Energy,Complexity, and Strategies of Evolution: As Illustrated by Maya Indians of Guatemala

Using free energy rate density (Φ_m) I differentiate two evolutionary strategies common to cosmic, biological, and cultural systems: the horizontal when energy increases proportional to mass, with no increase in complexity; and the vertical when it increases disproportionately to the mass and complexity increases. The vertical process is a continuing increase in complexity such that the system becomes vulnerable to collapse when energy sources fail. This is illustrated by a comparison of four Mayan Indian groups in Guatemala.     

Thermophysical properties of undercooled liquid cobalt

The surface tension of undercooled liquid cobalt has been measured by the oscillating-drop technique combined with electromagnetic levitation. The accuracy of the method was verified by measurements of the surface tension of liquid nickel. The liquid cobalt was undercooled by up to 231K (0.13T _m), and its surface tension determined to be σ_Co =1875 0.348(T-T _m)mNm^-1. From this result, the viscosity, self-diffusion coefficient, density and thermal diffusivity of undercooled liquid cobalt were derived. Using these thermophysical parameters, the growth velocity of cobalt dendrite is calculated and shown to agree well with experimental results. Furthermore, the Marangoni number and the Rayleigh number are calculated; these increase slowly with increasing degree of undercooling.     

Effect of heterogeneous solute distribution on the anomalous thermomechanical response of Cu–Ni alloy single crystals below 50 K

The anomalous temperature dependence of the critical resolved shear stress (CRSS) of Cu–Ni alloys observed below a certain temperature, T _o?=?50?K, has been accounted for by introducing a stress-concentration factor f(T)?=?[(T?′?+?T _o)/(T?′?+?T)] in the monotonic CRSS–T formulation of the kink-pair nucleation model of solid-solution hardening. The empirical constant T?′ is found to depend not only on the solute concentration, c, but also on the nature of the solute distribution in the host lattice. It is found that the solute distribution is random for c?≤?14 at.% Ni in the Cu lattice and for c?≤?20 at.% Cu in the Ni lattice, whereas some sort of local ordering occurs for all other values of solute concentration.     

What Causes the Mean Bias of the Likelihood Ratio Statistic with Many Variables?

Abstract

Survey data often contain many variables. Structural equation modeling (SEM) is commonly used in analyzing such data. However, conventional SEM methods are not crafted to handle data with a large number of variables (p). A large p can cause T_ml, the most widely used likelihood ratio statistic, to depart drastically from the assumed chi-square distribution even with normally distributed data and a relatively large sample size N. A key element affecting this behavior of T_ml is its mean bias. The focus of this article is to determine the cause of the bias. To this end, empirical means of T_ml via Monte Carlo simulation are used to obtain the empirical bias. The most effective predictors of the mean bias are subsequently identified and their predictive utility examined. The results are further used to predict type I errors of T_ml. The article also illustrates how to use the obtained results to determine the required sample size for T_ml to behave reasonably well. A real data example is presented to show the effect of the mean bias on model inference as well as how to correct the bias in practice.     

Differential Method of Characterizing Gait Strategies From Step Lengths and Frequencies: Strategy of Velocity Modulation

The differential method consists of the analysis of the variation of gait parameters length, frequency, and velocity with respect to their mean values, respectively, ΔL = L — L_m , Δf = f — f_m , and Δv = v – v_m , where L_m , f_m , and v_m represent the mean values of those parameters. Assuming that the strategy of modulation of velocity implies that L and f are functions of v and that statistical analyses of ratios ΔL/Δv and Δf/Δv have established that there is a very significant linear correlation, close to 1, between those ratios, the mathematical procedure allows one to determine the equation of step length, L = a · f + b · v + K, where a and b are the slope and the intercept of the linear regression and K is close to L_m . The equation was experimentally tested on 140 gait sequences performed by 6 participants and for gait velocities ranging from 0.6 to 2.2 m/s and was found to be very representative of all individual values. The differential method provides another way of using the derivative of velocity, v = L·f, to characterize the strategy of velocity modulation, which then permits one to determine the linear equation of velocity, v = f · L_m + L · f_m — L_m · f_m , and to show that the respective parts played by each parameter in the progression velocity are approximately equal. The author establishes the uniqueness of the different linear adjustments and discusses the differential method's own modes of use, that is, interindividually or globally.     

Transcending Lindemann's predictions for the melting temperatures of metals and for the long-wavelength limit of their liquid structure factors

Lindemann's melting criterion remains useful. However, one prediction it makes for liquid metals (our focus here) is that the long-wavelength limit of the structure factor S(q) at freezing, S _{T m} (0), where T _m is the melting temperature, is a universal constant. For 34 metals we have calculated S _{T m} (0) from input data, which is essentially the measured T _m and the surface thickness L, defined near freezing as the product of isothermal compressibility and surface tension. To complete the characterization of S _{T m} (0) we fit to one metal, chosen as Rb, for which S _{T m} (0) is well established experimentally. For a wide variety of metals considered, S _{T m} (0) is then found to vary by a factor of 10.     

Bulk metallic glass formation near the TiCu–TiNi pseudo-binary eutectic composition

No bulk metallic glass (BMG) has been observed so far in the Ti–Cu binary system. It has been found that by choosing a pseudo-binary eutectic (L?→?TiCu +TiNi) deeper than that in the binary, reachable via only small substitution of Cu with Ni, the glass-forming ability can be effectively elevated. BMGs of 1–1.5 mm diameter have been formed over a composition range around Ti₅₀Cu₄₃Ni₇. The new BMGs are reproducibly malleable with significant compressive plastic strains.     

Effect of severe plastic deformation on the coercivity of Co–Cu alloys

Cast Co–5.6 wt% Cu and Co–13.6 wt% Cu alloys were subjected to severe plastic deformation (SPD) by high-pressure torsion (HPT). The HPT treatment drastically decreases the size of the Co grains (from 20 µm to 100 nm) and the Cu precipitates (from 2 µm to 10 nm). As a result, the coercivity H _c of both the alloys radically increases. The saturation magnetization, M _s, remains almost unchanged. Thus, SPD of the bulk samples opens the way for drastic increase in the coercivity for the Co-based alloys.     

A statistical test for means of samples from skew populations

This paper presents a test for determining significance of differences between means of samples which are drawn from positively skewed populations, more specifically, those having a Pearson Type III distribution function. The quantity 2npx _g /x _p (wherep equals the mean squared divided by the variance andn is the number of cases in the sample), which distributes itself as Chi Square for 2np degrees of freedom, may be referred to the tables of Chi Square for testing hypotheses about the value of the true mean. For two independent samples, the larger mean divided by the smaller mean, which distributes itself asF for 2n ₁ p ₁ and 2n ₂ p ₂ degrees of freedom, may be referred to theF distribution tables for testing significance of difference between means. The test assumes that the range of possible scores is from zero to infinity. When a lower theoretical score limit (c) exists which is not zero, the quantity (Mean —c) should be used instead of the mean in all calculations.     

Surface tension of substantially undercooled liquid Ti–Al alloy

It is usually difficult to undercool Ti–Al alloys on account of their high reactivity in the liquid state. This results in a serious scarcity of information on their thermophysical properties in the metastable state. Here, we report on the surface tension of a liquid Ti–Al alloy under high undercooling condition. By using the electromagnetic levitation technique, a maximum undercooling of 324 K (0.19 T _L) was achieved for liquid Ti-51 at.% Al alloy. The surface tension of this alloy, which was determined over a broad temperature range 1429–2040 K, increases linearly with the enhancement of undercooling. The experimental value of the surface tension at the liquidus temperature of 1753 K is 1.094 N m^?1 and its temperature coefficient is ?1.422 × 10^?4 N m^?1 K^?1. The viscosity, solute diffusion coefficient and Marangoni number of this liquid Ti–Al alloy are also derived from the measured surface tension.     

On the size of refutation Kripke models for some linear modal and tense logics

LetL be any modal or tense logic with the finite model property. For eachm, definer _L (m) to be the smallest numberr such that for any formulaA withm modal operators,A is provable inL if and only ifA is valid in everyL-model with at mostr worlds. Thus, the functionr _L determines the size of refutation Kripke models forL. In this paper, we will give an estimation ofr _L (m) for some linear modal and tense logicsL.     

Structural heterogeneity in a binary Pd–Si metallic glass

A Pd₈₁Si₁₉ bulk metallic glassy rod with a diameter of 4.5 mm was produced by water quenching the fluxed alloy. Despite a negative heat of mixing between Pd and Si elements and very simple components constituting the binary Pd–Si glass-forming system, structural heterogeneity was induced either by slow cooling of a liquid or sub-T_g annealing of glassy ribbons. The sub-T_g annealing experiments evidenced that a more ordered amorphous phase emerged from the original glassy matrix. Our work provides an alternative way to tune the microstructure of metallic glasses by subsequent thermal treatment on an as-prepared single glassy phase.     

Room temperature ferromagnetism and photoluminescence of nanocrystalline Zn1 − xCoxO thin films prepared by sol–gel MOD

Zn_1???xCo_xO (ZC) [x?=?0, 1, 3, 5, 7 and 9?mol%] thin films were prepared by sol–gel combined metallo-organic decomposition method. The films were deposited on the Si substrate with spin-coating technique and annealed at 600?°C for 3?h. X-ray diffraction pattern shows the formation hexagonal wurtzite phase and distortion (c/a) decreases with increasing Co concentration in ZnO. The average grain size is measured using Scherer relation. Atomic force microscopy is used to confirm the formation of nanograins resulted by the use of polyethylene glycol as surfactant. The photoluminescence was recorded by using He-Cd laser of excitation wavelength 325?nm in wavelength region of 350–650?nm which exhibits some influence of Co doping on the multiplication of defects such as O vacancies, Zn interstitials and grain boundary defects. All thin films show room temperature ferromagnetism except pure ZnO which is diamagnetic and 9?mol% of Co shows paramagnetism. This behaviour is interpreted as due to fluctuations in the magnetic ordering, depending on grain size and site location in grain boundaries or oxygen vacancies.     

Synthesis and characterization of nanocrystalline MoBi2Te5 thin films for photoelectrode applications

Molybdenum bismuth telluride thin films have been prepared on clean glass substrate using arrested precipitation technique which is based on self-organized growth process. As deposited MoBi₂Te₅ thin films were dried in constant temperature oven at 110°C and further characterized for their optical, structural, morphological, compositional, and electrical analysis. Optical absorption spectra recorded in the wavelength range 300–800?nm showed band gap (E _g) 1.44?eV. X-ray diffraction pattern and scanning electron microscopic images showed that MoBi₂Te₅ thin films are granular, nanocrystalline having rhombohedral structure. The compositional analysis showed close agreements in theoretical and experimental atomic percentages of Mo⁴⁺, Bi³⁺, and Te^2? suggest that chemical formula MoBi₂Te₅ assigned to as deposited molybdenum bismuth telluride new material is confirmed. The electrical conductivity and thermoelectric power measurement showed that the films are semiconducting with n-type conduction. The fill factor and conversion efficiency was characterized by photoelectrochemical (PEC) technique. In this article, we report the optostructural, morphological, compositional, and electrical characteristics of nanocrystalline MoBi₂Te₅ thin films to check its suitability as photoelectrode in PEC cell.     

Anatomical Specialization of the Anterior Motor Speech Area: Hemispheric Differences in Magnopyramidal Neurons

The lateralization of motor speech function to the left hemisphere is supported by multiple lines of evidence, but relatively little is known about the anatomical basis of that specialization. In a preliminary study, we recently reported that area 45 of the left hemisphere (Broca′s area) contained a subpopulation of magnopyramidal neurons which were significantly larger than any seen in the homotopic region of the right hemisphere (Hayes and Lewis, 1993a). In the present study we examined a larger sample of cases in order to determine how consistently this difference is present in the population, if it is specific to Broca′s area or is a general feature of cortical regions mediating lateralized functions, and whether the subpopulation of large magnopyramidal neurons in left area 45 can be distinguished by their chemical phenotype. In Nissl-stained sections from 19 human brains, the mean (±SD) cross-sectional area of the largest layer III pyramidal neurons in area 45 was significantly (p < .0001) greater in the left hemisphere (522.1 ± 128.3 μm²) than in the right (454.1 ± 121.5 μm²). This interhemispheric difference appeared to be a unique characteristic of the largest neurons, since the mean size of all layer III pyramids in this area was not significantly different in the left (206.2 ± 93.5 μm²) and right (213.3 ± 103.9 μm²) hemispheres. In contrast to area 45, there was no interhemispheric difference in the mean cross-sectional area of the largest layer III pyramids in another lateralized region, primary motor cortex. in addition, in area 46, a region of prefrontal association cortex not known to be functionally lateralized, the mean somal size of the largest layer III pyramidal neurons was significantly (p < .001) smaller in the left hemisphere (402.4 ± 84.9 μm²) than in the right (437.8 ± 88.3 μm²). Finally, although the large layer III pyramids in area 45 were immunoreactive for nonphosphorylated neurofilament protein in both hemispheres, the mean cross-sectional area of the largest labeled neurons was significantly larger (p < .002) in the left hemisphere (525.2 ± 149.0 μm²) than in the right (490.3 ± 154.1 μm²). These findings demonstrate that layer III of Broca′s area contains a distinctive subpopulation of neurons that may play an important role in the specific functional architecture of this region.     

Accuracy and performance of the state-based Φ and liveliness measures of information integration

A number of people have suggested that there is a link between information integration and consciousness, and a number of algorithms for calculating information integration have been put forward. The most recent of these is Balduzzi and Tononi’s state-based Φ algorithm, which has factorial dependencies that severely limit the number of neurons that can be analyzed. To address this issue an alternative state-based measure known as liveliness has been developed, which uses the causal relationships between neurons to identify the areas of maximum information integration. This paper outlines the state-based Φ and liveliness algorithms and sets out a number of test networks that were used to compare their accuracy and performance. The results show that liveliness is a reasonable approximation to state-based Φ for some network topologies, and it has a much more scalable performance than state-based Φ.     

Microstructure and mechanical behavior of nanostructured composite Cu60Fe40 alloy

In this study, bulk nanostructured composite Cu₆₀Fe₄₀ alloy is prepared by a combustion synthesis technique. The prepared Cu₆₀Fe₄₀ alloy consists of Cu(Fe) solid solution and Fe(Cu) solid solution phases. The large-scaled compositional segregation in the Cu-rich and Fe-rich phases is not observed, respectively. A few micron-sized dendrite (Fe(Cu) solid solution) is embedded into the nanostructured matrix (Cu(Fe) solid solution). The grain size of the matrix is in the range 50–300?nm. The yield and fracture strength of the Cu₆₀Fe₄₀ alloy are 540 and 1050?MPa, respectively, and the fracture strain obtained from the compression test is about 20.9%. The Cu₆₀Fe₄₀ alloy displays notable work hardening in the compressive deformation.     

Short-range order in the arrangement of grains in two-dimensional polycrystals

Abstract

Experimental results for two-dimensional grain growth are compared with the results obtained from computer-generated random threefold vertex networks with a fixed one-particle distribution function. A considerable discrepancy in the two-particle distributions implies some kind of short-range order. New results in the computer simulation of normal grain growth are reported, demonstrating a similar kind of ordering. A simple relation is suggested for the quantity m _n, introduced by Aboav and the second moment of the one-particle distribution μ₂     

Compositions of different phases appearing during devitrification of Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass

The devitrification process of Zr_46.75Ti_8.25Cu_7.5Ni₁₀Be_27.5 metallic glass during annealing in the supercooled liquid region has been studied by conventional, high-resolution and analytical transmission electron microscopy (TEM). Two kinds of particle appear during devitrification: quasicrystals and crystalline precipitates. Nanoanalysis with energy-dispersive X-ray spectroscopy and electron energy-loss spectroscopy reveal that quasicrystals are Be free, while the crystallites have the ZrBe₂ hexagonal structure. These experiments confirm the key role of Be during devitrification. They also indicate that quasicrystals can form in the system Zr–Ti–Cu–Ni (without Be), as further evidenced by direct synthesis and an in situ neutron diffraction investigation, according to the chemical composition deduced from the TEM analysis.     

Intermetallic compound identification and Kirkendall void formation in eutectic SnIn/Cu solder joint during solid-state aging

Microstructural investigations were performed on the interfacial reactions between eutectic SnIn solder and Cu substrate during reflowing at 433?K and solid-state aging at 373?K. Cu₂(In,Sn) was identified as the only intermetallic compound (IMC) at the interface, which consists of two sublayers with different morphology, a fine-grained sublayer at the Cu side and a coarse-grained sublayer at the solder side. During solid-state aging, voids were found between these two Cu₂(In,Sn) sublayers but not at the substrate interface, which is also attributed to the Kirkendall effect considering the different diffusion fluxes of Sn or In and Cu atoms in different sublayers.