface photovoltage measurements on hydrogenated microcrystalline silicon layers

A new approach to the surface photovoltage method is demonstrated on thick undoped microcrystalline silicon films grown on different substrates. The model, which includes top as well as bottom space-charge regions, gives a good picture of rather complex experiments and allows good fitting of theoretical curves to experimental results. This method gives us not only the diffusion length of minority carriers but also information on the existence and properties of the space-charge regions in the sample and the results are verified by comparison with the standard procedure.